Abstract
Hard sphere colloidal suspensions composed of polymer particles in a non-aqueous solvent are studied using light scattering techniques. Single particle motions in the metastable fluid are obtained from measurement of the incoherent intermediate scattering function. The emergence of crystalline order is observed by monitoring the development of the main Bragg reflection
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
Kelton, K.F. (1991), Crystal Nucleation in Liquids and Glasses, Solid State Phys. 45, 75–177
Frenkel, J. (1946) Kinetic Theory ofLiquids, Oxford University Press, Oxford.
Pusey, P.N. (1991) Colloidal Suspensions, in J.P. Hansen, D. Levesque and J. Zinn-Justin (eds.), Liquids, Freezing and the Glass Transition, North-Holland, Amsterdam, pp. 765–942.
van Megen, W. (1995) Crystallisation and the Glass Transition in Suspensions of Hard Colloidal Spheres, Transport Theory and Stat. Phys 24, 1017 - 1051.
SchAtzel, K and Ackerson, B.J. (1993) Density Fluctuations during crystallization of colloids, Phys. Rev. E 48, 3766 - 3777
Harland, J.L., Henderson, S.I., Underwood, S.M. and van Megen, W. (1995) Observation of Accelerated Nucleation in Dense Colloidal Fluids of Hard Sphere Particles, Phys. Rev. Letters 75, 3572–3575.
Aastuen, D.J.W., Cleric, N.A., Cotter, L.K. and Ackerson, B.J. (1986) Nucleation and Growth of Colloidal Crystals, Phys. Rev. Letters 57, 1733–1736.
Wùrth, M., Schwarz, J., Culis, F., Leiderer, P. and Palberg, T. (1995) Growth kinetics of Body Centered Cubic Colloidal Crystals, Phys. Rev. E 52, 6415–6423.
van Megen, W. and Underwood, S.M., (1989) Tracer diffusion in concentrated colloidal dispersions. III. Mean squared displacements and self-diffusion coefficients, J. Chem. Phys91, 552–559.
Pusey, P.N. and van Megen, W, (1986) Phase behaviour in concentrated suspensions of nearly hard colloidal spheres, Nature (London) 320, 340–342.
van Megen, W. and Underwood, S.M. (1993) Change in crystallisation mechanism at the glass transition of colloidal spheres, Nature (London) 362, 616–617.
Underwood, S.M., Taylor, J.R. and van Megen, W. (1994) Sterically stabilised colloidal particles as model hard spheres, Langmuir 10, 3550–3554.
Underwood, S.M. and van Megen, W, (1996) Refractive Index Variation in Nonaqueous Sterically Stabilized Copolymer Particles, Colloid Polym. Sc (to appear)
Paulin, S.E. and Ackerson, B.J. (1990) Observation of a Phase Transition in the Sedimentation Velocity of Hard Spheres, Phys. Rev. Letters 64, 2663–2666.
Hoover, W.G. and Ree, F.H. 1968 Melting Transition and Communal Entropy for Hard Spheres, J. Chem. Phys. 49, 3609–3617
van Megen, W. and Underwood, S.M. (1988) Tracer diffusion in concentrated colloidal dispersions. II. Non-Gaussian effects, J. Chem. Phys 88, 7841–7846
Segré, P.N., van Megen, W., Pusey, P.N., SchAtzel, K. and Peters, W. (1995) Two-color dynamic light scattering J. Mod. Optics 42, 1929–1952.
Pusey, P.N. and van Megen, W. (1989) Dynamic light scattering by non-ergodic media, Physica A 157, 705–741.
van Duijneveldt, J.S. and Lekkerkerker, H.N.W. (1995) Crystallization in Colloidal Suspensions, in van der Eerden, J.P. and Bruinsma, O.D.L (eds.) Science and Technology ofCrystal Growth, Kluwer Academic, Dordrecht
He, Y., Ackerson, B.J., van Megen, W., Underwood, S.M. and SchAtzel, K (1996) Dynamics of Crystallization in Hard-Sphere Suspensions, Phys. Rev. E 54, 1–12.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Van Megen, W. et al. (1997). Particle Diffusion and Crystallisation in Suspensions of Hard Spheres. In: Pike, E.R., Abbiss, J.B. (eds) Light Scattering and Photon Correlation Spectroscopy. NATO ASI Series, vol 40. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5586-1_17
Download citation
DOI: https://doi.org/10.1007/978-94-011-5586-1_17
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6355-5
Online ISBN: 978-94-011-5586-1
eBook Packages: Springer Book Archive