Abstract
Inorganic-organic composite absorbers consisting of finely divided inorganic ion-exchangers incorporated into a binding matrix of modified polyacrylonitrile are described. List of the available absorbers is given. Their properties (namely chemical and radiation stability) are specified. Examples of application for the treatment of liquid radioactive waste of various origin are described in detail. Further, possibilities of absorbers regeneration and treatment for final disposal are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Clearfield, A. (ed.) (1983) Inorganic ion exchange materials, CRC Press Inc., Boca Raton, Florida.
Vesely, V. and Pekárek, V. (1972) Synthetic inorganic ion-exchangers, Talanta 19, 219–262.
Waste treatment and immobilization technologies involving inorganic sorbents (1997) IAEA-TECDOC-947, IAEA, Vienna.
Sebesta, F. (1997) Composite absorbers consisting of inorganic ion-exchangers and polyacrylonitrile binding matrix. I. Methods of modification of properties of inorganic ion-exchangers for application in column packed beds, J. Radioanal. Nucl. