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Improving agrochemical performance: possible mechanisms for adjuvancy

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Chemistry and Technology of Agrochemical Formulations

Abstract

It is well known that the activity of agrochemical formulations, especially those containing herbicides, can be improved substantially by the addition of certain biologically inactive ingredients, known collectively as adjuvants. Such products may be built into a formulation at the time of manufacture or used separately for tank mixing with a formulation prior to spray application. Perhaps understandably, the discovery and commercial development of adjuvants in the past has relied heavily on empirical or heuristic screening for enhancement effects on efficacy, with little consideration being given to underpinning modes or sites of action for adjuvancy. However, modern thinking on formulation design is becoming increasingly focused on more rational approaches to adjuvant selection, based on physico-chemical principles and a fundamental understanding of the key processes involved in optimizing the performance of agrochemicals. Past experience has already shown that adjuvant choice varies according to the properties of the pesticide, its mode of action (residual, contact or systemic) and the type of formulation used (solution, emulsion or suspension), as well as the nature of the intended target (weed, insect or fungus).

As much as 85‐90% of pesticides applied to crops never reach their target. Instead, they disperse into the air, soil, water, animals and people. Repetto and Baliga (1996)

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References

  • Anderson, N.H. and Hall, D.J. (1989) The role of dynamic surface tension in the retention of surfactant sprays on pea plants, in Adjuvants and Agrochemicals, Vol. II (eds P.N.P. Chow, C.A. Grant, A.M. Hinshalwood and E. Simundsson), CRC Press, Boca Raton, FL, pp. 5162.

    Google Scholar 

  • Anderson, N.H., Hall, D.J. and Western, N.M. (1988) Physicochemical aspects of spray atomisation and reduction of drop size by surfactants, in Proceedings of the International Symposium on Pesticide Application, Paris, 1 pp. 291–8.

    Google Scholar 

  • Arnold, A.C. (1983) Comparative droplet-size spectra for three different-angled flat fan nozzles. Crop Protection, 2 193–204.

    Article  Google Scholar 

  • Balzer, D. (1997) Alkyl polyglucosides as surfactants, in Specialist Surfactants (ed. I.D. Robb), Blackie, London, pp. 169–207.

    Chapter  Google Scholar 

  • Brazee, R.D., Bukovac, M.J., Cooper, J.A. et al. (1994) Surfactant diffusion and dynamic surface tension in spray solutions. Transactions of the American Society of Agricultural Engineers, 37 51–8.

    Google Scholar 

  • Briggs, G.G. and Bromilow, R.H. (1994) Influence of physicochemical properties on uptake and loss of pesticides and adjuvants from the leaf surface, in Interactions between Adjuvants, Agrochemicals and Target Organisms (eds P.J. Holloway, R.T. Rees and D. Stock), Springer-Verlag, Berlin, pp. 1–26.

    Google Scholar 

  • Butler Ellis, M.C. and Tuck, C.R. (1997) The effect of liquid properties on spray formation by flat fan nozzles. Aspects of Applied Biology, 48 105–12.

    Google Scholar 

  • Butler Ellis, M.C., Tuck, C.R. and Miller, P.C.H. (1997) The effect of some adjuvants on sprays produced by agricultural flat fan nozzles. Crop Protection, 16 41–50.

    Article  Google Scholar 

  • Chapple, A.C., Downer, R.A. and Hall, F.R. (1993) Effects of spray adjuvants on swath patterns and droplet spectra for a flat-fan hydraulic nozzle. Crop Protection, 12 579–90.

    Article  CAS  Google Scholar 

  • Cooke, B.K. and Hislop, E.C. (1993) Spray tracing techniques, in Application Technology for Crop Protection (eds G.A. Matthews and E.C. Hislop), CAB International, Oxford, pp. 85–100.

    Google Scholar 

  • Csorba, C., Hislop, E.C. and Western, N.M. (1995) Options for reduced volume ‘coarse’ droplet spraying, in Proceedings of the Brighton Crop Protection Conference - Weeds, pp. 513–20.

    Google Scholar 

  • Denis, M.-H. and Debrot, S. (1997) Effects of salts and surfactants on foliar uptake and long distance transport of glyphosate. Plant Physiology and Biochemistry, 35 291–301.

    CAS  Google Scholar 

  • de Ruiter, H., Uffing, A.J.M., Meinen, E. and Prins, A. (1990) Influence of surfactants and plant species on leaf retention of spray solutions. Weed Science,38 567–72.

    Google Scholar 

  • Dexter, R.W. (1996) Interactions of anionic surfactants and polymers used as spray tank adjuvants, in Pesticide Formulations and Application Systems: 16th Volume (eds M.J. Hopkinson, H.M. Collins and G.R. Goss), American Society for Testing and Materials, Philadelphia, ASTM STP 1312, pp. 77–92.

    Google Scholar 

  • Downer, R.A., Cooper, J.A., Chapple, A.C. et al. (1995) The effect of dynamic surface tension and high shear viscosity on droplet size distributions produced by a flat fan nozzle, in Pesticide Formulations and Application Systems: 14th Volume (eds F.R. Hall, P.D. Berger and H.M. Collins), American Society for Testing and Materials, Philadelphia, ASTM STP 1234, pp. 63–70.

    Google Scholar 

  • Franses, E.I., Basaran, O.A. and Chang, C.-H. (1996) Techniques to measure dynamic surface tension. Current Opinion in Colloid and Interface Science, 1, 296–303.

    Article  CAS  Google Scholar 

  • Friloux, K.M. and Berger, P.D. (1994) The relation of tallowamine ethoxylates to dynamic surface tension and field performance, in Pesticide Formulations and Application Systems: 15th Volume (eds H.M. Collins, F.R. Hall and M. Hopkinson), American Society for Testing and Materials, Philadelphia, ASTM STP 1268, pp. 83–97.

    Google Scholar 

  • Gaskin, R.E. (1995) Phytotoxicity of agrochemical adjuvants. in Proceedings of the Fourth International Symposium on Adjuvants for Agrochemicals, pp. 193–200.

    Google Scholar 

  • Gaskin, R.E. and Holloway, P.J. (1992) Some physicochemical factors influencing foliar uptake enhancement of glyphosate-mono(isopropylammonium) by polyoxyethylene surfactants. Pesticide Science, 34 195–206.

    Article  CAS  Google Scholar 

  • Gauvrit, C. (1994) Methodology for determining foliar penetration of herbicides with reference to oil-based adjuvants, in Interactions between Adjuvants, Agrochemicals and Target Organisms (eds P.J. Holloway, R.T. Rees and D. Stock), Springer-Verlag, Berlin, pp. 171–91.

    Google Scholar 

  • Gauvrit, C. and Cabanne, F. (1993) Oils for weed control: uses and mode of action. Pesticide Science, 37 147–53.

    Article  CAS  Google Scholar 

  • Grayson, B.T., Pack, S.E., Edwards, E. and Webb, J.D. (1993) Assessment of a mathematical model to predict spray deposition under laboratory track spraying conditions. II. Examination with further plant species and diluted formulations. Pesticide Science, 3713340.

    Google Scholar 

  • Grayson, B.T., Webb, J.D., Pack, S.E. and Edwards, E. (1991) Development and assessment of a mathematical model to predict foliar spray deposition under laboratory track spraying conditions. Pesticide Science, 33 281–304.

    Article  Google Scholar 

  • Green, J.M. (1997) Varying surfactant type changes quizalofop-P herbicidal activity. Weed Technology, 11, 298–302.

    CAS  Google Scholar 

  • Griffin, W.C. (1954) Calculation of HLB of nonionic surfactants. Journal of Society of Cosmetic Chemists, 5 249–58.

    Google Scholar 

  • Hall, F.R., Chapple, A.C., Downer, R.A. et al. (1993) Pesticide application as affected by spray modifiers. Pesticide Science, 38 123–34.

    Article  CAS  Google Scholar 

  • Hall, K.J., Holloway, P.J. and Stock, D. (1997a) Factors affecting the efficiency of spray delivery onto foliage using oil-based adjuvants. Aspects of Applied Biology, 48 11320.

    Google Scholar 

  • Hall, K.J., Western, N.M., Holloway, P.J. and Stock, D. (1997b) Effects of adjuvant oil emulsions on foliar retention and spray quality, in Proceedings of the Brighton Crop Protection Conference - Weeds,pp. 549–54.

    Google Scholar 

  • Hartley, G.S. and Brunskill, R.T. (1958) Reflection of water drops from surfaces, in Surface Phenomena in Chemistry and Biology (eds J.F. Danielli, K.G.A. Parkhurst and A.C. Riddiford), Pergamon Press, Oxford, pp. 214–23.

    Google Scholar 

  • Hill, R.M. (1997) Siloxane surfactants, in Specialist Surfactants (ed. I.D. Robb), Blackie, London, pp. 143–68.

    Chapter  Google Scholar 

  • Holloway, P.J. (1993) Adjuvants for agrochemicals: why do we need them? Mededelingen van de Faculteit Landbouwwetenschappen, Rijksuniversiteit,Gent, 58/2a 125–40.

    Google Scholar 

  • Holloway, P.J. (1994) Physicochemical factors influencing the adjuvant-enhanced spray deposition and coverage of foliage-applied agrochemicals, in Interactions between Adjuvants, Agrochemicals and Target Organisms (eds P.J. Holloway, R.T. Rees and D. Stock), Springer-Verlag, Berlin, pp. 83–106.

