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Coordination Defects Formation Model for Reversible Photostructural Transformations in Amorphous As2S(Se)3

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Physics and Applications of Non-Crystalline Semiconductors in Optoelectronics

Part of the book series: NATO ASI Series ((ASHT,volume 36))

Abstract

Photoinduced destruction-polymerization transformations in the amorphous a-As2S(Se)3 associated with coordination defects formation processes have been studied by differential IR Fourier spectroscopy method in the 400-100 cm-1 region. All topological variants of these processes statistically possible in the investigated samples have been taken into account for physical consideration of the real microstructural transformations. The model for the both irreversible and reversible photoinduced effects has been developed at the basis of coordination defects concept.

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References

  1. DeNeufville, J.P., Moss, S.C., and Ovshinsky, S.R. (1974) Photostructural trans-formations in amorphous As2Se3and As2S3 films, J. Non-Cryst. Solids 13, 191–223.

    Article  ADS  Google Scholar 

  2. Tanaka, K. (1974) Evidence for reversible photostructural change in local order of amorphous As2S3 film, Solid State Commun. 15, 1521–1524.

    Article  ADS  Google Scholar 

  3. Amorphous Semiconductors Ed. Brodsky, M. (1982) Mir, Moscow.

    Google Scholar 

  4. Felts, A. (1986), Amorphous and vitreous inorganic solids, Mir, Moscow.

    Google Scholar 

  5. Elliott, S.R. (1986) A unified model for reversible photostructural effects in chalcogenide glasses, J. Non-Cryst Solids 81, 71–98.

    Article  ADS  Google Scholar 

  6. Tanaka, K. (1983) Mechanism of photodarkening in amorphous chalcogenides, J. Non-Cryst. Solids 59/60, 925–928.

    Google Scholar 

  7. Frumar, M., Firth, A.P., and Owen, AE. (1983) A model for photostructural changes in the amorphous As-S system, J. Non-Cryst. Solids 59-60, 921–924.

    Google Scholar 

  8. Shpotyuk, O.I. (1994) Reversible radiation effects in vitreous As2S3. 2. Mechanism of structural transformations, Phys. Stat. Sol. A 145, 69–75.

    Article  ADS  Google Scholar 

  9. Komelyuk, V.N., Savytsky, I.V., Shpotyuk, O.I., and Yaskovets, II. (1989) Mechanism of reversible photoinduced effects in As2S3 thin films, Fiz. Tverd. Tela 31, 311–313.

    Google Scholar 

  10. Lowe, A.J., Elliott, S.R., and Greaves, G.N. (1986) Extended X-ray absorption fine-structure spectroscopy study of photostructural changes in amorphous arsenic chalcogenides, Phil. Mag. B. 54, 483–490.

    Article  Google Scholar 

  11. Yang, C.Y., Paesler, M.A, and Sayers, D.E. (1987) Measurement of local structural configurations associated with reversible photostructural changes in arsenic trisulphide films, Phys. Rev. B. 36, 9160–9167.

    Article  ADS  Google Scholar 

  12. Weiqing, Z., Paesler, M.A, and Sayers, D.E. (1992) Structure and photoinduced structural changes in nonstoichiometric a-AsxS1-x: A study by x-ray-absorption fine structure, Phys. Rev. B. 46, 3817–3825.

    Article  ADS  Google Scholar 

  13. Mott, N., and Davis, E. (1974) Electronic processes in non-crystalline materials, Mir, Moscow.

    Google Scholar 

  14. Marshall, J.M., and Owen, A.E. (1971) Drift mobility studies in vitreous arsenic triselenide, Phil. Mag. 24, 1281–1305.

    Article  ADS  Google Scholar 

  15. Bishop, S.G., Strom, U., and Taylor, P.C. (1976) Optically induced localized paramagnetic states in chalcogenide glasses, Solid State Commun 18, 573–576.

    Article  ADS  Google Scholar 

  16. Anderson, P.W. (1975) Model for the electronic structure of amorphous semiconductors, Phys. Rev. Lett. 34, 953–955.

    Article  ADS  Google Scholar 

  17. Baranovsky, S.D., and Karpov, V.G. (1987) Localized electronic states in vitreous semiconductors, Phys. I Techn. Poluprov 21, 3–17.

