Abstract
A reactive surfactant is an amphiphilic molecule with an additional functionality that provides it with chemical reactivity. An important class of reactive surfactants are those that act in radical polymerizations either as comonomer (SURFMERS), or as initiator (INISURFS), or as chain transfer agent (TRANSURFS) [1,2].
Keywords
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Kusters, J.M.H. and German, A.L. (1990) Emulsions polymerization with INISURFS: emulsifiers with initiating properties, 33rd IUPAC International Symposium on Macromolecules, July 8–13, 1990Montreal Book of Abstracts, Session 2.5.6
Guyot, A. and Tauer, K. (1994) Reactive surfactants in emulsion polymerization, Adv.Polym.Sci. 111, 43–65
Dickstein, J. (1986) Relationship of chemical structure to applications of specialty monomers,.Polym.Prepr. 27, 427–428
Hyde, A.J. and Robb, D.J.M. (1963) The apparent molecular weights of polymerized soap micelles, J.Amer.Chem.Soc. 67, 2089–2092
Kammer, U. and Elias, H.-G. (1972) Zur Assoziation von Seifen V. Synthese und Polymerisation von Seifen aus N-Mathacryloyl-1 1-alkylamino-undecansäure-Typs, Kolloid-Z. u. Z. Polymere 250, 344–351
Hamid, S. and Sherrington D. (1986) Polymerized micelles: fact or fancyJ.Chem.Soc., Chem.Commun. 12, 936–938
Law, T.K., Florence, A.T. and Whateley, T.L. (1986) Stabilization of emulsions by interfacial polymerisation of poloxamer surfactants derivatives, Coll.Polym.Sci. 262, 167–170
Egorov, V.V. and Subov, V.P. (1987) Radical polymerisation in aggregates of ionic surface active monomers in water, Usp.Chim. 56, 2076–2097
Nagai, K. and Elias, H.-G. (1987) Polymerizable amphiphiles, 3 Polymerization of micellized 1–0–3-(4vinylphenyl)propyl-b-D-glucopyranose, Makromol.Chem. 188, 1095–1127
Torstensson, M. and Hult, A. (1992) Surface modification of polymers using surfactant monomers, Polym.Bull. 29, 549–556
Cochin, D., Zana, R. and Candau, F. (1992) Photopolymerization of micelle-forming monomers. 2. Kinetic study and mechanism, Macromol. 26, 5765–5771
Anton, P., Köberle, P. and Laschewsky, A. (1993) Recent developments in the field of micellar polymers, Makromol.Chem. 194, 1–27
Nagai, K. (1994) Polymerization of surface active monomers and applications, Macromol.Symp. 84, 29–36
Pucci, B., Polidori, A., Rakotomanomana, N., Chorro, M., and Pavia, A.A. (1993) Synthèse de Glycolipides Polymérisables Dérivés du Tris(hydroxyméthyl)aminométhane: Préparation de Micelles Polymérisées, Tetrahedron Lett. 34, 4185–4188
Tauer, K. (1995) Emulsion polymerization with reactive surfactants, Polymer News 20, 342–347
Tauer, K., Goebel, K.-H., Kosmella, S., Neelsen, J., and Stähler, K. (1988) Neuere Entwicklungen bei der Synthese von Polymerdispersionen, Plaste Kautschuk 35, 373–378
Tauer, K. (1994) Block copolymers prepared by emulsion polymerization with poly(ethylene oxide)azo-initiators, Polym.Adv.Technol. 6, 435–440
Liu, L-J. and Krieger, I.M. (1977) Control of surface charge on polymer latex particles in P. Becher and M.N. Yudenfreund (eds.), Emulsions,Latices, and Dispersions, Marcel Dekker, Inc., New York and Basel, pp. 41–69
Bistline, R.G., Stirton, A.J., Weil, J.K., and Port, W.S. (1956) Synthetic detergents from animal fats. VI. Polymerizable esters of alpha-sulfonated fatty acids, JAmer.Oil Chem.Soc. 33, 44–45
Paleos, C.M., Stassinopoulou, C.I., and Malliaris, A. (1983) Comparative studies between monomeric and polymeric sodium I0-undecenoate, J.Phys.Chem. 87, 251–254
Richtering, W., Löffler, R., and Burchard, W. (1992) Comparison between monomeric and polymeric surfactants. 2. Properties of polysurfactants in aqueous and nonaqueous solution, Macromol. 25, 3642–3650
Boyer, B., Lamaty, G., Leydet, A., Roque, J.-P., and Sama P. (1992) Polymerized surfactants. I. The influence of polymerization on the solubilization of hydrophobic substrates by ionic surfactants, New J.Chem. 16, 883–886
Guyot, A., Asua, J.M., Sherrington, D.C., German, A.L., and Tauer, K. (1994/1995) Results obtained within a European network, Reactive surfactants in heterophasc polymerization for high performance polymers, CT 93–0159 (DG DSCS)
Ferguson, P., Sherrington, D.C., and Gough, A. (1993) Preparation, characterization and use in emulsion polymerization of acrylated alkyl ethoxylate surface-active monomers, Polymer 34, 3281–3292
Ivanchev, S.S., Pavljuchenko, V.N., and Byrdina, N.A. (1987) Elementary reactions of the emulsion polymerization of styrene with the localization of radical formation acts at the interface, JPolym.Sci.: Part A: Polym.Chem., 25, 47–62
Kusters, J.H.M. (1994) INISURFS: surface-active initiators, PhD thesis Technical University Eindhoven, The Netherlands
Kusters, J.M.H., Napper, D.H., Gilbert, R.G., and German, A.L. (1992) Kinetics and particle growth in emulsion polymerization systems with surface-active initiators, Macromol. 25, 7043–7050
