Abstract
Supramolecular structures possessing useful functionalities have been paid to much attention by many investigators. My group have been interested in modified electrode interfaces which play not only molecular recognition to specific substrate but also electron transfer or charge transfer between electrode and specific substrate. Focussing my group’s recent results, I would present 1) selective electroorganic reactions on poly (acrylic acid) thin layer coated graphite felt (PAA-GF) electrode in which mediator(s), enzyme(s) and co-factor(s) are immobilized, and 2) enzyme sensors based on alternate deposition of avidin and biotinylated enzyme on electrode surface.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Osa, T., Kashiwagi, Y., Bobbitt, J.M., and Ma, Z.: Electroorganic Synthesis on Catalyst Coated Electrodes, in R. D. Little and N. L. Weinberg (eds.), Electroorganic Synthesis, Marcel Dekker, Inc., New York, 1991, pp. 343–354.
Osa, T., Akiba, U., Segawa, I., and Bobbitt, J.M.: Electrocatalytic Oxidation of Nerol with Nitroxyl Radical Covalently Immobilized to Poly (acrylic acid) Coated on Carbon Electrodes, Chem. Lett. (1988), 1423–1426.
Kashiwagi, Y., Ono, H., and Osa, T.: Electrocatalytic Oxidative Coupling of Methylquinolines on TEMPO-modified Graphite Felt Electrodes, Chem. Lett. (1993), 257–280.
Osa, T., Kashiwagi, Y., Yanagisawa, Y., and Bobbitt, J.M.: Enantioselective, Electrocatalytic Oxidative Coupling of Naphthol, Naphthyl Ether and Phenanthrol on a TEMPO-modified Graphite Felt Electrode in the Presence of (-)-Sparteine (TEMPO=2,2,6,6-tetramethylpiperidin-l-yloxyl), J. Chem. Soc., Chem Commun. (1994), 2535–2537.
Kashiwagi, Y., Yanagisawa, Y., Kurashima, F., Anzai, J., Osa, T., and Bobbitt, J.M.: Enantioselective, Electrocatalytic Oxidation of Racemic Alcohols on a TEMPO-modified Graphite Felt Electrode by Use of Chiral Base (TEMPO=2,2,6,6-tetramethylpiperidin-l-yloxyl), J. Chem. Soc., Chem. Commun. (1996: in press).
Osa, T., Kashiwagi, Y., and Yanagisawa, Y.: Electroenzymatic Oxidation of Alcohols on a Poly (acrylic acid)-coated Graphite Felt Electrode Terimmobilizing Ferrocene, Diaphorase and Alcohol Dehydrogenase, Chem. Lett. (1994), 367–370.
Kashiwagi, Y., Yanagisawa, Y., Shibayama, N., Nakahara, K, Kurashima, F., Anzai, J., and Osa, T.: Preparative, Electroenzymatic Reduction of Ketones on an All Components-immobilized Graphite Felt Electrode, Electrochim. Acta. (1996: in press).
Anzai, J., Kusano, T., Osa, T., Nakajima, H., and Matsuo, T.: Urea Sensor Based on Ion Sensitive Field Effect Transistor Coated with Cross-Linked Urease-Albumin Membrane, Bunseki Kagaku E33 (1984), 131–136.
Anzai, J., Tezuka, S., Osa, T., Nakajima, H., and Matsuo, T.: Urea Sensor Based on Ion-Sensitive Field Effect Transistor. IV. Determination of Urea in Human Blood, Chem. Pharm. Bull 35 (1987), 693–698.
Anzai, J., Lee, S., and Osa, T.: Reactive Langmuir-Blodgett Membrane for Biosensor Applications. Use of Succinimidyl Behenoate-Based Membranes as Support for Covalently Immobilizing α-Chymotrypsin, Bull Chem. Soc. Jpn. 62 (1989), 3018–3020.
Anzai, J. and Osa, T.: Langmuir-Blodgett Membranes in Chemical Sensor Applications, Selective Electrode Rev. 12 (1990), 3–33.
Anzai, J., Hoshi, T., and Osa, T.: Electrochemical Preparation of Active Avidin Films for Enzyme Sensor Applications, Chem.Lett. (1993), 1231–1234.
Wilchek, M. and Bayer, E.A.: The Avidin-Biotin Complex in Bioanalytical Applications, Anal Biochem. 171 (1988), 1–32.
Bayer, E.A. and Wilchek, M.: Applications of Avidin-Biotin Technology, Method Enzymol. 184 (1990), 14–45.
Anzai, J., Hoshi, T., Lee, S., and Osa, T.: Use of the Avidin-Biotin System for Immobilization of an Enzyme on the Electrode Surface, Sensors and Actuators B 13–14 (1993), 73–75.
He, P.-G., Takeshita, H., Hoshi, T., Anzai, J., Suzuki, Y., and Osa, T.: Preparation of Enzyme Multilayers on Electrode Surface by Use of Avidin and Bio-labeled Enzyme for Biosensor Applications, Materials Science & Engineering C2 (1994), 103–106.
Anzai, J., Takeshita, H., Hoshi, H., and Osa, T.: Regulation of Output Current of L-Lactate Sensors Based on Alternate Deposition of Avidin and Biotinylated Lactate Oxidase on Electrode Surface through Avidin/Biotin Complexation, Chem. Pharm. Bull. 43 (1995), 520–522.
Hoshi, T., Anzai, J., and Osa, T.: Controlled Deposition of Glucose Oxidase on Platinum Electrode Based on an Avidin/Biotin System for the Regulation of Output Current of Glucose Sensors, Anal Chem. 67 (1995), 770–774.
Anzai, J., Takeshita, H., Hoshi, T., and Osa, T.: Elimination of Ascorbate Interference of Glucose Biosensors by Use of Enzyme Multilayers Composed of Avidin and Biotin-labeled Glucose Oxidase and Ascorbate Oxidase, Denki Kagaku 63 (1995), 1141–1142.
Hoshi, T., Takeshita, H., Anzai, J., and Osa, T.: Use of Electrodeposited Avidin Film for the Preparation of Lactate and Choline Sensors, Anal Sci. 11 (1995), 311–312.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media Dordrecht
About this paper
Cite this paper
Osa, T. (1998). Construction of the Interfaces Possessing Both Functionalities of Molecular Recognition and Electron Transfer. In: Coleman, A.W. (eds) Molecular Recognition and Inclusion. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5288-4_4
Download citation
DOI: https://doi.org/10.1007/978-94-011-5288-4_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6226-8
Online ISBN: 978-94-011-5288-4
eBook Packages: Springer Book Archive