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Artificial latices

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Abstract

Artificial latices are produced by the dispersion or redispersion of solid polymers in an appropriate medium. In the present state of latex technology, the dispersion medium is exclusively aqueous. Artificial latices have been of some industrial interest for many years. Notwithstanding this, they have never attained the level of industrial application which has been enjoyed by natural and synthetic latices. As will appear subsequently, artificial latices are not easy to prepare. Attempts are made to produce them only if the polymer cannot be conveniently produced as a synthetic latex, or if it is not available as a natural latex. If latices of such polymers are required, then they must be produced by dispersion of the bulk polymer. As a generalization, the problems associated with the production and application of artificial latices are tolerable only if the dispersed polymer offers some special properties, and only if it is particularly advantageous to manufacture the desired product from a latex rather than from the polymer in bulk. Quite apart from the difficulties associated with their production and utilization, artificial latices suffer from two important fundamental disadvantages relative to synthetic latices: the methods of preparation available at present are such that it is not possible to produce artificial latices which contain structured particles; and it is not possible conveniently to produce functionalized artificial latices, unless the initial bulk polymer is already functionalized.

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References

  1. Sievier, R. W., British Patent No. 7015, 27 August, 1836.

    Google Scholar 

  2. Alexander, P., British Patent No. 14,681, application date 17 July, 1905, acceptance date 26 October, 1905.

    Google Scholar 

  3. Alexander, P., British Patent No. 25,735, application date 14 November, 1906, acceptance date 10 October, 1907.

    Google Scholar 

  4. H. O. Traun’s Forschungslaboratorium GMBH, British Patent No. 156,150, 31 March, 1922.

    Google Scholar 

  5. Pratt, W. B., British Patent No. 217,612, 19 June, 1924.

    Google Scholar 

  6. Pratt, W. B., British Patent No. 233,370, 7 May, 1925.

    Google Scholar 

  7. Klein, P., and Szegvári, A./The Anode Rubber Company Ltd., British Patent No. 296,685, 4 September, 1928.

    Google Scholar 

  8. Madge, E. W., (1943) Transactions of the Institution of the Rubber Industry, 19 103.

    CAS  Google Scholar 

  9. Trumbull, H. L. and Dickson, J. B./The B. F. Goodrich Company, United States Patent No. 1,513,139, 28 October, 1924.

    Google Scholar 

  10. Murphy, E. A. and Madge, E. W./Dunlop Rubber Company Ltd., British Patent No. 445,541, 14 April, 1936.

    Google Scholar 

  11. Hunter, E. A., Segura, M. A., Small, A. B. and Miller, A. L./Esso Research and Engineering Company, United States Patent No. 2,944,038, 5 July, 1960.

    Google Scholar 

  12. Hunter, E. A., Small, A. B. and Miller, A. L./Esso Research and Engineering Company, United States Patent No. 3,062,767, 6 November, 1962.

    Google Scholar 

  13. Beerbower, A., Burton, G. W. and Malloy, P. L./Exxon Research and Engineering Company, British Patent No. 1,497,757, 12 January, 1978.

    Google Scholar 

  14. Le Suer, W. M. and Norman, G. R./The Lubrizol Corporation, United States Patent No. 3,172,892, 9 March, 1965.

    Google Scholar 

  15. Le Suer, W. M. and Norman, G. R./The Lubrizol Corporation, United States Patent No. 3,448,048, 3 June, 1969.

    Google Scholar 

  16. Vanderhoff, J. W., El-Aasser, M. S. and Ugelstad, J., United States Patent No. 4,177,177, 4 December, 1979.

    Google Scholar 

  17. Dieterich, D. (1981) Progress in Organic Coatings, 9 281.

    Article  CAS  Google Scholar 

  18. Wicks, Z. W. (1975) Progress in Organic Coatings, 3 73.

    Article  CAS  Google Scholar 

  19. Wicks, Z. W. (1981) Progress in Organic Coatings, 9 3.

    Article  CAS  Google Scholar 

  20. Vanderhoff, J. W., El-Aasser, M. S. and Hoffman, J. D., United States Patent No. 4,070,323, 24 January, 1978.

    Google Scholar 

  21. Rogers, T. H., Ryan, A. O. and Hecker, K. C. (1962) Rubber World, 147(1) 86.

    Google Scholar 

  22. Technical literature published by Burke-Palmason Chemical Company, Florida, undated.

    Google Scholar 

  23. Burke-Palmason Chemical Company (1987) Latexes Produced by Solvent Polymerization, in The Vanderbilt Latex Handbook, 3rd edn (ed. R. F. Mausser). R. T. Vanderbilt Company Inc., Norwalk, Connecticut, Chapter 4.

    Google Scholar 

  24. Miller, A. L. and Powers, K. W. (1959) Rubber Age, New York, 86 89.

    Google Scholar 

  25. Wales, M. (1962) Journal of Physical Chemistry, 66 1768.

    Article  CAS  Google Scholar 

  26. Preiss, D. M., Sawyer, W. M. and Simpson, W. C. (1963) Journal of Applied Polymer Science, 7 1803.

    Article  CAS  Google Scholar 

  27. Schmit, K. H. (1962) Rubber Age, New York, 91 437.

    Google Scholar 

  28. Gorton, A. D. T. (1970) Rubber Chemistry and Technology, 43, 1255.

    Article  CAS  Google Scholar 

  29. Smith, F. G. (1978) Reclaimed Rubber, in The Vanderbilt Rubber Handbook (ed. R. O. Babbit), R. T. Vanderbilt Company Inc., Norwalk, Connecticut, p. 319.

    Google Scholar 

  30. Patterson, P. D. (1932) Transactions of the Institution of the Rubber Industry, 8, 80.

    CAS  Google Scholar 

  31. Cubberley, R. H. (1954) Reclaim Rubber Dispersions, in The Vanderbilt Latex Handbook (ed. G. G. Winspear), R. T. Vanderbilt Company Inc., New York, p. 75.

    Google Scholar 

  32. Taub, B. (1983) Water Dispersible Urethanes, paper presented at Water-Borne and Higher-Solids Coatings Symposium, New Orleans, Louisiana, 1983.

    Google Scholar 

  33. Ney, E. A., Regos, N. and Labb, P. (1976) Journal of Elastomers and Plastics, 8, 210.

    Article  CAS  Google Scholar 

  34. . Guidelines for the Manufacture of Hypalon Latex, E. I. du Pont de Nemours, Wilmington, Delaware, undated.

    Google Scholar 

  35. Athey, R. D. (1991) Emulsion Polymer Technology, Marcel Dekker Inc., New York, p. 103.

    Google Scholar 

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© 1997 Springer Science+Business Media Dordrecht

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Blackley, D.C. (1997). Artificial latices. In: Polymer Latices. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5866-4_4

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  • DOI: https://doi.org/10.1007/978-94-011-5866-4_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6479-8

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