    Google Scholar 

  • Holloway, P.J. (1995) Adjuvants for foliage-applied agrochemicals: the need for more science not serendipity? in Proceedings of the Fourth International Symposium on Adjuvants for Agrochemicals, pp. 167–76.

    Google Scholar 

  • Holloway, P.J. and Edgerton, B.M. (1992) Effects of formulation with different adjuvants on foliar uptake of difenzoquat and 2,4-D: model experiments with wild oat and field bean. Weed Research,32 183–95.

    Article  CAS  Google Scholar 

  • Holloway, P.J. and Stock, D. (1990) Factors affecting the activation of foliar uptake of agrochemicals by surfactants, in Industrial Applications of Surfactants II (ed. D.R. Karsa), Special Publication No.77, Royal Society of Chemistry, Cambridge, pp. 303–37.

    Google Scholar 

  • Holloway, P.J., Wong, W.W.-C., Partridge, H.J. et al. (1992) Effects of some nonionic polyoxyethylene surfactants on uptake of ethirimol and diclobutrazol from suspension formulations applied to wheat leaves. Pesticide Science, 34 109–18.

    Article  CAS  Google Scholar 

  • Hoyle, E.R. and Holloway, P.J. (1996) Performance of alkyl polyglucosides as spray deposition agents, in Proceedings of the Brighton Crop Protection Conference - Pests and Diseases, pp. 441–2.

    Google Scholar 

  • Köcher, H. and Kocur, J. (1993) Influence of wetting agents on the foliar uptake and herbicidal activity of glufosinate. Pesticide Science, 37 155–8.

    Article  Google Scholar 

  • Langevin, D. (ed.) (1992) Light Scattering by Liquid Surfaces and Complementary Techniques,Surfactant Science Series, 41 Marcel Dekker, New York.

    Google Scholar 

  • Lasic, D. (1996) Liposones - an industrial view. Chemistry & Industry, 210–14.

    Google Scholar 

  • Leaper, C. (1996) Rational approaches to the design of formulations of glyphosatemono(isopropylammonium). PhD thesis, University of Bristol.

    Google Scholar 

  • Login, R.B. (1995) Pyrollidone-based surfactants. Journal of American Oil Chemists Society, 72 759–71.

    Article  CAS  Google Scholar 

  • Mercier, L., Serre, I. Cabanne, F. and Gauvrit, C. (1997) Behaviour of alkyl oleates following foliar application in relation to their influence on the penetration of phenmedipham and quizalofop-P-ethyl. Weed Research, 37 267–76.

    Article  CAS  Google Scholar 

  • Merritt, C.R. and Morrison, J.R. (1988) Some physical and biological effects of spray adjuvants, in Proceedings of the International Symposium on Pesticide Application, Paris, 1 pp. 299–308.

    Google Scholar 

  • Miller, P.C.H. (1992) Herbicide application, in Proceedings of the First International Weed Control Congress, 1 pp. 150–8.

    Google Scholar 

  • Nalewaja, J.D. (1995) Behaviour, applicability and efficacy of non-surfactant adjuvants, in Proceedings of the Fourth International Symposium on Adjuvants for Agrochemicals, pp. 186–92.

    Google Scholar 

  • Ozkan, H.E., Reichard, D.L., Zhu, H. and Ackerman, K.D. (1993) Effect of drift retardant chemicals on spray drift, droplet size and spray pattern, in Pesticide Formulations and Application Systems: 13th Volume (eds P.D. Berger, B.N. Devisetty and F.R. Hall), American Society for Testing and Materials, Philadelphia, ASTM STP 1183, pp. 173–89.

    Chapter  Google Scholar 

  • Policello, G.A., Stevens, P.J.G., Forster, W.A. and Gaskin, R.E. (1996) The influence of cosurfactant and role of spreading in stomatal infiltration by organosilicones, in Pesticide Formulations and Application Systems: 15th Volume (eds H.M. Collins, F.R. Hall and M. Hopkinson), American Society for Testing and Materials, Philadelphia, ASTM STP 1268, pp. 59–66.

    Chapter  Google Scholar 

  • Proceedings of the First International Symposium on Adjuvants for Agrochemicals (1986) in Chow, P.N.P., Grant, C.A., Hinshalwood, A.M. and Simundsson, E. (eds) (1989) Adjuvants and Agrochemicals, Vols I and II, CRC Press, Boca Raton, FL.

