Abstract
Catalytic oxidation mediated by bimetallic complexes is a rapidly expanding area of chemistry due to the potential of multimetal complexes for enhanced reactivity and selectivity compared to mononuclear analogs.1 A wealth of papers on mononuclear transition metal catalyzed oxidation reactions, using oxygen donors such as alkylhydroperoxides, hydrogen peroxide, alkaline hypohalides or iodosylbenzene, has been reported in the last decades.2 Important goals of both academic and industrial importance are;
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i.
oxidations without the production of stoichiometric amounts of salts and high atom economy conversions
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ii.
direct oxygenation of unfunctionalized hydrocarbons i.e. hydroxylations, although selective epoxidations, dehydrogenations, phenol oxidations, oxidative coupling reactions etc. are also highly warranted.
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Feringa, B.L. (1993). Oxidation Catalysis; A Dinuclear Approach. In: Karlin, K.D., Tyeklár, Z. (eds) Bioinorganic Chemistry of Copper. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-6875-5_24
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