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Part of the book series: NATO Science Series ((ASHT,volume 47))

Abstract

Electron paramagnetic resonance (EPR) is one of the most powerful techniques for studying defects in electronic materials. It has been applied to the Si/SiO2 system with considerable success over the past few decades. This paper will review recent work using this technique in conjunction with electrical characterization methods to study the physics and chemistry of electrically active defects in metal-oxide-semiconductor field effect transistors (MOSFETs). This work has revealed the crucial role played by atomic hydrogen (H0) in the chemistry of defects in Si02. Experiments in which Si/Si02 structures are exposed to H0 help to explain various phenomena resulting from electrical stress or radiation exposure in MOS structures. However, this work has also opened new questions about the nature of the dominant electrically active defects at or near the Si/Si02 interface.

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References

  1. E.H. Poindexter and P.J. Caplan, Prog. Surf. Sci. 14 201 (1983).

    Article  CAS  Google Scholar 

  2. D.L Griscom, in D.R. Uhlmann and N.J. Kreidl (eds.), Glass Science and Technology, vol 4B (Academic Press, New York, 1990) p. 151.

    Google Scholar 

  3. B. Henderson, M. Pepper, and R.L. Vranch, Semicond. Sci. Technol 4 1045 (1989).

    Article  CAS  Google Scholar 

  4. J.H. Stathis and D.J. DiMaria, Appl. Phys. Lett. 61 2887 (1992).

    Article  CAS  Google Scholar 

  5. J.H. Stathis, Appl. Phys. Lett. 68 1669 (1996).

    CAS  Google Scholar 

  6. E. Cartier and J.H. Stathis, Microelectron. Eng. 28 3 (1995).

    Article  CAS  Google Scholar 

  7. A.G. Revesz, J. Electrochem. Soc. 126 122 (1979).

    Article  CAS  Google Scholar 

  8. Unless all the hydrogen could be replace by deuterium; see J.W. Lyding, K. Hess, and I.C. Kizilyalli, Appl. Phys. Lett. 68 2526 (1996).

    Google Scholar 

  9. D.J. DiMaria and J.W. Stasiak, J. Appl. Phys. 65 2342 (1989), and references therein.

    CAS  Google Scholar 

  10. D.L. Griscom, J. Electron. Mater. 21 763 (1992).

    Article  CAS  Google Scholar 

  11. E. Cartier, J.H. Stathis, and D.A. Buchanan, J. Appl. Phys. 63 1510 (1993).

    CAS  Google Scholar 

  12. J. H. Stathis and E. Cartier, Phys. Rev. Lett. 72 2745 (1994).

    Article  CAS  Google Scholar 

  13. A.H. Edwards, in C.R. Helms and B.E. Deal (eds.), The Physics and Chemistry of Si0 2 and the Si-SiO. Interface (Plenum, New York, 1988), p. 271.

    Google Scholar 

  14. R.E. Stahlbush, E. Cartier, and D.A. Buchanan, Microelectron. Eng. 28 15 (1995).

    Article  CAS  Google Scholar 

  15. E.H. Poindexter, in Z.C. Feng (ed.), Semiconductor Interfaces, Microstructures, and Devices: Properties and Applications (Insititute of Physics Publishing, Bristol, 1993) p. 229.

    Google Scholar 

  16. E. Cartier and J.H. Stathis, Appl. Phys. Lett. 69 103 (1996).

    Article  CAS  Google Scholar 

  17. K.G. Druijf, J.M.M. deNijs, E. v.d. Drift, V.V. Afanas’ev, E.H.A. Granneman, and P. Balk, J. Non-Crystalline Sol. 187 206 (1995).

    Article  CAS  Google Scholar 

  18. D.J. DiMaria and E. Cartier, J. Appl. Phys. 78 3883 (1995).

    Article  CAS  Google Scholar 

  19. B. Ricco, M. Ya. Azbel, and M.H. Brodsky, Phys. Rev. Lett. 51 1795 (1983).

    Article  CAS  Google Scholar 

  20. J.H. Stathis, Microelectron. Eng. 22 191 (1993).

    Article  CAS  Google Scholar 

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© 1998 Springer Science+Business Media Dordrecht

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Stathis, J.H. (1998). Electrical Defects at the SiO2/Si Interface Studied by EPR. In: Garfunkel, E., Gusev, E., Vul’, A. (eds) Fundamental Aspects of Ultrathin Dielectrics on Si-based Devices. NATO Science Series, vol 47. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5008-8_23

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  • DOI: https://doi.org/10.1007/978-94-011-5008-8_23

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-5008-8

  • Online ISBN: 978-94-011-5008-8

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