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GC/MS Investigation of Ethyl S-2-diisopropyl Aminoethyl Methylphosphonothiolate (VX) Age Decomposition Products

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Analytical Chemistry Associated with the Destruction of Chemical Weapons

Part of the book series: NATO ASI Series ((ASDT,volume 13))

Abstract

Sample of VX stored for a long time in glass container was investigated using GC/MS system. A variety of age decomposition products including O-alkyl and N,N-diisopropylamino- substituted thiophosphonic esters and acids as well as phosphonic anhydrides were identified. Diazomethane methylation was used to obtain derivatives convenient to GC process. Retention parameters and EI-MS spectra were obtained and presented in the paper.

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© 1997 Springer Science+Business Media Dordrecht

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Sliwakowski, M. (1997). GC/MS Investigation of Ethyl S-2-diisopropyl Aminoethyl Methylphosphonothiolate (VX) Age Decomposition Products. In: Heyl, M., McGuire, R. (eds) Analytical Chemistry Associated with the Destruction of Chemical Weapons. NATO ASI Series, vol 13. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5600-4_11

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  • DOI: https://doi.org/10.1007/978-94-011-5600-4_11

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6362-3

  • Online ISBN: 978-94-011-5600-4

  • eBook Packages: Springer Book Archive

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