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Colloidally Processed Alumina — Ceria Stabilized Zirconia Composites

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Part of the book series: NATO ASI Series ((ASHT,volume 25))

Abstract

Alumina-zirconia composites, containing 20 wt% ZrO2 stabilized with 0, 3 and 6 mol% CeO2 were derived from two aqueous alumina suspensions (the pure α-alumina and the α-alumina/boehmite suspensions), aqueous, alkoxide derived zirconia sol and aqueous cerium-nitrate solution by mixing, milling, ultrasonically homogenizing, slowly evaporating, drying and sintering in air. The results are summarized as follows: (i) cerium-nitrate has considerable influence on the gelation of the composite suspensions, producing less homogeneous gel microstructures with lower densities. (ii) Sintered ceria stabilized zirconia alumina composites have lower densities, less homogeneous microstructures and broader size distribution of the alumina grains and zirconia particles than unstabilized zirconia alumina composites. (iii) The stability of tetragonal zirconia increases with increasing the ceria content.

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References

  1. Claussen, N. (1976) Fracture toughness of A12O3 with an unstabilized ZrO2 dispersed phase, J.Am.Ceram.Soc. 59, 49–51.

    Article  CAS  Google Scholar 

  2. Wang, J. and Stevens, R. (1989) Review-Zirconia-toughened alumina (ZTA) ceramics, J Mater.Sci. 24, 3421–3440.

    Article  CAS  Google Scholar 

  3. Bleier, A., Becher, P.F., Alexander, K.B. and Westmoreland, C.G. (1992) Effect of aqueous processing conditions on the microstructure and transformation behavior in Al2O3-ZrO2(CeO2) composites, J.Am.Ceram. Soc. 75, 2649–2658.

    Article  CAS  Google Scholar 

  4. Claussen, N. and Ruhle, M. (1982) Design of transformation toughened ceramics, in A.H. Heuer and L.W. Hobbs (eds.), Advances in Ceramics Vol 3, Science and Technology of Zirconia I, Am.Ceram.Soc, Westerville, OH, pp. 137–163.

    Google Scholar 

  5. Tsukuma, K. and Shimada, M. (1985) Strength, fracture toughness and vickers hardness of CeO2-stabilized tetragonal ZrO2 polycrystals (Ce-TZP), J.Mater.Sci. 20, 1178–1184.

    Article  CAS  Google Scholar 

  6. Becher, P.F. and Swain, M.V. (1992) Grain-size dependent transformation behavior in polycrystalline tetragonal zirconia, J.Am.Ceram.Soc. 75, 493–502.

    Google Scholar 

  7. Messing, G.L. and Kumagai, M. (1989) Low-temperature sintering of sol-gel derived ZrO2-toughened Al2O3 composites, J.Am.Ceram.Soc. 72, 40–44.

    Google Scholar 

  8. Srdic, V. and Radonjic, L. (1995) Seeded sol-gel derived alumina-zirconia composites, Ceram.Inter. 21, 5–11.

    Article  CAS  Google Scholar 

  9. Toraya, H. Yoshimura, M. and Somiya, S. (1984) Calibration curve for quantitative analysis of the monoclinic-tetragonal ZrO2 system by X-ray diffraction, J.Am.Ceram.Soc. 67, C119–121.

    CAS  Google Scholar 

  10. Wurst, J.C. and Nelson, J.A. (1972) Linear-intercept technique for measuring grain size in two-phase polycrystalline ceramics, J.Am.Ceram. Soc. 55,109.

    Article  CAS  Google Scholar 

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© 1997 Springer Science+Business Media Dordrecht

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Srdic, V.V., Radonjic, L. (1997). Colloidally Processed Alumina — Ceria Stabilized Zirconia Composites. In: Babini, G.N., Haviar, M., Šajgalík, P. (eds) Engineering Ceramics ’96: Higher Reliability through Processing. NATO ASI Series, vol 25. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5798-8_5

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  • DOI: https://doi.org/10.1007/978-94-011-5798-8_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6448-4

  • Online ISBN: 978-94-011-5798-8

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