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Organometallic compounds of bivalent tin

  • Chapter
Chemistry of Tin

Abstract

The last 10 years have seen steady growth in the number of investigations into the chemistry of organom et al. lic R2Sn species. Much of this work has concentrated on the chemistry of relatively stable stannylenes and stannocenes and the preparation of new, even more stable compounds. The potential for bivalent organom et al. lic tin species in organic synthesis has also been studied. This chapter includes a description of the work covered in the first edition but concentrates on work published since 1988.

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References

  1. Neumann, W.P. (1978) in The Organom et al. lic and Coordination Chemistry of Germanium, Tin and Lead (eds M. Gielen and P. G. Harrison), Freund, Tel Aviv, 51.

    Google Scholar 

  2. Connolly, J.W. and Hoff, C. (1981) Adv. Organomet. Chem., 19, 123.

    CAS  Google Scholar 

  3. Neumann, W.P. (1991) Chem. Rev., 91, 311.

    CAS  Google Scholar 

  4. Mackay K.M. (1995) in The Chemistry of Organic Germanium, Tin and Lead Compounds (ed. S. Patai) Wiley, Chichester.

    Google Scholar 

  5. Davies, A.G. (1995) in Comprehensive Organom et al. lic Chemistry II (eds E. W. Abel, F. G. A. Stone and G. Wilkinson), Pergamon, Oxford, Vol. 2, 217.

