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Ring-Opening Metathesis Polymerization by Molybdenum Imido Alkylidene Complexes

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Metathesis Polymerization of Olefins and Polymerization of Alkynes

Part of the book series: NATO ASI Series ((ASIC,volume 506))

Abstract

“Ring-opening metathesis polymerization” (ROMP) is a way of making polymers from cyclic olefins, as shown in equation 1, where R1 is the rate of forming polymer initially (in some cases reversibly) and R2 is the rate of “secondary metathesis” to give all possible linear and cyclic species.

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References

  1. Eleuterio, H. S., 1957, U. S. Patent 3,074,918.

    Google Scholar 

  2. Anderson, A. W.; Merckling, N. C., 1955, U. S. Patent 2,721,189.

    Google Scholar 

  3. Feldman, J.; Schrock, R. R. Prog. Inorg. Chem. 1991, 39, 1.

    Article  Google Scholar 

  4. Grubbs, R. H. J. Macromol. Sci., Pure Appl. Chem. 1994, A31, 1829.

    Article  CAS  Google Scholar 

  5. Grubbs, R. H.; Tumas, W. Science 1989, 243, 907.

    Article  CAS  Google Scholar 

  6. Schrock, R. R. in “Ring-Opening Polymerization”; D. J. Brunelle, Ed.; Hanser: Munich, 1993; pp 129.

    Google Scholar 

  7. Webster, O. W. Science 1991, 257, 887.

    Article  Google Scholar 

  8. Odian, G. “Principles of Polymerization”; Wiley: New York, 1981.

    Google Scholar 

  9. Noshay, A.; McGrath, J. E. “Block Copolymers”; Academic: New York, 1977.

    Google Scholar 

  10. Cummins, C. C; Schrock, R. R.; Vale, M. G.; Sankaran, V.; Cohen, R. E. Chem. Mat. 1992, 4, in press.

    Google Scholar 

  11. Sankaran, V.; Cohen, R. E.; Cummins, C. C; Schrock, R. R. Macromolecules 1992, 25, in press.

    Google Scholar 

  12. Krouse, S. A.; Schrock, R. R. Macromolecules 1988, 27, 1885.

    Article  Google Scholar 

  13. Sankaran, V.; Cummins, C. C; Schrock, R. R.; Cohen, R. E.; Silbey, R. J. J. Am. Chem. Soc. 1990, 112, 6858.

    Article  CAS  Google Scholar 

  14. Park, L. Y.; Stieglitz, S. G.; Crowe, W. M.; Schrock, R. R. Macromolecules 1991, 24, 3489.

    Article  CAS  Google Scholar 

  15. Bazan, G. C; Schrock, R. R. Macromolecules 1991, 23, 817.

    Article  Google Scholar 

  16. Saunders, R. S.; Cohen, R. E.; Schrock, R. R. Macromolecules 1991, 23, in press.

    Google Scholar 

  17. Cummins, C. C; Beachy, M. D.; Schrock, R. R.; Vale, M. G.; Sankaran, V.; Cohen, R. E. Chem. Mat. 1991, 5, 1153.

    Article  Google Scholar 

  18. Ng Cheong Chan, Y.; Schrock, R. R.; Cohen, R. E. Chem. Mater. 1992, 4, 24.

    Article  Google Scholar 

  19. Cummins, C. C.; Schrock, R. R.; Cohen, R. E. Chem. Mater. 1992, 4, 27.

    Article  CAS  Google Scholar 

  20. Saunders, R. S.; Cohen, R. E.; Wong, S. J.; Schrock, R. R. Macromolecules 1992, 25, 2055.

    Article  CAS  Google Scholar 

  21. Albagli, D.; Bazan, G. C; Wrighton, M. S.; Schrock, R. R. J. Am. Chem. Soc. 1992, 114, 4150.

    Article  CAS  Google Scholar 

  22. Ng Cheong Chan, Y.; Craig, G. S. W.; Schrock, R. R.; Cohen, R. E. Chem. Mater. 1992, 4, 885.

    Article  Google Scholar 

  23. Ng Cheong Chan, Y.; Schrock, R. R.; Cohen, R. E. J. Am. Chem. Soc. 1992, 114, 7295.

    Article  CAS  Google Scholar 

  24. Craig, G. S. W.; Cohen, R. E.; Schrock, R. R.; Silbey, R. J.; Puccetti, G.; Ledoux, L; Zyss, J. J. Am. Chem. Soc. 1993, 115, 860.

