Skip to main content
SpringerLink
Log in
Book cover

Engineering Ceramics ’96: Higher Reliability through Processing pp 121–129Cite as

Covalent Ceramics from Organosilicon Polymers

  • Chapter

  • 256 Accesses

Part of the book series: NATO ASI Series ((ASHT,volume 25))

Abstract

It is the purpose of this paper to demonstrate how ceramic products like monoliths or coatings can be prepared by using organosilicon polymers. Micro- or nanostructures of Si3N4/SiC composite materials can be designed by the synthesis and the chemical modification of the starting polymers. Depending on the select polymer the crystallite size of Si3N4 and SiC can be varied from the range of l μm to sizes below 50 nm which provides a completely powder-free process for the preparation of nanocrystalline ceramics.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD   54.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Popper, P. (1967) New electrical ceramics and inorganic polymers, Brit. Ceram. Res. Assn. Special Publ. 57,1

    Google Scholar 

  2. Verbeek, W. (1973) German Patent 2218960

    Google Scholar 

  3. Verbeek, W., Winter, G. (1974) German Patent 2236078

    Google Scholar 

  4. Yajima, S., Hayashi, J., Omori, M., Okamura, K. (1976) Development of a silicon carbide fibre with high tensile strength, Nature 261,683

    Article  CAS  Google Scholar 

  5. Rice, R. W. (1983) Ceramics from polymer pyrolysis, opportunities and needs-a materials perspective, Am. Ceram. Soc. Bull. 62, 889

    CAS  Google Scholar 

  6. Peuckert, M., Vaahs, T., Brück, M. (1990) Ceramics from organoelement polymers, Adv. Mater. 2,398

    Article  CAS  Google Scholar 

  7. Bill, J., Aldinger, F. (1995) Precursor-derived covalent ceramics, Adv. Mater. 7, 776

    Article  Google Scholar 

  8. Bill, J., Kienzle, A., Riedel, R., Aldinger, F. (1995), Herstellung keramischer Materialien durch Pyrolyse von hochvernetzten polymeren Carbodiimiden, German Patent Appl. P44 30 817.5-45

    Google Scholar 

  9. Kienzle, A., Bill, J., Aldinger, F., Riedel, R. (1995) Nanosized Si-C-N powder by pyrolysis of highly crosslinked silylcarbodiimide, Nanostructured Materials 6,349

    Article  CAS  Google Scholar 

  10. Riedel, R., Greiner, A., Miehe, G., Dressler, W., Fueß, H., Bill, J., Aldinger, F., (1996), to be published in Ang. Chem.

    Google Scholar 

  11. Polyhydridomethylsilazane NCP 200, Chisso Corp., Tokyo, Japan

    Google Scholar 

  12. Polyvinylsilazane VT50, Hoechst AG, Germany

    Google Scholar 

  13. Bill, J., Frieß, M., Aldinger, F., Riedel, R. (1994) Doped silicon carbonitride: synthesis, characterization and properties, Mat. Res. Soc. Symp. Proc. 346, 605

    Article  CAS  Google Scholar 

  14. Bill, J., Kienzle, A., Sasaki, M., R. Riedel, R. and Aldinger, F. (1995) Novel routes for the synthesis of materials in the quaternary system Si-B-C-N and their characterization, in P. Vincenzini (ed.), Advances in Science and Technology 3B, Ceramics: Charting the Future, Techna Srl, p. 1291

    Google Scholar 

  15. Jalowiecki, A., Bill, J., Mayer, J., Aldinger, F.(1995) Monolithic nanosized Si3N4/SiC composites prepared by in-situ crystallization of amorphous SiCN(B,P) ceramics, Proc. 4th European Conference on Advanced Materials, Padua/Venice, Italy, 25-28 September 1995, Symposium G-Special and Functional Materials, Associatione Italiana di Metallurgia, p. 265

    Google Scholar 

  16. Riedel, R., Passing, G., Schönfelder, H., Brook, R. J. (1992) Synthesis of dense silicon based ceramics at low temperatures, Nature 355, 714

    Article  CAS  Google Scholar 

  17. Seitz, J., Bill, J. (1996) Preparation of compact polysilazane-derived Si/C/N-Ceramics by hot-pressing, J. Mat. Sci. Lett. 15, 391

    CAS  Google Scholar 

  18. Bill, J., Riedel, R., Aldinger, F. (1995) Hybride processing of silicon-based polymers to composite-ceramics, in A. Bellosi (ed.), Fourth Euro Ceramics, Basic Science-Trends in Emerging Materials and Appliations, Gruppo Editoriale Faenza Editrice S. p. A., Vol. 4, p. 125

    Google Scholar 

  19. Krenkel, W., Gern, F. H. (1993) Microstructure and characteristics of CMC manufactured via the liquid phase route, Ninth International Conference on Composite Materials ICCM-9, Madrid, Spain, 12–16 July

    Google Scholar 

  20. Haug, R., Heimann, D., Bill, J., Aldinger, F. (1996), Keramische Oxidationsschutzschichten aus polymeren Vorstufen, in G. Ziegler (ed.), Verbundwerkstoffe und Werkstoffverbunde, DGM Informationsgesellschaft Verlag, 429

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Max-Planck-Institut für Metallforschung Institut für Nichtmetallische Anorganische Materialien, der Universität Stuttgart, Heisenbergstr. 5, 70569, Stuttgart, Germany

    J. Bill

Authors
  1. J. Bill
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Research Institute for Ceramics Technology, National Research Council, Faenza, Italy

    Gian Nicola Babini

  2. Institute of Inorganic Chemistry, Slovak Academy of Sciences, Bratislava, Slovakia

    Miroslav Haviar  & Pavol Šajgalík  & 

Rights and permissions

Reprints and permissions

Copyright information

© 1997 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Bill, J. (1997). Covalent Ceramics from Organosilicon Polymers. In: Babini, G.N., Haviar, M., Šajgalík, P. (eds) Engineering Ceramics ’96: Higher Reliability through Processing. NATO ASI Series, vol 25. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5798-8_10

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-5798-8_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6448-4

  • Online ISBN: 978-94-011-5798-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation