Abstract
Laboratory applications to the study of interstellar ices are reviewed. An overview is given of the state-of-the-art in infrared spectroscopy of astrophysical ice analogs. Laboratory results on chemical processes relevant to the evolution of interstellar ice mantles are summarized. These are grain surface chemistry involving activationless reactions between atoms and molecules, activationless acid-base reactions, cryogenic reactions involving formaldehyde, and the energetic processing of the ices by ultraviolet radiation or energetic ions. Furthermore, the sublimation properties of pure and mixed ices of astrophysical relevance are summarized. Some areas in which the laboratory results have stimulated essential progress in the study of interstellar and comet ices are pointed out. Finally, some avenues are discussed through which the combined observation/laboratory simulation approach could clarify a number of standing issues on the role of ices in dense cloud chemistry.
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References
Agarwai V.K., Schutte W., Greenberg J.M., Ferris J.P., Briggs R., Connor S., van de Bult, C.P.E.M., Baas F. 1985, Photochemical reactions in interstellar grains. Photolysis of CO, NH3, and H2O, Origins of Life 16, 21–40.
Allamandola L.J., Sandford S. A. and Valero G. J. 1988, Photochemical and thermal evolution of interstellar/precometary ice analogs, Icarus 76, 225–252.
Allamandola L. J., Sandford S. A., Tielens A. G. G. M. and Herbst T. M. 1992, Infrared spectroscopy of dense clouds in the C-H stretching region: Methanol and “diamonds”, ApJ 399, 134–146.
Benit J., Bibring J.-R, Della-Negra S., Le Beyec Y., Mendenhall M., Rocard F., Standing K. 1987, Nuclear Instruments and Methods in Physics Research B19/20, 838–842.
Bergren M.S., Schuh D., Sceats M.G., Rice S.A. 1978, The OH stretching region infrared spectra of low density amorphous solid water and polycrystalline ice Ih, J. Chem. Phys. 69, 3477–3482.
Bernstein M.P., Sandford S.A, Allamandola L.J., Chang S., Scharberg M.A. 1995, Organic compounds produced by photolysis of realistic interstellar and cometary ice analogs containing methanol, ApJ 454, 327–344.
Bernstein M.P., Sandford S.A, Allamandola L.J. 1997, The infrared spectra of nitriles and related compounds frozen in Ar and H2O, ApJ 476, 932–942.
Blake D., Allamandola L., Sandford AA., Hudgins D., Freund F. 1991, Clathrate hydrate formation in amorphous cometary ice analogs in vacuo, Science 254, 548–551.
Boogert, A.C.A., Schutte, W.A., Tielens, A.G.G.M., Whittet, D.C.B., Helmich, F.P., Ehrenfreund, P., Wesseelius, P.R., de Graauw, Th., and Prusti, T. 1996, Solid methane towards deeply embedded protostars, A&A 315, L377–L380.
Boogert A.C.A., Schutte W.A., Helmich F.P, Tielens A.G.G.M., Wooden D.H. 1997, Infrared observations and laboratory simulations of interstellar CH4 and SO2, A&A 317, 929–941.
Boudin N., Schutte W.A., Greenberg J.M. 1998, Constraints to the abundance of a number of molecules in interstellar ice: Laboratory studies and astrophysical implications, submitted to A&A.
Briggs R., Ertem G., Ferris J. P., Greenberg J. M., McCain P. J., Mendoza-Gomez C. X. and Schutte W. 1992, Comet Halley as an aggregate of interstellar dust and further evidence for the photochemical formation of organics in the interstellar medium, Origins of Life and Evolution of the Biosphere 22, 287–307.
Charnley S.B., Kress M.E., Tielens A.G.G.M., Millar T.J. 1995, Interstellar alcohols, ApJ 448, 232–239.
Chiar J. E., Adamson A. J., Kerr T. H. and Whittet D. C. B. 1994, Solid carbon monoxide in the Serpens dark cloud, ApJ 426, 240–248.