    Google Scholar 

  6. Petz, W. (1986), Chem. Rev., 86, 1019.

    CAS  Google Scholar 

  7. Lappert, M.F. and Rowe, R.S. (1990) Coord. Chem. Rev., 100, 267.

    CAS  Google Scholar 

  8. Jutzi, P.(1986) Adv. Organomet. Chem., 26, 217.

    Google Scholar 

  9. Sita, L. R. (1995) Adv. Organomet Chem., 38, 189.

    CAS  Google Scholar 

  10. Neumann, W.P. and Fu, J.(1984) J. Organomet. Chem., 273, 295.

    CAS  Google Scholar 

  11. Behr, G. and Gelius, R. (1958) Chem. Ber., 91, 829.

    Google Scholar 

  12. Mathiasch, B. (1980) J. Organomet. Chem., 194, 37.

    CAS  Google Scholar 

  13. Hani, R. and Geanangel, R.A. (1985) Inorg. Chim. Acta, 96, 225.

    CAS  Google Scholar 

  14. Hani, R. and Geanangel, R.A. (1982) Polyhedron, 1, 826.

    CAS  Google Scholar 

  15. Gross, L.-W., Moser, R., Neumann, W.P. and Scherping, K.-H. (1982) Tetrahedron Lett., 23, 635.

    CAS  Google Scholar 

  16. Edelman, M.A., Hitchcock, P.B. and Lappert, M. F. (1990) J. Chem. Soc., Chem. Commun., 1116.

    Google Scholar 

  17. Ohtaki, Y., Kabe, Y and Ando W. (1994) Heteroatom. Chem., 5, 313.

    CAS  Google Scholar 

  18. Cowley, A.H., Hall, S.W., Nunn, C.M. and Power, J.M. (1988) Angew. Chem., Int. Edn Engl., 27, 838.

    Google Scholar 

  19. Egorov, M.P., Nefedov, O.M., Lin, T.-S. and Gaspar, P.P. (1995) Organom et al. lics, 14, 1539.

    CAS  Google Scholar 

  20. Grützmacher, H., Deck, W., Pritzkow, H. and Sander, M. (1994) Angew. Chem., Int. Edn Engl., 33, 456.

    Google Scholar 

  21. Herbst-Irmer, R., Freitag, S., Herbst-Irmer, R. et al.. (1995) Acta Crystallogr., C51, 631.

    Google Scholar 

  22. Grützmacher, H., Freitag, S., Herbst-Irmer, R. and Sheldrick, G.S. (1992) Angew. Chem., Int. Edn Engl, 31, 437.

    Google Scholar 

  23. Grützmacher, H. and Pritzkow, H. (1991) Angew. Chem., Int. Edn Engl, 30, 1017.

    Google Scholar 

  24. Grützmacher, H. and Pritzkow, H. (1993) Chem. Ber, 126, 2409

    Google Scholar 

  25. Saito, M., Tokitoh, N. and Okazaki, R. (1995) J. Organomet. Chem., 499, 43.

    CAS  Google Scholar 

  26. Cotton, J.D., Davidson, P. J. and Goldberg, D.E. et al.. (1974) J. Chem. Soc., Chem. Commun., 893.

    Google Scholar 

  27. Cardin, C. J., Cardin, D. J., Hursthouse, M.B. et al. (1988) J. Chem. Soc., Chem. Commun., 312.

    Google Scholar 

  28. Cardin, C. J., Cardin, D J., Lawless, G.A. et al.. (1987) J. Organomet. Chem., 325, 203.

    CAS  Google Scholar 

  29. Cardin, C. J., Cardin, D J., Parge, H.E. and Power, J.M. (1984) J. Chem. Soc., Chem. Commun., 609.

    Google Scholar 

  30. Cardin, C. J., Cardin, D J., Power, J.M. and Hursthouse, M.B. (1985) J. Am. Chem. Soc., 107, 505.

    CAS  Google Scholar 

  31. Marks, T. J. (1971) J. Am. Chem. Soc., 93, 7090.

    CAS  Google Scholar 

  32. Grynkewich, G.W., Ho, B.Y.K., Marks, T. J. et al.. (1973) Inorg. Chem., 12, 2522.

    CAS  Google Scholar 

  33. Marks, T. J. and Newman, A.R. (1973) J. Am. Chem. Soc., 95, 769.

    CAS  Google Scholar 

  34. Brice, M.D. and Cotton, F.A. (1973) J. Am. Chem. Soc., 95, 4529.

    CAS  Google Scholar 

  35. Jurkschat, K., Abicht, H.-P., Tzschach, A. and Mathieu, B. (1986) J. Organomet. Chem., 309, C47.

    CAS  Google Scholar 

  36. Abicht, H.-P., Jurkschat, K., Tzschach, A. et al.. (1986) J. Organomet. Chem., 326, 357.

    Google Scholar 

  37. King, R.B. and Stone, F.G.A. (1960) J. Am. Chem. Soc., 82, 3833.

    CAS  Google Scholar 

  38. Sweet, R.M., Fritchie, C J. and Schunn, R.A. (1967) Inorg. Chem., 6, 749.

    CAS  Google Scholar 

  39. Gilmore, C. J. and Woodward, P. (1972) J. Chem. Soc., Dalton Trans. 1387.

    Google Scholar 