    Google Scholar 

  18. Mott, N.F.,. Davis, E.A, and Street, R.A.(1975) States in the gap and recombination in amorphous semiconductors,” Phil. Mag. 32, 961–996.

    Article  ADS  Google Scholar 

  19. Kastner, M.A., Adler, D, and Fritzshe, H. (1976) Valence-alternation model for localized gap states in lone-pair semiconductors, Phys. Rev. Lett. 37, 1504–1507.

    Article  ADS  Google Scholar 

  20. Kastner, M., (1978) Defect chemistry and states in the gap of lone-pair semiconductors, J. Non-Cryst. Solids 31, 223–240.

    Article  ADS  Google Scholar 

  21. Street, R.A. (1977) Non-radiative recombination in chalcogenide glasses, Solid State Commun. 24, 363–365.

    Article  ADS  Google Scholar 

  22. Street, R.A. (1978) Recombination in amorphous semiconductors, Phys. Rev. B 17, 3984–3995.

    Article  ADS  Google Scholar 

  23. Klinger, M.I. (1983) Model of electronic processes in glassy semiconductors: correlation with structural features, Solid State Commun. 45, 949–953.

    Article  ADS  Google Scholar 

  24. Klinger, M.I. (1988) Glassy disordered systems: topology, atomic dynamics and localised electron states, Phys. Rep. 165, 275–397.

    Article  ADS  Google Scholar 

  25. Vardeny, Z., and Tauc, J. (1985) Method for direct determination of the effective correlation energy of defects in semiconductors: Optical modulation spectroscopy of dangling bonds, Phys. Rev. Lett. 54, 1844–1847.

    Article  ADS  Google Scholar 

  26. Zakis, Yu.R. (1984) Defects in vitreous state of substance, Zinatne, Riga.

    Google Scholar 

  27. Solin, S.A., and Papatheodorou, G.N. (1977) Irreversible thermostructural transformations in amorphous As2S3 films: A light scattering study, Phys. Rev. B. 15, 2084–2090.

    Article  ADS  Google Scholar 

  28. Strom, U., and Martin, T.P. (1979) Photo-induced changes in the infrared vibrational spectrum of evaporated As2S3, Solid State Commun. 29, 527–530.

    Article  ADS  Google Scholar 

  29. Mori, T., Matsuishi, K., and Arai, T. (1984) Vibrational properties and network topology of amorphous As-S systems, J. Non-Cryst. Solids 65, 269–283.

    Article  ADS  Google Scholar 

  30. Scott, D.W., McCullough, J.P., and Kruse, F.H. (1964) Vibrational assignment and force constants of S8 from a normal-coordinate treatment, J. Molec. Spectroscopy 13, 313–320.

    Article  ADS  Google Scholar 

  31. Fritzsche, H. (1993) The origin of reversible and irreversible photostructural changes in chalcogenide glasses, Philosophical Magazine B 68, 561–572.

    Article  Google Scholar 

  32. Shimakawa, K., Inami, S., and Kato, T. (1992) Origin of photoinduced metastable defects in amorphous chalcogenides, Phys. Rev. B. 46, 10062–10069.

    Article  ADS  Google Scholar 

  33. Shpotyuk, O.I. (1994) On the mechanism of reversible photostructural transformations in amorphous arsenic triselenide, Zh. Prikl. Spektroskopii 61, 143–148.

    Google Scholar 

  34. Rao, K.J., and Mohan, R. (1981) Chemical bond approach to determining conductivity band gaps in amorphous chalcogenides and pnictides, Solid State Commun. 39, 1065–1068.

    Article  ADS  Google Scholar 

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© 1997 Springer Science+Business Media Dordrecht

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Shpotyuk, O.I. (1997). Coordination Defects Formation Model for Reversible Photostructural Transformations in Amorphous As2S(Se)3 . In: Andriesh, A., Bertolotti, M. (eds) Physics and Applications of Non-Crystalline Semiconductors in Optoelectronics. NATO ASI Series, vol 36. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5496-3_19

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  • DOI: https://doi.org/10.1007/978-94-011-5496-3_19

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6313-5

  • Online ISBN: 978-94-011-5496-3

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