Chiar J.E., Gerakines P.A., Whittet D.C.B., Pendleton Y.J., Tielens A.G.G.M., Adamson A.J., Boogert A.C.A. 1998, Processing of icy mantles in protostellar envelopes, ApJ, in press.
de Graauw, Th., Whittet, D.C.B., Gerakines, P.A., Bauer, O.H., Beintema, D.A., Boogert, A.C.A., Boxhoorn, D.R., Chiar, J.E., Ehrenfreund, P., Feuchtgruber, H., Helmich, F.P., Heras, A.M., Huygen, R., Kester, D.J.M., Kunze, D., Lahuis, F., Leech, K.J., Lutz, D., Morris, P.W., Prusti, T., Roelfsema, P.R., Salama, A., Schaeidt, S.G., Schutte, W.A., Spoon, H.W.W., Tielens, A.G.G.M., Valentijn, E.A., Vandenbusshe, B., van Dishoeck, E. F., Wesselius, P.R., Wieprecht, E., Wright, C.M. 1996, SWS observations of solid CO2 in molecular clouds, A&A 315, L345–L348.
d’Hendecourt L. B., Allamandola L. J., Baas F., and Greenberg J. M. 1982, Interstellar grain explosions: Molecule cycling between gas and dust, A&A 109, L12–L14.
d’Hendecourt L. B., Allamandola L. J. and Greenberg J. M. 1985, Time dependent chemistry indense molecular clouds: I. Grain surface reactions, gas/grain interactions and infrared spectroscopy, A&A 152, 130–150.
d’Hendecourt L. B., Allamandola L. J., Grim R. J. A. and Greenberg J. M. 1986, Time dependent chemistry indense molecular clouds: II. Ultraviolet photoprocessing and infrared spectroscopy of grain mantles, A&A 158, 119–134.
d’Hendecourt L. B. and Allamandola L. J. 1986, Time dependent chemistry in dense molecular clouds. HI. Infrared band cross sections of molecules in solid state at 10 K, A&AS, 64, 453–467.
d’Hendecourt L. B. and Jourdain de Muizon M. 1989, The discovery of interstellar carbon dioxide, A&A 223, L5–L8.
Ehrenfreund P., Breukers R., d’Hendecourt L. and Greenberg J. M. 1992, On the possibility of detecting solid O2 in interstellar grain mantles, A&A 260, 431–436.
Ehrenfreund, P., Gerakines, P. A., Schutte, W. A., and van Dishoeck, E. F. 1996a, Infrared properties of isolated water ice, A&A 312, 263–274.
Ehrenfreund, P., Boogert, A.C.A., Gerakines, P.A., Jansen, D.J., Schutte, W.A., Tielens, A.G.G.M., van Dishoeck, E.F. 1996b, A laboratory database of solid CO and CO2 for ISO, A&A 315, L341–L344.
Ehrenfreund, P., Boogert, A.C.A., Gerakines, P.A., Tielens, A.G.G.M., van Dishoeck, E.F. 1998, Infrared spectroscopy of interstellar apolar ice analogs, A&A, in press.
Elsila J., Allamandola L.J., Sandford S.A. 1997, The 2140 cm−1 (4.673 µm) solid CO band: The case for interstellar O2 and N2 and the photochemistry of non-polar interstellar ice analogs, ApJ 479, 818–833.
Foti G., Calcagno L., Sheng K.L., Strazzulla G., Micrometre-sized polymer layers synthesized by MeV ions impinging on frozen methane 1984, Nature 310, 126–128.
Geballe T. R., Baas F., Greenberg J. M. and Schutte W. 1985, New infrared absorption features due to solid phase molecules containing sulfur in W 33 A, A&A 146, L6–L8.
Gerakines P. A., Schutte W. A., Greenberg J. M. and van Dishoeck E. F. 1995, The infrared band strenghts of H2O, CO and CO2 in laboratory simulations of astrophysical ice mixtures, A&A 296, 810–818.
Gerakines, P. A., Schutte, W. A., Ehrenfreund, P., and van Dishoeck, E. F. 1996, Ultraviolet processing of interstellar ice analogs. I. Pure ices, A&A 312, 289–305.