  40. Fischer, E.O. and Grubert, H. (1956) Z. Naturforsch. B, 11, 423.

    Google Scholar 

  41. Hani, R. and Geanangel, R.A. (1985) J. Organomet. Chem., 293, 197.

    CAS  Google Scholar 

  42. Schumann, H., Janiak, C., Hahn, E. et al.. (1986) Chem. Ber., 119, 2656.

    CAS  Google Scholar 

  43. Heeg, M J., Janiak, C. and Zuckerman, J. J.(1984) J. Am. Chem. Soc., 106, 4259.

    CAS  Google Scholar 

  44. Janiak, C., Schumann, H., Stader, C. et al.. (1988) Chem. Ber., 121, 1745.

    CAS  Google Scholar 

  45. Gonsalves, K., Zhan-Ru, L., Lenz, R.W. and Rausch, M.D. (1985) J. Polym. Sci., Polym. Chem. Edn, 23, 1707.

    CAS  Google Scholar 

  46. Jutzi, P. and Kohl, F. (1979) J. Organomet. Chem., 164, 141.

    CAS  Google Scholar 

  47. Jutzi, P., Kohl, F., Hofmann, P. et al.. (1980) Chem. Ber., 113, 757.

    CAS  Google Scholar 

  48. Bonny, A., McMaster, A.D. and Stobart, S.R. (1978) Inorg. Chem., 17, 935.

    CAS  Google Scholar 

  49. Cowley, A.H., Jutzi, P., Kohl, F.X. et al.. (1984) Angew. Chem., Int. Edn Engl., 23, 616.

    Google Scholar 

  50. Dory, T.S. and Zuckerman, J. J.(1984) J. Organomet. Chem., 264, 295.

    CAS  Google Scholar 

  51. Jutzi, P. and Dickbreder, R. (1986) Chem. Ber., 119, 1750.

    CAS  Google Scholar 

  52. Janiak, C. and Schumann, H. (1991) Adv. Organomet. Chem., 33, 291.

    CAS  Google Scholar 

  53. Burkey, D J. and Hanusa, T.P. (1995) Organometallics, 14, 11.

    CAS  Google Scholar 

  54. Jutzi, P. and Dickbreder, R. (1989) J. Organomet. Chem., 313, 301.

    Google Scholar 

  55. Schumann, H., Janiak, C. and Zuckerman, J. J.(1988) Chem. Ber., 121, 207.

    CAS  Google Scholar 

  56. Heeg, M.J., Herber, R.H., Janiak, C. et al.. (1988) J. Organomet. Chem., 346, 321.

    CAS  Google Scholar 

  57. Lowack, R.H. and Vollhardt, K.P.C. (1994) J. Organomet. Chem., 416, 25.

    Google Scholar 

  58. Kohl, F.X., Dickbreder, R., Jutzi, P. et al.. (1989) Chem. Ber., 122, 871.

    CAS  Google Scholar 

  59. Jutzi, P. and Schwanzen, K.-H. (1989) Chem. Ber., 122, 287.

    CAS  Google Scholar 

  60. Jutzi, P. and Hielscher, B. (1986) Organometallics, 5, 1201.

    CAS  Google Scholar 

  61. Bos, K.D., Bulten, E. J. and Noltes, J.G. (1972) J. Organomet. Chem., 39, C52.

    CAS  Google Scholar 

  62. Rodesiler, P.F., Auel, Th. and Amma, E.L. (1975) J. Am. Chem. Soc., 97, 7405.

    CAS  Google Scholar 

  63. Weininger, M.S., Rodesiler, P.F., Gash, A.G. and Amma, E.L. (1972) J. Am. Chem. Soc., 94, 2135.

    CAS  Google Scholar 

  64. Weininger, M.S., Rodesiler, P.F. and Amma, E.L. (1979) Inorg. Chem., 18, 751.

    CAS  Google Scholar 

  65. Gin, D.Y., Cader, M.S.R., Sams, J.R. and Aubke, F. (1990) Can. J. Chem., 68, 350.

    CAS  Google Scholar 

  66. Wong, K.-S. and Grimes, R.N. (1977) Inorg. Chem., 16, 2053.

    CAS  Google Scholar 

  67. Cowley, A.H., Galow, P., Hosmane, N.S. et al.. (1984) J. Chem. Soc., Chem. Commun., 1564.

    Google Scholar 

  68. Hosmane, N.S., Sirmokadam, N.N. and Herber, R.H. (1984) Organometallics, 3, 1665.

    CAS  Google Scholar 

  69. Islam, M.S., Siriwardane, U., Hosmane, N.S. et al.. (1987) Organometallics, 6, 1936.

    CAS  Google Scholar 

  70. Jutzi, P., Galow, P., Abu-Orabi, S. et al. (1987) Organom et al. lics, 6, 1024.

    CAS  Google Scholar 

  71. Hosmane, N.S. and Maguire, J.A. (1990) Adv. Organomet. Chem., 30, 99.

    CAS  Google Scholar 

  72. Wadepohl, H., Pritzkow, H. and Siebert, W. (1983) Organometallics, 2, 1899.

    CAS  Google Scholar 

  73. Schmid, G., Zeika, D. and Boese, R. (1985) Angew. Chem., Int. Edn Engl, 24, 602.

    Google Scholar 