    Article  CAS  Google Scholar 

  25. Ng Cheong Chan, Y.; Schrock, R. R.; Cohen, R. E. Chem. Mater. 1993, 5, 566.

    Article  Google Scholar 

  26. Yue, J.; Sankaran, V.; Cohen, R. E.; Schrock, R. R. J. Am. Chem. Soc. 1993, 115, 4409.

    Article  CAS  Google Scholar 

  27. Albagli, D.; Bazan, G. C; Schrock, R. R.; Wrighton, M. S. J. Am. Chem. Soc. 1993, 775, 7328.

    Article  Google Scholar 

  28. Sankaran, V.; Yue, J.; Cohen, R. E.; Schrock, R. R.; Silbey, R. J. Chem. Mater. 1993, 5, 1133.

    Article  CAS  Google Scholar 

  29. Tassoni, R.; Schrock, R. R. Chem. Mater. 1994, 6, 744.

    Article  CAS  Google Scholar 

  30. Schrock, R. R.; Murdzek, J. S.; Bazan, G. C; Robbins, J.; DiMare, M.; O’Regan, M. J. Am. Chem. Soc. 1990, 112, 3875.

    Article  CAS  Google Scholar 

  31. Oskam, J. H.; Fox, H. H.; Yap, K. B.; McConville, D. H.; O’Dell, R.; Lichtenstein, B. J.; Schrock, R. R. J. Organometal Chem. 1993, 459, 185.

    Article  CAS  Google Scholar 

  32. Fox, H. H.; Lee, J.-K.; Park, L. Y.; Schrock, R. R. Organometallics 1993, 12, 759.

    Article  CAS  Google Scholar 

  33. Fox, H. H.; Yap, K. B.; Robbins, J.; Cai, S.; Schrock, R. R. Inorg. Chem. 1992, 31, 2287.

    Article  CAS  Google Scholar 

  34. Bazan, G.; Khosravi, E.; Schrock, R. R.; Feast, W. J.; Gibson, V. C; O’Regan, M. B.; Thomas, J. K.; Davis, W. M. J. Am. Chem. Soc. 1990, 772, 8378.

    Article  Google Scholar 

  35. Bazan, G. C.; Schrock, R. R.; Cho, H.-N.; Gibson, V. C. Macromolecules 1991, 23, 4495.

    Article  Google Scholar 

  36. Bazan, G. C; Oskam, J. H.; Cho, H.-N.; Park, L. Y.; Schrock, R. R. J. Am. Chem. Soc. 1991, 113, 6899.

    Article  CAS  Google Scholar 

  37. Schrock, R. R. Acc. Chem. Res. 1990, 23, 158.

    Article  CAS  Google Scholar 

  38. Schrock, R. R.; Crowe, W. E.; Bazan, G. C.; DiMare, M.; O’Regan, M. B.; Schofield, M. H. Organometallics 1991, 10, 1832.