Gillett F. C. and Forrest W. J. 1973, Spectra of the Becklin-Neugebauer point source and the Kleinmann-Low nebula from 2.8–13.5 microns, ApJ 179, 483–491.
Gillett F. C, Jones T. W., Merrill K. M. and Stein W. A. 1975, Anisotropy of constituents of interstellar grains, A&A 45, 77–81.
Goldsmith P.F. 1987, Molecular clouds: An overview, in Interstellar Processes, D.J. Hollenbach and H. Thronson eds., Reidel, Dordrecht, pp. 51–70.
Greenberg J.M. 1971, Interstellar grain temperatures: Effects of grain materials and radiation fields, A&A 12, 240–249.
Greenberg J.M. 1982, What are comets made of ? A model based on interstellar dust. In Comets, L. Wilkening, Ed., Univ. of Arizona press, Tucson, pp. 131–163.
Greenberg J.M., van de Bult C.E.P.M., Allamandola L.J. 1983, Ices in space, J. Phys. Chem. 87, 4243–4260.
Grim R. J. A. and d’Hendecourt L. B. 1986, Time dependent chemistry in dense molecular clouds: IV. Interstellar grain surface reactions inferred from a matrix isolation study, A&A 167, 161–165.
Grim R. J. A. and Greenberg J. M. 1987, Ions in grain mantles: The 4.62 micron absorption by OCN− in W33A, ApJ 321, L91–L96.
Grim R. J. A., Greenberg J. M., de Groot M. S., Baas F., Schutte W. A., and Schmitt B. 1989, Infrared spectroscopy of astrophysical ices: New insights in the photochemistry, A&AS 78, 161–186.
Grim R. J. A., Baas F., Geballe T. R., Greenberg J. M. and Schutte W. 1991, Detection of solid methanol toward W 33A, A&A 243, 473–477.
Gürtler J., Henningg Th., Kömpe C, Pfau W., Krätschmer W., Lemke D. 1996, Detection of an absorption band at the position of the 4.27-µm band of solid CO2, A&A 315, L189–L192.
Hagen W., Tielens A.G.G.M., Greenberg J.M. 1981, The spectrum of amorphous solid water and ice Ic between 10 and 140 K, Chem. Phys. 56, 367–379.
Hagen W. and Tielens A. G. G. M. 1981, Infrared spectrum of H2O matrix isolated in CO at 10 K: Evidence for bifurcated dimers, J. Chem. Phys. 75, 4198–4207.
Hagen W. 1982, Chemistry and infrared spectroscopy of interstellar grains, PhD thesis, University of Leiden, the Netherlands.
Hagen W., Tielens A.G.G.M., Greenberg J.M. 1983, A laboratory study of the infrared spectra of interstellar ices, A&AS 51, 389–416.
Hasegawa T. I., Herbst E. and Leung C. M. 1992, Models of gas-grain chemistry in dense interstellar clouds with complex organic molecules, ApJS 82, 167–195.
Hasegawa T. I. and Herbst E. 1993, New gas-grain chemical models of quiescent dense interstellar clouds: the effects of H2 tunnelling reactions and cosmic ray induced desorption, MNRAS 261, 83–102.
Helmich F.P., Millar T.J., van Dishoeck E.F. 1998, in preparation.
Hiraoka K., Yamashita A., Yachi Y., Aruga K., Sata T., Muto H. 1995, Ammonia formation from the reaction of H atoms with N atoms trapped in a solid N2 matrix at 10–30 K, ApJ 443, 363–370.
Hiraoka K., Ohashi N., Kihara Y., Yamamoto K., Sata T., Yamashita A. 1994, Formation of formaldehyde and methanol from the reaction of H atoms with solid CO at 10–20 K, Chem. Phys. Letters 229, 408–414.
Hudgins D. M., Sandford S. A., Allamandola L. J. and Tielens A. G. G. M. 1993, Mid-and Far-infrared spectroscopy of ices: Optical constants and integrated absorbances, ApJS 86, 713–870.
