Abstract
The remarkable properties of materials synthesized from nanometer-sized particles were discovered using particles that were formed as aerosols. Although other routes for nanoparticle synthesis have evolved, aerosol routes remain a major method. The original processes employed by Gleiter and coworkers entailed evaporation of a metal into a low density gas where the vapors formed nanoparticles by homogeneous nucleation. Those nanoparticles were then collected by thermophoresis for subsequent consolidation. In a study that predated the use of vapor condensation as a step in the production of consolidated nanostructures, Granqvist and Buhrman provided empirical observations of the role of major control variables. A number of points of confusion remain in this method of nanoparticle synthesis, notably the distinctions between particle size, and the sizes of the microstructures that attract the attention of materials scientists.
This paper will examine the aerosol physics of nanoparticle synthesis with emphasis on unraveling this distinction. The physical processes that govern particle formation growth, structure, and deposition will be examined. The on-line characterization of aerosol nanoparticles will also be probed, with a view toward monitoring of the synthesis process.
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References
Alonso, M., & Kousaka, Y. 1996. Mobility shift in the differential mobility analyzer due to Brownian diffusion and space charge effects. J. Aerosol Sci., 27, 1201–1225.
Birringer, R., Gleiter, H., Klein, H. P., & Marquardt, P. 1984. Phys. Lett., 102A, 365–369.
Camata, R. 1997. Aerosol Synthesis and Characterization of Silicon Nanocrystals. Ph.D. thesis, California Institute of Technology.
Ellerby, H. M., Weakliem, C. L., & Reiss, H. 1991. Toward a molecular theory of vapor phase nucleation. 1. Identification of the average embryo. J. Chem. Phys., 95, 9209–9218.
Flagan, R. C., & Lundell, M. M. 1995. Particle structure control in nanoparticle synthesis from the vapor phase. Mater. Sci. Eng. A., 204, 113–124.
Flagan, R. C., & Seinfeld, J. H. 1988. Fundamentals of Air Pollution Enganeering. Engelwood Cliffs, NJ: Prentice-Hall.
Forrest, S. R., & Witten, T. A. 1979. J. Phys. A.: Math. Gen., 12, L109 - L117.
Frenkel, J. 1945. J. Phys., 9, 385.
Granqvist, C. G., & Buhrman, R. A. 1976. Ultrafine metal particles. J. Appl. Phys., 47. 2200–2219.
Hiram, Y., & Nir, A. 1983. J. Colloid Interface Sri., 95, 462.
Johnson, D.L. 1968. New Method of Obtaining Volume, Grain-Boundary, and Surface Diffusion Coefficients from Sintering Data. J. Appl. Phys., 40, 192–200.
Katz, J. L. 1992. Homogeneous nucleation theory and experiment - A survey. Pure Appl. Chem., 64. 1661.
Katz, J. L., & Donohue, M. D. 1982. Nucleation with simultaneous chemical reaction. J. Colloid Interface Sci., 85, 267–277.
Kingery, W.D., & Berg, M. 1955. Study of the Initial Stages of Sintering Solids by Viscous Flow. Evaporation-Condensation, and Self-Diffusion. J. Appl. Phys., 26(10), 1205–1212.
Knutson, E. O., & Whitby, K. T. 1975. Aerosol classification by electric mobility: apparatus, theory, and applications. J. Aerosol Sci., 6, 443–451.
Kobata, A., Kusakabe, K., & Morooka, S. 1991. Growth and transformation of TiO2 crystallites in aerosol reactor. AIChE J., 37, 347–359.
Koch, W., & Friedlander, S. K. 1990. The effect of particle coalescence on the surface area of a coagulating aerosol. J. Colloid Interface Sri., 140, 419–427.
Koch, W., & Friedlander, S. K. 1991. Particle growth by coalescence and agglomeration. Part. Part. Syst., 8, 86–89.
Kruis, F. E., Kusters, K. A., Pratsinis, S. E., & Scarlett, B. 1993. A simple model for the evolution of the characteristics of aggregate particles undergoing coagulation and sintering. Aerosol Sei. Technol., 19, 514–526.