Tauer, K. and Kosmella, S. (1993) Synthesis, characterization and application of surface active initiators, Polym.Intern. 30, 253–258
Yasuda, Y., Rindo, K., Tsushima, R., and Aoki, S. (1993) Spontaneous polymerization of amphiphilic vinyl monomers 2. Spontaneous polymerization of sodium alkyl 2-hydroxy-3-methacryloyloxypropyl phosphates in micellar and inverse micellar systems, Makromol.Chem. 194, 485–491
Yasuda, Y., Rindo, K., Tsushima, R., and Aoki, S. (1993) Spontaneous polymerization of amphiphilic vinyl polymers, 4. Spontaneous polymerization of methacrylic derivatives of quarternary ammonium bromides with a long alkyl chain, Makromol.Chem. 194, 1893–1899
Aoki, S. (1995) Spontaneous polymerization in micelles as reaction loci, J.Synth.Org.Chem.Jpn. 53, 423–431
Asahara, T., Seno, M., Shiraishi, S., and Arita, Y. (1970) The polymerization of vinyl monomers in the presence of surface active agents. I. The polymerization of methyl methacrylate, Bull.Chem.Soc,Jpn. 43, 3895–3898
Yasuda, Y., Rindo, K., and Aoki, S. (1992) Spontaneous polymerization of amphiphilic vinyl monomers. 1. Spontaneous polymerization of sodium dodecyl 2-hydroxy-3-methacryloyloxypropyl phosphate, Makromol.Chem. 193, 2875–2882
Glatzhofer, D.T., Cho, G., Lai, C.L., O’Rear, E.A., and Fung, B.M. (1993) Polymerization and copolymerization of sodium l0-undecen-1-yl sulfate in micelles and in admicelles on the surface of alumina, Langmuir 9, 2949–2954
Strauss, U.P. and Jackson, E.G. (1951) Polysoaps. I. Viscosity and solubilization studies on an ndodecyl bromide addition compound of poly-2-vinylpyridine, J.Polym.Sci. VI, 649–659
Greene, B.W., Sheetz, D.P., and Filer, T.D. (1970) In situ polymerization of surface-active agents on latex particles I. Preparation and characterization of styrene/butadiene latexes, J.Coll.Interf.Sci. 32, 9095
Green, B.W. and Sheetz, D.P. (1970) In situ polymerization of surface-active agents on latex particles II. The mechanical stability of styrene/butadiene latexes, J.Coll.Interf.Sci. 32, 96–100
Greenley, R.Z. (1989) Free radical copolymerization reactivity ratios, in J. Brandrup and E.H. Immergut (eds.), Polymer Handbook, John Wiley & Sons, New York, pp. II/153-II/266
Goebel, K.-H. and Stähler, K. (1994) Emulsion copolymerization of styrene with monomeric emulsifiers, Polym.Adv.Technol. 6, 452–454
Schoonbrood, H.A.S., and Asua, J.M. (1996), to be published.
Goebel, K.-H., and Tauer, K. (1990), unpublished results.
Odian, G. (1991) Principles of Polymerization, J. Wiley & Sons, Inc., New York
Tsaur, S-L. and Fitch, R.M. (1987) Preparation and properties of polystyrene model colloids I. Preparation of surface-active monomer and model colloids derived therefrom,.I Coll.Interf.Sci. 115, 450–462
Urquiola, M.B., Dimonie, V.L., Sudol, E.D., and El-Aasser, M.S. (1992) Emulsion polymerization of vinyl acetate using a polymerizable surfactant. 1. Kinetic studies, JPolym.Sci.: Part A: Polym.Chem. 30, 2619–2629
Urquiola, M.B., Dimonie, V.L., Sudol, E.D., and El-Aasser, M.S. (1992) Emulsion polymerization of vinyl acetate using a polymerizable surfactant. II. Polymerization mechanism, JPolym.Chem.:Part A: Polym.Chem. 30, 2631–2644
Urquiola, M.B., Sudol, E.D., Dimonie, V.L., and El-Aasser, M.S. (1993) Emulsion polymerization of vinyl acetate using a polymerizable surfactant. III. Mathematical model, JPolym.Chem.: Part A. Polym.Chem. 31, 1403–1415
Wagner, R., Richter, L., Weiland, D., Reiners, J., and Weißmüller, J. (1996) Silicon modified carbohydrate surfactants (II). Siloxanoyl containing branched structures, Appl.Organaomet.Chem. in press
Tauer, K. (1995) unpublished results
Karaborni, S., Esselink, K., Hilbers, P.A.J., Smit, B., Karthäuser, J., van Os, N.M., and Zana, R. (1994) Simulating the self-assembly of gemini (dimeric) surfactants, Science 266, 254–256
Pavljuchenko, V.N., Lesnikova, N.N., Byrdina, N.A., and Ivanchev, S.S. (1995) Kinetic pecularities of emulsion polymerization of styrene with a surface-active initiator (russ.), Dokl.Akad.Nauk 342, 70–72
Tauer, K. and Sedlak, M. (1995), to be published.
Fifield, C.C. (1985) Phd thesis University of Connecticut, University Microfilms International 5869 (1992), Ann Arbor, Michigan USA
Vidal, F., Guillot, J., and Guyot, A. (1995) Surfactants with transfer agent properties (transurfs) in styrene emulsion polymerization, Colloid.Polym.Sci. 273, 999–1007
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1997 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
Tauer, K. (1997). Reactive Surfactants. In: Asua, J.M. (eds) Polymeric Dispersions: Principles and Applications. NATO ASI Series, vol 335. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5512-0_30
Download citation
DOI: https://doi.org/10.1007/978-94-011-5512-0_30
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6321-0
Online ISBN: 978-94-011-5512-0
eBook Packages: Springer Book Archive