  74. Dewar, M. J. S., Healy, E.F., Kuhn, D.R. and Holder, A. J.(1991) Organometallics, 10, 431.

    CAS  Google Scholar 

  75. Timofeeva, T.V., Lii, J.-H. and Allinger, N.L. (1995) J. Am. Chem. Soc., 117, 7452.

    CAS  Google Scholar 

  76. Harrison, P.G. and Healy. M. A. (1973) J. Organomet. Chem., 51, 153.

    CAS  Google Scholar 

  77. Atwood, J.L., Hunter, W.E., Cowley, A.H. et al. (1981) J. Chem. Soc., Chem. Commun., 925.

    Google Scholar 

  78. Almenningen, A., Haaland, A. and Motzfeldt, T. (1967) J. Organomet. Chem., 7, 97.

    Google Scholar 

  79. Almlöf, J., Fernholt, L., Faegri, K. et al. (1983) Acta Chem. Scand. A, 37, 131.

    Google Scholar 

  80. Cowley, A.H., Lasch, J.G., Norman, N.C. et al. (1983) Organom et al. lics, 2, 1691.

    CAS  Google Scholar 

  81. Dory, T.S., Zuckerman, J. J. and Barnes, C.L. (1985) J. Organomet. Chem., 281, C1.

    CAS  Google Scholar 

  82. Baxter, S.G., Cowley, A.H., Lasch, J.G. et al.. (1982) J. Am. Chem. Soc., 104, 4064.

    CAS  Google Scholar 

  83. Bruno, G., Ciliberto, E., Fragal, I.L. and Jutzi, P. (1985) J. Organomet. Chem., 289, 263.

    CAS  Google Scholar 

  84. Cradock, S. and Duncan, W. (1978) J. Chem. Soc., Faraday Trans. 2, 74, 194.

    Google Scholar 

  85. Wrackmeyer, B., Sebald, A. and Merwin, L.H. (1991) Magn. Res. Chem., 29, 260.

    CAS  Google Scholar 

  86. Wrackmeyer, B., Kupce, E., Kehr, G. and Sebald, A. (1992) Magn. Res. Chem., 30, 964.

    CAS  Google Scholar 

  87. Williamson, R.L. and Hall, M.B. (1986) Organometallics, 5, 2142.

    CAS  Google Scholar 

  88. Hani, R. and Geanangel, R.A. (1985) J. Organomet. Chem., 293, 197.

    CAS  Google Scholar 

  89. Jutzi, P., Kohl, F. and Krüger, C. (1979) Angew. Chem., Int. Edn Engl, 18, 59.

    Google Scholar 

  90. Bos, K.D., Buken, E. J., Noltes, J.G. and Spek, A.L. (1975) J. Organomet. Chem., 99, 71.

    CAS  Google Scholar 

  91. Jutzi, P., Kohl, F., Krüger, C. et al. (1982) Angew. Chem., Int. Edn Engl, 21, 70.

    Google Scholar 

  92. Kohl, F.X., Schlüter, E., Jutzi, P. et al. (1984) Chem. Ber., 117, 1178.

    CAS  Google Scholar 

  93. Hosmane, N.S., de Meester, P., Maldar, N.N. et al.. (1986) Organom et al. lics, 5, 772.

    CAS  Google Scholar 

  94. Siriwardane, U., Hosmane, N.S. and Chu, S.S.C. (1987) Acta Crystallogr., C43, 1067.

    CAS  Google Scholar 

  95. Hosmane, N.S., Islam, M.S., Siriwardane, U. and Maguire, J.A. (1987) Organom et al. lics, 6, 2447.

    CAS  Google Scholar 

  96. Lüth, H. and Amma, E.L. (1969) J. Am. Chem. Soc., 91, 7515.

    Google Scholar 

  97. Harrison, P.G. and Zuckerman, J. J.(1969) J. Am. Chem. Soc., 91, 6885.

    CAS  Google Scholar 

  98. Bos, K.D., Buken, E. J. and Noltes, J.G.(1975) J. Organomet. Chem., 99, 397.

    CAS  Google Scholar 

  99. Bos, K.D., Buken, E. J. and Noltes, J.G.(1974) J. Organomet. Chem., 67, C13.

    CAS  Google Scholar 

  100. Burger, K., Geith, K. and Sewald, N. (1990) J. Fluorine Chem., 46, 105.

    CAS  Google Scholar 

  101. Plass, W., Heckmann, G., Fluck, E. (1990) Phosphorus, Sulfur, Silicon and Related Elements, 54, 81.

    Google Scholar 

  102. Harris, D.H. and Lappert, M.F. (1974) J. Chem. Soc., Chem. Commun., 895.

    Google Scholar 

  103. Kohl, F.X. and Jutzi, P. (1981) Chem. Ber., 114, 488.

    CAS  Google Scholar 

  104. Jutzi, P., Kohl, F.X., Schlüter, E. et al. (1984) J. Organomet. Chem., 271, 393.

    CAS  Google Scholar 

  105. Harrison, P.G. and Zuckerman, J. J.(1990) J. Am. Chem. Soc., 92, 2577.

    Google Scholar 

  106. Harrison, P.G. and Richards, J.A. (1976) J. Organomet. Chem., 108, 35.

    CAS  Google Scholar 

