Skip to main content
SpringerLink
Log in

MHD and Micro-MHD Effects in Electrochemical Systems

  • Chapter
Transfer Phenomena in Magnetohydrodynamic and Electroconducting Flows

Part of the book series: Fluid Mechanics and Its Applications ((FMIA,volume 51))

Abstract

Using a new type of electrode, MHDE, copper electrodeposition from acidic copper sulfate solution was examined.

Resultantly, remarkable hysteresis effect of the magnetic field on reaction rate emerged, accompanied with drastic decrease of the reaction activity.

To clarify this phenomenon, another experiment, i.e., copper dissolution in nitric acid was carried out. The results obtained exhibited the quite curious facts that in concentrated nitric acid, the dissolution process is almost blocked by magnetic field, whereas dilute nitric acid, on the contrary, makes acceleration of the dissolution.

All these results revealed the existence of micro-scopic MHD flow induced by the micro-scale electrochemical process and the magnetic field, which affects the unstable growth of the concentration fluctuation of copper ion to restrain or enhance the reaction.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. J. Sakuraba, M. Ishihara, S. Yasuhara, K. Jikihara, K. Watazawa, T. Hasebe, C.-K. Chong, Y. Yamada and K. Watanabe, IEICE TRANS. ELECTRON., E78-C (1995) 535.

    Google Scholar 

  2. E. Beaugnon and R. Tournier, J. Phys. III France 1(1991) 1423.

    Article  Google Scholar 

  3. S. Ueno and M. Iwasaka, J. Appl. Phys. 75(1994) 7177.

    Article  Google Scholar 

  4. N. Hirota, T. Honma, H. Sugawara, K. Kitazawa, M. Iwasaka, S. Ueno, H. Yokoi, Y. Kakudate, S. Fujiwara and M. Kawamura, Jpn. J. Appl. Phys. 34 (1995)L991–L993.

    Article  CAS  Google Scholar 

  5. A. Yamagishi, Handai Kyojiba, 7 (1993) 43.

    Google Scholar 

  6. H. Sata, M. Yamato and E. Ito, Rep. Prog. Polym. Phys. Jpn. 36 (1993)199.

    Google Scholar 

  7. R. Aogaki, K Fueki and T. Mukaibo, Denki Kagaku 43 (1975) 504.

    CAS  Google Scholar 

  8. R. Aogaki, K. Fueki and T. Mukaibo, Denki Kagaku 43 (1975) 509.

    CAS  Google Scholar 

  9. R. Aogaki, K. Fueki and T. Mukaibo, Denki Kagaku 44 (1976) 89.

    CAS  Google Scholar 

  10. S._ Yamanaka, R. Aogaki, M. Yamato, E. Ito and I. Mogi, Sci. Rep. RITU A-vol.1, 38 (1993)399.

    CAS  Google Scholar 

  11. A. Tadano and R. Aogaki, E. Ito, S. Morisaki, and I. Mogi, submitted to J. Electrochem. Soc..

    Google Scholar 

  12. R. Aogaki, J. Chem. Phys. 103 (1995) 8616.

    Article  CAS  Google Scholar 

  13. A. Tadano and R. Aogaki, J. Chem. Phys. 106 (1997) 6126.

    Article  CAS  Google Scholar 

  14. R. Aogaki, J. Electrochem. Soc. 142 (1995) 2954.

    Article  CAS  Google Scholar 

  15. M. Asanuma and R. Aogaki, J. Chem. Phys. 106 (1997) 9930.

    Article  CAS  Google Scholar 

  16. N. Sato, “Electrode Chemistry”, Vol. 2, P. 365, Nittetsu-Gijutsu Jyoho Center, Tokyo (1994).

    Google Scholar 

  17. N. Sato, “Electrode Chemistry”, Vol. 2, P. 359, Nittetsu-Gijutsu Jyoho Center, Tokyo (1994).

    Google Scholar 

  18. K. Shinohara and R. Aogaki, in the course of submission.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. National Research Laboratory for Magnetic Science, Japan Science and Technology Corporation, 1-1-56, Shibashimo, Kawaguchi, Saitama, 333, Japan

    Ryoichi Aogaki, Atsushi Tadano & Kenji Shinohara

  2. Department of Product Design, Polytechnic University, 4-1-1, Hashimoto-dai, Sagamihara, 229, Japan

    Ryoichi Aogaki, Atsushi Tadano & Kenji Shinohara

Authors
  1. Ryoichi Aogaki
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Atsushi Tadano
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kenji Shinohara
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Industrial and Geophysical Flows Laboratory, Institute of Mechanics Grenoble, France

    A. Alemany , Ph. Marty  & J. P. Thibault ,  & 

Rights and permissions

Reprints and permissions

Copyright information

© 1999 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Aogaki, R., Tadano, A., Shinohara, K. (1999). MHD and Micro-MHD Effects in Electrochemical Systems. In: Alemany, A., Marty, P., Thibault, J.P. (eds) Transfer Phenomena in Magnetohydrodynamic and Electroconducting Flows. Fluid Mechanics and Its Applications, vol 51. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4764-4_12

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-4764-4_12

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6002-8

  • Online ISBN: 978-94-011-4764-4

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation