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Molecular Mechanical Modeling of the Metathesis-Active Tungsta-Carbenes

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Metathesis Polymerization of Olefins and Polymerization of Alkynes

Part of the book series: NATO ASI Series ((ASIC,volume 506))

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Abstract

A large number of catalyst systems are known to initiate the metathesis of olefins [1]. Transition metal carbenes formed in these systems trigger the transalkylidenation reaction. This carbene mechanism is well documented and accepted by now: olefin coordination to the complex carbene leads to a metalla-cyclobutane which rearranges to a new olefin and a new metalla-carbene [2] (Scheme 1).

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Authors and Affiliations

  1. Müller Laboratory, Department of Organic Chemistry, University of Veszprém, P.O.B. 158, H-8201, Veszprém, Hungary

    Lajos Bencze & Róbert K. Szilágyi

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  1. Lajos Bencze
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  2. Róbert K. Szilágyi
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Editors and Affiliations

  1. Department of Chemistry, Hacettepe University, Ankara, Turkey

    Yavuz Imamoglu

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Bencze, L., Szilágyi, R.K. (1998). Molecular Mechanical Modeling of the Metathesis-Active Tungsta-Carbenes. In: Imamoglu, Y. (eds) Metathesis Polymerization of Olefins and Polymerization of Alkynes. NATO ASI Series, vol 506. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5188-7_26

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  • DOI: https://doi.org/10.1007/978-94-011-5188-7_26

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6183-4

  • Online ISBN: 978-94-011-5188-7

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