Hudson R.L., Moore M.H. 1997, Hydrocarbon radiation chemistry in ices of cometary relevance, Icarus 126, 233–235.
Jenniskens P. and Blake D. F. 1994, Structural transitions in amorphous water ice and astrophysical implications, Science 265, 753–756.
Jessberger E.K., Kissel J., Cehmical properties of cometary dust and a note on carbon isotopes, In Comets in the Post-Halley era, R.L. Newburn, M. Neugebauer, and J. Rahe, Eds., Kluwer Academic Publishers, Dordrecht, pp. 1075–1091.
Jiang G.J., Willis B.P., Brown K.G. 1975, Absolute infrared intensities and band shapes in pure solid CO and CO in some solid matrices, J. Chem. Phys. 62, 1201–1211.
Kaiser R.I., Roessler K. 1997, Theoretical and experimental studies of the interaction of cosmic ray particles with frozen matter in space. I. Synthesis of polycyclic aromatic hydrocarbons by cosmic ray induced multi center mechanism, ApJ, in press.
Keane J., Schutte W.A. 1998, in preparation.
Kerr T. H., Adamson A. J. and Whittet D. C. B. 1993, Infrared spectroscopy of solid CO: the Ophiuchi molecular cloud, MNRAS 262, 1047–1056.
Kitta K., Krätschmer W. 1983, Status of laboratory experiments on ice mixtures and on the 12 µm H2O ice feature, A&A 122, 105–110.
Lacy J. H., Baas F., Allamandola L. J., Persson S. E., McGregor P. J., Lonsdale C. J., Geballe T. R. and van de Bult C. E. P. 1984, 4.6 micron absorption features due to solid phase CO and cyano group molecules toward compact infrared sources, ApJ 276, 533–543.
Lacy J. H., Carr J. S., Evans N., Baas F., Achtermann J. M. and Arens F. 1991, Discovery of interstellar methane: Observations of gaseous and solid CH4 absorption toward youngg stars in molecular clouds, ApJ 376, 556–560.
Lanzerotti L.J., Brown W.L., Marcantonio K.J. 1987, Experimental study of erosion of methane ice by energetic ions and some considerations for astrophysics, ApJ 313, 910–919.
Léger A., Gauthier S., Defourneau D., Rouan D. 1983, Properties of amorphous H2O ice and origin of the 3.1 µm absorption, A&A 117, 164–169.
Léger A., Jura M., Omont A. 1985, Desorption from interstellar grains, A&A 144, 147–160.
Maréchal Y. 1987, IR spectra of carboxylic acids in the gas-phase: A quantitative reinvestigation, J. Chem. Phys. 87, 6344–6353.
Mathis J.S., Mezger P.G., Panagia N. 1983, Interstellar radiation field and dust temperatures in the diffuse matter and in giant molecular clouds, A&A 128, 212–229.
Millar T.J., Macdonald G.H., Habing R.J. 1995, The detection of hot ethanol in G34.3+0.15, MNRAS 273, 25–29.
Millar T.J. 1997, Models of hot molecular cores, In I.A.U. symposium no. 178: Molecules in astrophysics: Probes and processes, E. F. van Dishoeck, Ed., Kluwer, Dordrecht, pp. 75–88.
Moore M.H., Donn B. 1982, The infrared spectrum of a laboratory synthesized residue: Implications for the 3.4 micron interstellar absorption feature 1982, ApJ 257, L47–L50.
Moore, M. H. Hudson R. L. 1992, Far-infrared spectral studies of phase changes in water ice produced by proton irradiation, ApJ 401, 353–360.
Moore, M. H. Hudson R. L. 1994, Far-infrared spectra of cosmic-type and mixed ices, A&AS. 103, 45–56.
Ohishi M. 1997, Observations of “hot cores”, In I.A.U. symposium no. 178: Molecules in astrophysics: Probes and processes, E. F. van Dishoeck, Ed., Kluwer, Dordrecht, pp. 61–74.
