Abstract
Hartree-Fock [1] and density functional [2, 3] theories offer one-electron pictures of molecular electronic structure. The former has been the standard by which the concept of electron correlation has been defined [4] and its errors therefore are known as correlation effects. Density functional theories provide a variety of exchange and correlation approximations that can be incorporated into orbital eigenvalue equations. The widespread application of methods based on the Kohn-Sham equations [5] attests to the appeal of the one-electron paradigm.
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Ortiz, J.V., Zakrzewski, V.G., Dolgounitcheva, O. (1997). One-Electron Pictures of Electronic Structure: Propagator Calculations on Photoelectron Spectra of Aromatic Molecules. In: Calais, JL., Kryachko, E. (eds) Conceptual Perspectives in Quantum Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5572-4_13
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