Kuczinski, G.C. 1949. Self-Diffusion in Sintering of Metallic Particles. Trans. Am. Inst. Mater.. Eng., 185, 169–178.
Lai, F. S., Friedlander, S. K., Pich, J., & Hidy, G. M. 1972. The self-preserving particle size distribution for Brownian coagulation in the free-molecule regime. J. Colloid Interface Sri., 39, 395.
Matsoukas, T., & Friedlander, S. K. 1991. J. Colloid Interface Sci., 146, 495.
McClurg, R. B. 1997. Homogeneous Nucleation Theory.
McClurg, R. B., C., R., & Goddard, W. A. 1997. Influences of binding transit ions on t homogeneous nucleation of mercury. Nanostructured Maier., 9, 53–61.
Meakin, P. 1986. Pages 111–135 of: Stanley, H., & Ostrowsky, N. (eds), On Growth and Form. Boston, MA: Martinus Nijhoff.
Mountain, R. D., Mulholland, G. W., & Baum, H. 1986. J. Colloid Interface Sri., 114, 67.
Nguyen, H. V., & Flagan, R. C. 1991. Particle formation and growth in single stage aerosol reactors. Langmuir, 7, 1807–1814.
Pluyni, T. C., Lyons, S. W., Powell, Q. H., Gurav, A. S., Kodas, T. T., Wang, L. M., & Glocksman, H. D. 1993. Palladium metal and palladium oxide particle production by spray pyrolysis. Mater. Res. Bull., 28, 369–376.
Rao, N. P., & McMurry, P. H. 1990. Effect of the Tolman surface-tension correction on nucleation in chemically reacting systems. Aerosol Sci. Technol., 13, 183–195.
Rossell-Llompart, J., Loscertales, I. G., Bingham, D., & d. l. Mora, J. F. 1996. Sizing nanoparticles and ions with a short differential mobility analyzer. J. Aerosol Sci., 27, 695–719.
Shen, Y. C., & Oxtoby, D. W. 1996. Nucleation of Lennard-Jones fluids–A density-functional approach. J. Chem. Phys, 105, 6517–6524.
Ulrich, G. D. 1971. Theory of Particle Formation and Growth in Oxide Synthesis Flames. Combust. Sci Technol., 4, 47–57.
Ulrich, G. D. 1984. Flame synthesis of fine particles. Chem. Engr. News, 62, 22–29.
Ulrich, G. D., & Riehl, J. W. 1982. Aggregation of Growth of Submicron Oxide Particles in Flames. J. Colloid Interface Sri., 87, 257.
Ulrich, G.D., Milnes, B.A., & Subramanian, N.S. 1976. Particle Growth in Flames H. Experimental Results for Silica Particles. Combustion Science and Technology, 14, 243.
Ulrich, G.D., and Subramanian, N.S. 1977. “Particle growth in flames III. coalescence as a rate controlling process”. Combust. Sci Technol., 17, 119–126.
Wu, M. K., Windier, R. S., Steiner, C. K. R., Bors, T., & Friedlander, S. K. 1993. Controlled synthesi, of nanosized particles by aerosol processes. Aerosol Sci. Technol., 19, 527–548.
Xiong, Y., & Pratsinis, S. E. 1993a. Formation of agglomerate particles by coagulation and sintering 1. A 2-dimensional solution of the population balance equation. J. Aerosol Sci., 24, 283–300.
Xiong, Y., & Pratsinis, S. E. 1993b. Formation of agglomerate particles by coagulation and sintering 2. The evolution of the morphology of aerosol-made titania, silica, and silica-doped titania powders. J Aerosol Sci., 24, 301–313.
Zhang, S. H., Akutsu, Y., Russell, L. M., & Flagan, R. C. 1995. Radial differential mobility analyzer. Aerosol Sci. Technol., 23, 357–372.
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Flagan, R.C. (1998). Nanoparticles and Nanostructures: Aerosol Synthesis and Characterization. In: Chow, GM., Noskova, N.I. (eds) Nanostructured Materials. NATO ASI Series, vol 50. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-5002-6_2
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DOI: https://doi.org/10.1007/978-94-011-5002-6_2
Publisher Name: Springer, Dordrecht
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