Omont A., Moseley S.H., Forveille T., Glaccum W.J., Harvey P.M., Likkel L., Loewenstein R.F., Lisse C.M. 1990, Observations of the 40–70 micron bands of ice in IRAS 09371+1212 and other stars, ApJ 355, L27–L30.
Palumbo M. E. and Strazulla G. 1992, The 2140 cm−1 band of frozen CO in ion-irradiated and unirradiated mixtures with methanol and water, A&A 259, L12–L14.
Palumbo M. E. and Strazulla G. 1993, The 2140 cm−1 band of frozen CO: laboratory experiments and astrophysical applications, A&A 269, 568–580.
Palumbo M.E., Tielens A.G.G.M., Tokunaga A.T. 1995, Solid carbonyl sulphide (OCS) in W33A, ApJ 449, 674–680.
Pironello V., Brown W. L., Lanzerotti L. J., Marcantonio K. J., Simmons E. J. 1982, Formaldehyde formation in a H2O/CO2 ice mixture under irradiation by fast ions, ApJ 262, 636–640.
Ritzhaupt G., Devlin J.P., 1977, Ionic vs. molecular nature of monomelic ammonium and hydronium nitrate. Infrared spectra of H3O+NO −3 and NH +4 NO −3 solvated in argon matrices, J. Phys. Chem. 81, 521–525.
Sandford S. A. and Allamandola L. J. 1988, The condensation and vaporization behavior of H2O:CO ices and the implications for interstellar grains and cometary activity, Icarus 76, 201–224.
Sandford S. A., Allamandola L. J., Tielens A. G. G. M., and Valero L. J. 1988, Laboratory studies of the infrared spectral properties of CO in astrophysical ices, ApJ 329, 498–510.
Sandford S. A. and Allamandola L. J. 1990, The physical and infrared spectral properties of CO2 in astrophysical ice analogues, ApJ 355, 357–372.
Sandford S. A. and Allamandola L. J. 1993a, H2 in interstellar and extragalactic ices: Infrared characteristics, ultraviolet production and implications, ApJ 409, L65–L68.
Sandford S. A., Allamandola L. J. and Geballe T. R. 1993, Spectroscopic detection of molecular hydrogen frozen in interstellar ices, Science 262, 400–402.
Sandford S. A. and Allamandola L. J. 1993b, Condensation and vaporization studies of CH3OH and NH3 ices: Major implications for astrochemistry, ApJ 417, 815–825.
Schmitt B., Grim R. J. A. and Greenberg J. M. 1988, Molecular diffusion in ices — Implications for the composition of interstellar grain mantles and comet nuclei, in experiments on cosmic dust analogues, eds. E. Bussoletti, C. Fusco and G. Longo (Dordrecht, Kluwer), p. 259–269.
Schmitt B. 1994, Physical and chemical processes in icy grain mantles, in AIP conference proceedings 312: Molecules and grains in space, ed. I. Nenner (New York, AIP press), 735–757.
Schutte, W. A. 1988, The evolution of interstellar organic grain mantles, PhD thesis, University of Leiden, the Netherlands.
Schutte W. A. and Greenberg J. M. 1991, Explosive desorption of icy grain mantles in dense clouds, A&A 244, 190–204.
Schutte W. A., Tielens A. G. G. M. and Sandford S. A. 1991, 10 micron spectra of protostars and the solid methanol abundance, ApJ 382, 523–529.
Schutte W. A., Allamandola L. J. and Sandford S. A. 1993, An experimental study of the organic molecules produced in cometary and interstellar ice analogs by thermal formaldehyde reactions, Icarus 104, 118–137.
Schutte, W. A., Gerakines, P. A., Geballe, T. R., van Dishoeck, E. F., and Greenberg, J. M. 1996a, Discovery of solid formaldehyde towards the protostar GL 2136: Observations and laboratory simulation, A&A 309, 633–647.
Schutte, W.A. 1996, Formation and Evolution of Interstellar Icy Grain Mantles, in: “The Cosmic Dust Connection”, ed. J. M. Greenberg, pp. 1–42.