  107. Bos, K.D., Buken, E. J., Meinema, H.A. and Noltes, J.G. (1979) J. Organomet. Chem., 168, 159.

    CAS  Google Scholar 

  108. Dory, T.S., Zuckerman, J. J. and Rausch, M.D. (1985) J. Organomet. Chem., 281, C8.

    CAS  Google Scholar 

  109. Cornwell, A.B., Cornwell, C.-A. and Harrison, P.G. (1976) J. Chem. Soc., Dalton Trans., 1612.

    Google Scholar 

  110. Harrison, P.G. and Stobart, S.R. (1973) J. Chem. Soc., Dalton Trans. 940.

    Google Scholar 

  111. Harrison, P.G. and Stobart, S.R. (1973) Inorg. Chim. Acta, 7, 306.

    CAS  Google Scholar 

  112. Ewings, P.F.R. and Harrison, P.G. (1975) J. Chem. Soc., Dalton Trans. 2015.

    Google Scholar 

  113. Ewings, P.F.R. and Harrison, P.G. (1975) J. Chem. Soc., Ballon Trans. 1717.

    Google Scholar 

  114. Ewings, P.F.R., Harrison, P.G. and Fenton, D.E. (1975) J. Chem. Soc., Dalton Trans. 821.

    Google Scholar 

  115. Cornwell, A.B. and Harrison, P.G. (1975) J. Chem. Soc., Dalton Trans. 1722.

    Google Scholar 

  116. Ewings, P.F.R., Harrison, P.G. and Mangia, A. (1976) J. Organomet. Chem., 114, 35.

    CAS  Google Scholar 

  117. Ichikawa, I. J., Asami, M. and Mukaiyama, T. (1984) Chem. Lett., 949.

    Google Scholar 

  118. Mukaiyama, T., Ichikawa, I. J. and Asami, M. (1983) Chem. Lett, 683.

    Google Scholar 

  119. Mukaiyama, T., Ichikawa, I. J., Toba, M. and Asami, M. (1983) Chem. Lett., 879.

    Google Scholar 

  120. Mukaiyama, T., Ichikawa, I. J. and Asami, M. (1983) Chem. Lett., 293.

    Google Scholar 

  121. Ichikawa, I. J. and Mukaiyama, T. (1985) Chem. Lett., 1009.

    Google Scholar 

  122. Kobayashi, S., Tsuchiya, Y. and Mukaiyama, T. (1991) Chem. Lett., 541.

    Google Scholar 

  123. du Mont, W.-W. and Grenz, M. (1985) Chem. Ber., 118, 1045.

    Google Scholar 

  124. Kohl, F.X., Schlüter, E. and Jutzi, P.(1983) J. Organomet. Chem., 243, C37.

    CAS  Google Scholar 

  125. Cowley, A.H., Kemp, R.A. and Stewart, C.A. (1982) J. Am. Chem. Soc., 104, 3239.

    CAS  Google Scholar 

  126. Buken, E. J. and Budding, H.A. (1978) J. Organomet. Chem., 157, C3.

    Google Scholar 

  127. Stalke, D., Paver, M.A. and Wright, D.S. (1993) Angew. Chem., Int. Edn Engl, 32, 428.

    Google Scholar 

  128. Edwards, A. J., Paver, M.A., Raithby, P.R. et al.. (1995) J. Chem. Soc., Dalton Trans. 1587.

    Google Scholar 

  129. Edwards, A. J., Power, M.A., Raithby, P.R. et al.. (1993) J. Chem. Soc., Dalton Trans. 1465.

    Google Scholar 

  130. Davidson, M.G., Stalke, D. and Wright, D.S. (1992) Angew. Chem., Int. Edn Engl, 31, 1226.

    Google Scholar 

  131. Köpf-Maier, P., Janiak, C. and Schumann, H. (1988) Inorg. Chim. Acta, 152, 75.

    Google Scholar 

  132. Cornwell, A.B., Harrison, P.G. and Richards, J.A. (1976) J. Organomet. Chem., 108, 47.

    CAS  Google Scholar 

  133. Sriyunyongwat, V., Hani, R., Albright, T.A. and Geanangel, R. (1986) Inorg. Chim. Acta, 122, 91.

    CAS  Google Scholar 

  134. Bos, K.D., Bulten, E. J., Noltes, J.G. and Spek, A.L. (1975) J. Organomet. Chem., 92, 33.

    CAS  Google Scholar 

  135. Hoff, CD. and Connolly, J.W. (1978) J. Organomet. Chem., 148, 127.

    CAS  Google Scholar 

  136. Harrison, P.G. (1981) J. Organomet. Chem., 212, 183.

    CAS  Google Scholar 

  137. Dory, T.S., Zuckerman, J.J., Hoff, C.D. and Connolly, J.W. (1981) J. Chem. Soc., Chem. Commun. 521.

    Google Scholar 

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Lickiss, P.D. (1998). Organometallic compounds of bivalent tin. In: Smith, P.J. (eds) Chemistry of Tin. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4938-9_6

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