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Nuclear magnetic resonance

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Structure and Properties of Oriented Polymers

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Abstract

Nuclear magnetic resonance (NMR) spectroscopy may now be the most valuable tool for elucidation of molecular structure, order and dynamics. As far as macromolecules are concerned, NMR is divided into two major areas. From the chemist’s viewpoint, high resolution NMR provides detailed information about the chain microstructure in solution [I] and is an indispensable tool of polymer chemistry. From the materials scientist’s viewpoint, many of the macroscopic properties of polymers arise from the organization of macromolecules in the bulk. Thus solid-state techniques are needed to characterize chain alignment in oriented polymers [2]. In order to fully exploit the potential of solid-state NMR multidimensional techniques [3], which proved so powerful in liquidstate NMR, have to be employed. In the past, Progress in multidimensional solid-state NMR, has been hampered by technical and conceptual difficulties, which have now been overcome [4].

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References

  1. Bovey, F. A. (1988) Nuclear Magnetic Resonance Spectroscopy, Academic Press, San Diego CA.

    Google Scholar 

  2. McBrierty, V. J. and Packer, K. J. (1993) Nuclear Magnetic Resonance of Solid Polymers, Cambridge University Press, Cambridge.

    Book  Google Scholar 

  3. Ernst, R. R., Bodenhausen, G. and Wokaun, A. (1987) Principles of Nuclear Magnetic Resonance in One and Two Dimensions, Oxford University Press, Oxford.

    Google Scholar 

  4. Schmidt-Rohr, K. and Spiess, H. W. (1994) Multidimensional Solid-State NMR and Polymers, Academic Press, London.

    Google Scholar 

  5. Griesinger, C., Sørensen, O. W. and Ernst, R. R. (1989) J. Magn. Reson. 84, 14.

    CAS  Google Scholar 

  6. Spiess, H. W. (1982) in Developments in Oriented Polymers — 1, Ward, I. M. (ed.), Applied Science Publishers, London, p. 44.

    Google Scholar 

  7. Ward, I. M. and Klein, P. G. (1996) in Encyclopedia of NMR, Grant, D. M. and Harris, R. K. (eds), John Wiley, Chichester, p. 3693.

    Google Scholar 

  8. Harbison, G. S., Vogt, V.-D. and Spiess, H. W. (1987) J. Chem. Phys. 86, 1206.

    Article  CAS  Google Scholar 

  9. Hagemeyer, A., Schmidt-Rohr, K. and Spiess, H. W. (1989) Adv. Magn. Reson. 13, 85.

    Article  Google Scholar 

  10. Titman, J. J., Féaux de Lacroix, S. and Spiess, H. W. (1993) J. Chem. Phys. 98, 3816.

    Article  CAS  Google Scholar 

  11. Henrichs, P. M. (1987) Macromolecules 20, 2099.

    Article  CAS  Google Scholar 

  12. Schmidt-Rohr, K., Hehn, M., Schaefer, D. and Spiess, H. W. (1992) J. Chem. Phys. 97, 2247.

    Article  CAS  Google Scholar 

  13. Lewis, R. H., Long, H. W., Schmidt-Rohr, K. and Spiess, H. W. (1995) J. Magn. Reson. A115, 26.

    Google Scholar 

  14. Gan, Z. (1992) J. Amer. Chem. Soc. 114, 8307.

    Article  CAS  Google Scholar 

  15. Baltá-Calleja, F. J. and Vonk, C. G. (1989) X-ray Scattering of Synthetic Polymers, Elsevier, Amsterdam.

    Google Scholar 

  16. Fujara, F., Wefing, S. and Spiess, H. W. (1986) J. Chem. Phys. 84, 4579.

    Article  CAS  Google Scholar 

  17. Chmelka, B. F., Schmidt-Rohr, K. and Spiess, H. W. (1993) Macromolecules 26, 2282.

    Article  CAS  Google Scholar 

  18. Hentschel, R., Sillescu, H. and Spiess, H. W. (1981) Polymer 22, 1516.

    Article  CAS  Google Scholar 

  19. Boeffel, C. and Spiess, H. W. (1988) in Liquid-Crystalline Side Group Polymers, McArdle, C. D. (ed.), Blackie, London, p. 224.