Schutte, W.A., Tielens, A.G.G.M., Whittet, D.C.B., Boogert, A., Ehrenfreund, P., de Graauw, Th., Prusti, T., van Dishoeck, E. F., and Wesselius, P. 1996b, The 6 and 6.8 μm absorption features in the spectrum of NGC7538:IRS9, A&A 315, L333–L336.
Schutte W.A., Greenberg J.M. 1997, Further evidence for the OCN− assignment to the XCN band in astrophysical ice analogs, A&A 317, L43–L46.
Skinner C. J., Tielens A. G. G. M., Barlow M. J., and Justtanont K. 1992, Methanol ice in the protostar GL 2136, ApJ 399, L79–L82.
Smith M. A. H., Rinsland C. P., Fridovich B., Rao K. N. 1985, in Molecular Spectroscopy: Modern research, Ed. K. N. Rao (Academic Press), Vol. III, p. 111.
Smith R. G., Sellgren K. and Tokunaga A. T. 1989, Absorption features in the 3 micron spectra of protostars, ApJ 344, 413–426.
Strazzulla G., Calcagno L., Foti G. 1984, Build up of carbonaceous material by fast protons in Pluto and Triton, A&A 140, 441–444.
Strazzulla G. and Baratta G. A. 1991, Laboratory study of the IR spectrum of ion-irradiated frozen methane, A&A 241, 310–316.
Strazzulla G. and Baratta G. A. 1992, Carbonaceous Material by ion irradiation in space, A&A 266, 434–438.
Tegler S.C., Weintraub D.A., Allamandola L.J., Sandford S.A., Rettig T.W., Campins H. 1993, Detection of the 2165 cm−1 inverse centimeter (4.619 micron) XCN band in the spectrum of L1551 IRS5, ApJ 411, 260–265.
Tegler S.C., Weintraub D.A., Rettig T.W., Pendleton Y.J., Whittet D.C.B., Kulesa C.A. 1995, Evidence for chemical processing of precometary ice grains in circumstellar environments of pre-main-sequence stars, ApJ 439, 279–287.
Tielens A.G.G.M. and Hagen W. 1982, Model calculations of the molecular composition of interstellar grain mantles, A&A 114, 245–260.
Tielens A.G.G.M., Allamandola L.J. 1987a, Composition, structure, and chemistry of interstellar dust, in Interstellar Processes, D.J. Hollenbach and H. Thronson eds., Reidel, Dordrecht, 397–469.
Tielens A. G. G. M. and Allamandola L. J. 1987b, Evolution of interstellar dust, in Physical processes in interstellar clouds, eds. G. E. Morfill and M. Scholer, p. 333–376.
Tielens A. G. G. M., Tokunaga A. T., Geballe T. R. and Baas F. 1991, Interstellar solid CO: Polar and nonpolar interstellar ices, ApJ 381, 181–199.
van Uzendoorn L.J., Allamandola L.J., Baas F., Greenberg J.M. 1983, Visible spectroscopy of matrix isolated HCO, J. Chem. Phys. 78, 7019–7018.
Whittet, D.C.B., Schutte, W.A., Tielens, A.G.G.M., Boogert, A.C.A., de Graauw, Th., Ehrenfreund, P., Gerakines, P.A., Helmich, F.P., Prusti, T., and van Dishoeck, E. F. 1996, An ISO view of interstellar ices-First results, A&A 315, L357–L360.
Willner S. P., Gillett F. C, Herter T. L., Jones B., Merrill K. M., Pipher J. L., Puetter R. C, Rudy R. J., Russell R. W. and Soifer B. T. 1982, Infrared spectra of protostars: Composition of the dust shells, ApJ 253, 174–187.
Yamada H., Person W.B. 1964,, Absolute infrared intensities of the fundamental absorption bands is solid CO2 and N2O, J. Chem. Phys. 41, 2478–2487.
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Schutte, W.A. (1999). Laboratory Simulation of Processes in Interstellar Ices. In: Greenberg, J.M., Li, A. (eds) Formation and Evolution of Solids in Space. NATO ASI Series, vol 523. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4806-1_12
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