    Article  CAS  Google Scholar 

  39. Fox, H. H.; Schofield, M. H.; Schrock, R. R. Organometallics 1994, 13, 2804.

    Article  CAS  Google Scholar 

  40. Toreki, R.; Schrock, R. R. J. Am. Chem. Soc. 1992, 114, 3367.

    Article  CAS  Google Scholar 

  41. Feast, W. J.; Gibson, V. C; Marshall, E. L. J. Chem. Soc, Chem. Commun. 1992, 1157.

    Google Scholar 

  42. Ivin, K. J.; Kress, J.; Osborn, J. A. J. Molec. Catal. 1988, 46, 351.

    Article  Google Scholar 

  43. Ishikawa, M.; Hasegawa, Y.; Hatano, T.; Kunai, A. Organometallics 1989, 8, 2741.

    Article  CAS  Google Scholar 

  44. Ivin, K. J. “Olefin Metathesis”; Academic: New York, 1983.

    Google Scholar 

  45. McConville, D. H.; Wolf, J. R.; Schrock, R. R. J. Am. Chem. Soc. 1993, 115, 4413.

    Article  CAS  Google Scholar 

  46. Edwards, J. H.; Feast, W. J.; Bott, D. C. Polymer 1984, 25, 395.

    Article  CAS  Google Scholar 

  47. Knoll, K.; Schrock, R. R. J. Am. Chem. Soc. 1989, 111, 7989.

    Article  CAS  Google Scholar 

  48. Park, L. Y.; Ofer, D.; Schrock, R. R.; Wrighton, M. S. Chem. Mater. 1992, 4, 1388.

    Article  CAS  Google Scholar 

  49. Saunders, R. S.; Cohen, R. E.; Schrock, R. R. Acta Polymerica 1994, 45, 301.

    Article  CAS  Google Scholar 

  50. Fox, H. H.; Wolf, M. O.; O’Dell, R.; Lin, B. L.; Schrock, R. R.; Wrighton, M. S. J. Am. Chem. Soc. 1994, 116, 2827.

    Article  CAS  Google Scholar 

  51. Buchmeiser, M.; Schrock, R. R. Macromolecules 1995, 28, 0000.

    Article  CAS  Google Scholar 

  52. Craig, G. S. W.; Cohen, R. E.; Schrock, R. R.; Esser, A.; Schrof, W. Macromolecules 1995, 28, 2512.

    Article  CAS  Google Scholar 

  53. Perrott, M. G.; Novak, B. M. Macromolecules 1995, 28, 3492.

    Article  CAS  Google Scholar 

  54. Wu, A.; Grubbs, R. H. Macromolecules 1995, 28, 3502.

    Article  CAS  Google Scholar 

  55. Alder, R. W.; Allen, P. R.; Khosravi, E. J. Chem. Soc., Chem. Commun. 1994, 1235.

    Google Scholar 

  56. Conticello, V. P.; Gin, D. L.; Grubbs, R. H. J. Am. Chem. Soc. 1992, 114, 9708.

    Article  CAS  Google Scholar 

  57. Miao, Y.-J.; Bazan, G. C. J. Am. Chem. Soc. 1994, 116, 9379.

    Article  CAS  Google Scholar 

  58. Thorn-Csanyi, E.; Hohnk, H.-D. J. Mol. Catal. 1992, 76, 101.

    Article  Google Scholar 

  59. Wagener, K. B.; Patton, J. T. Macromolecules 1993, 26, 249.

    Article  CAS  Google Scholar 

  60. Smith, D. W.; Wagener, K. B. Macromolecules 1993, 26, 3533.

    Article  CAS  Google Scholar 

  61. Ogara, J. E.; Wagener, K. B. Makromol. Chem. — Rapid Comm. 1993, 14, 657.

    Article  CAS  Google Scholar 

  62. Marmo, J. C; Wagener, K. B. Macromolecules 1993, 26, 2137.

    Article  CAS  Google Scholar 

  63. Thorn-Csanyi, E.; Kraxner, P. Macromol Rapid Commun. 1995, 16, 147.

    Article  CAS  Google Scholar 

  64. Sita, L. R.; Lyon, S. R. J. Am. Chem. Soc. 1993, 115, 10374.

    Article  CAS  Google Scholar 

  65. Sita, L. R. Macromolecules 1995, 28, 656.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts, 02139, USA

    Richard R. Schrock

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  1. Richard R. Schrock
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Editors and Affiliations

  1. Department of Chemistry, Hacettepe University, Ankara, Turkey

    Yavuz Imamoglu

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Schrock, R.R. (1998). Ring-Opening Metathesis Polymerization by Molybdenum Imido Alkylidene Complexes. In: Imamoglu, Y. (eds) Metathesis Polymerization of Olefins and Polymerization of Alkynes. NATO ASI Series, vol 506. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5188-7_1

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  • DOI: https://doi.org/10.1007/978-94-011-5188-7_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6183-4

  • Online ISBN: 978-94-011-5188-7

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