    Google Scholar 

  • Proceedings of the Second International Symposium on Adjuvants for Agrochemicals (1989) in Foy, C.L. (ed.) (1992) Adjuvants for Agrochemicals,CRC Press, Boca Raton, FL. Proceedings of the Third International Symposium on Adjuvants for Agrochemicals (1992) in Holloway, P.J. (ed.) (1993) Pesticide Science,37(2) and 38(2-3).

    Google Scholar 

  • Proceedings of the Fourth International Symposium on Adjuvants for Agrochemicals (1995) in Gaskin, R.E. (ed.) (1995) New Zealand Forest Research Institute Bulletin No. 193, Rotorua. Quinn, P.J., Perett, S.F. and Arnold, A.C. (1986) An evaluation of soya lecithin in crop spray performance. Atomisation and Spray Technology, 2 235–46.

    Google Scholar 

  • Repetto, R. and Baliga, S.S. (1996) Pesticides and The Immune System: The Public Health Risks, World Resources Institute Report, New York.

    Google Scholar 

  • Roggenbuck, F.C., Burow, R.F. and Penner, D. (1994) Relationship of leaf position to herbicide absorption and organosilicone adjuvant efficacy. Weed Technology, 8 582–5.

    CAS  Google Scholar 

  • Schönherr, J. and Baur, P. (1994) Modelling penetration of plant cuticles by crop protection agents and effects of adjuvants on their rates of penetration. Pesticide Science, 42 185–208.

    Article  Google Scholar 

  • Sharma, S.D., Kirkwood, R.C. and Whateley, T.L. (1996) Effect of non-ionic nonylphenol surfactants on surface physicochemical properties, uptake and distribution of asulam and diflufenican. Weed Research, 36 227–40.

    Article  CAS  Google Scholar 

  • Sharpe, D. and Eastoe, J. (1996) Properties of surfactant monolayers studied by surface light scattering. Langmuir, 12 2303–7.

    Article  CAS  Google Scholar 

  • Stevens, P.J.G. (1993) Organosilicone surfactants as adjuvants for agrochemicals. Pesticide Science, 38 103–22.

    Article  Google Scholar 

  • Stevens, P.J.G., Kimberley, M.O., Murphy, D.S. and Policello, G.A. (1993) Adhesion of spray droplets to foliage: the role of dynamic surface tension and advantages of organosilicone surfactants. Pesticide Science, 38 237–46.

    Article  CAS  Google Scholar 

  • Stock, D. and Holloway, P.J. (1993) Possible mechanisms for surfactant-induced foliar uptake of agrochemicals. Pesticide Science, 38 165–77.

    Article  CAS  Google Scholar 

  • Stock, D., Edgerton, B.M., Gaskin, R.E. and Holloway, P.J. (1992) Surfactant-enhanced foliar uptake of some organic compounds: interactions with two model polyoxyethylene aliphatic alcohols. Pesticide Science, 34 233–42.

    Article  CAS  Google Scholar 

  • Stock, D., Holloway, P.J., Grayson, B.T. and Whitehouse, P. (1993) Development of a predictive uptake model to rationalise selection of polyoxyethylene surfactant adjuvants for foliage-applied agrochemicals. Pesticide Science, 37 233–45.

    Article  CAS  Google Scholar 

  • Urvoy, C., Pollacsek, M. and Gauvrit, C. (1992) Seed oils as additives: penetration of triolein, methyl oleate and diclofop-methyl in maize leaves. Weed Research,32 375–83.

    Article  CAS  Google Scholar 

  • Uttley, M.J. (1995) Adjuvant use in the USA and Western Europe, in Proceedings of the Fourth International Symposium on Adjuvants for Agrochemicals, pp. 356–61.

    Google Scholar 

  • van Toor, R.F., Hayes, A.L. and Holloway, P.J. (1995) Relationships between herbicidal activity and foliar uptake of surfactant-containing solutions of diclofop-methyl on oats, in Proceedings of the Fourth International Conference on Adjuvants for Agrochemicals, pp. 279–84.

    Google Scholar 

  • Wales, D.J. and Griffiths, P.L. (1995) A study examining relationships between physicochemical properties and bioefficacy of tank added surfactant adjuvants with IPA glyphosate, in Proceedings of the Fourth International Conference on Adjuvants for Agrochemicals, pp. 11-19.

    Google Scholar 

  • Wirth, W., Storp, S. and Jacobsen, W. (1991) Mechanisms controlling leaf retention of agricultural spray solutions. Pesticide Science, 33 411–20.

    Article  CAS  Google Scholar 

  • Young, B.W. (1986) The need for a greater understanding in the application of pesticides. Outlook on Agriculture, 15 80–7.

    Google Scholar 

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Holloway, P.J. (1998). Improving agrochemical performance: possible mechanisms for adjuvancy. In: Knowles, D.A. (eds) Chemistry and Technology of Agrochemical Formulations. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4956-3_8

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