    Google Scholar 

  20. Müller, K., Wassmer, K.-H. and Kothe, G. (1990) Adv. Polym. Sci., 95, 1.

    Article  Google Scholar 

  21. Spiess, H. W. (1993) Ber. Bunsenges. Phys. Chem. 97, 1294.

    Article  CAS  Google Scholar 

  22. Kroschwitz, J. I. (ed.) (1990) Concise Encyclopedia of Polymer Science and Technology, John Wiley, New York.

    Google Scholar 

  23. Long, S. D. and Ward, I. M. (1991) J. Appl. Polym. Sci. 42, 1911, 1921.

    Article  CAS  Google Scholar 

  24. Wilhelm, M., Féaux de Lacroix, S., Titman, J. J., et al. (1993) Acta Polym. 44, 279.

    Article  CAS  Google Scholar 

  25. Schaefer, D. J., Schadt, R. J., Gardner, R. J., et al. (1995) Macromolecules 28, 1152.

    Article  CAS  Google Scholar 

  26. Tang, P., Santos, R. A. and Harbison, G. S. (1989) Adv. Magn. Reson. 13, 225.

    Article  Google Scholar 

  27. McArdle, C. B. (ed.) (1988) Liquid-Crystalline Side Group Polymers, Blackie, London.

    Google Scholar 

  28. Kannan, R. M., Kornfield, J. A., Schwenk, N. and Boeffel, C. (1993) Macromolecules 26, 2050.

    Article  CAS  Google Scholar 

  29. Gleim, W. and Finkelmann, H. (1988) in Liquid-Crystalline Side Group Polymers, Blackie, London, p. 287.

    Google Scholar 

  30. Vogt, V.-D., Dettenmaier, M., Spiess, H. W. and Pietralla, M. (1990) Colloid Polym. Sci. 268, 22.

    Article  CAS  Google Scholar 

  31. Kulik, A. S. and Spiess, H. W. (1994) Macromol. Chem. Phys. 195, 1755.

    Article  CAS  Google Scholar 

  32. Ward, I. M. (1983) Mechanical Properties of Solid Polymers, John Wiley, Chichester.

    Google Scholar 

  33. Windle, A. H. (1982) in Developments in Oriented Polymers — 1, Ward, I. M. (ed.) Applied Science Publishers, London, p. 1

    Google Scholar 

  34. Kulik, A. S., Radloff, D. and Spiess, H. W. (1994) Macromolecules 27, 3111.

    Article  CAS  Google Scholar 

  35. McCrum, N. G., Read, B. E. and Williams, G. (1967) Anelastic and Dielectric Effects in Polymeric Solids, John Wiley, New York.

    Google Scholar 

  36. Kentgens A. P. M., de Jong A. F., dede Boer, E. and Veeman, W. S. (1985) Macromolecules, 18, 1045.

    Article  CAS  Google Scholar 

  37. Wilhelm, M. and Spiess, H. W. (1996) Macromolecules, 29, 1088.

    Article  CAS  Google Scholar 

  38. Hansen, M. T., Blümich, B., Boeffel, C. et al. (1992) Macromolecules, 25, 5542.

    Article  CAS  Google Scholar 

  39. Haward, R. N. (1973) The Physics of Glassy Polymers, Applied Science Publishers, London.

    Book  Google Scholar 

  40. Blümich, B. and Kuhn, W. (eds) (1992) Magnetic Resonance Microscopy: Methods and Applications in Materials Science, Agriculture and Biomedicine, VCH, Weinheim.

    Google Scholar 

  41. Günther, E., Blümich, B. and Spiess, H. W. (1992) Macromolecules 25, 3315.

    Article  Google Scholar 

  42. Fujiyama, M., Wakino, T. and Kawasaki (1988) J. Appl. Polym. Sci. 35, 29.

    Article  CAS  Google Scholar 

  43. Weigand, F. and Spiess, H. W. (1995) Macromolecules 28, 6361.

    Article  CAS  Google Scholar 

  44. Weigand, F., Wiesner, U. and Spiess, H. W. (1996) Adv. Mater. 8, 481.

    Article  CAS  Google Scholar 

  45. Ostroff, E. D. and Waugh, J. S. (1966) Phys. Rev. Lett. 16, 1097.

    Article  CAS  Google Scholar 

  46. Schaefer, J., Stejskal E. O., Perchak, D. et al. (1985) Macromolecules 18, 368.

    Article  CAS  Google Scholar 

  47. Cohen-Addad, J. P. (1993) in Progress in NMR Spectroscopy, Emsley, J. W., Feeney, J. and Sutcliffe, L. H. (eds), Pergamon, Oxford, Vol. 25, p. 1.

    Google Scholar 

  48. Collignon, J., Sillescu, H. and Spiess, H. W. (1981) Colloid Polym. Sci. 251, 220.

    Article  Google Scholar 

  49. Brereton, M. G. (1990) Macromolecules 23, 1119.

    Article  CAS  Google Scholar 

  50. Sotta, P. and Deloche, B. (1990) Macromolecules 23, 1999.

    Article  CAS  Google Scholar 

  51. Sotta, P., Fülber, C., Demco, D. E. et al. (1996) Macromolecules 29, 6222.

    Article  CAS  Google Scholar 

  52. Geen, H., Titman, J. J., Gottwald, J. and Spiess, H. W. (1994) Chem. Phys. Lett. 227, 79.

    Article  CAS  Google Scholar 

  53. Gottwald, J., Demco, D. E., Graf, R. and Spiess, H. W. (1995) Chem. Phys. Lett. 243, 314.

    Article  CAS  Google Scholar 

  54. Born, R. and Spiess, H. W. (1995) Macromolecules 28, 7785.

    Article  CAS  Google Scholar 

  55. Böhm, L. L., Enderle, H.-F. and Fleissner, M. (1994) Catalyst Design for Tailormade Olefins, Kodansha, Tokyo, p. 351.

    Google Scholar 

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Authors
  1. H. W. Spiess
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Editors and Affiliations

  1. IRC in Polymer Science and Technology, Universities of Leeds, Bradford and Durham, UK

    I. M. Ward

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© 1997 Springer Science+Business Media Dordrecht

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Spiess, H.W. (1997). Nuclear magnetic resonance. In: Ward, I.M. (eds) Structure and Properties of Oriented Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5844-2_5

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  • DOI: https://doi.org/10.1007/978-94-011-5844-2_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6469-9

  • Online ISBN: 978-94-011-5844-2

  • eBook Packages: Springer Book Archive

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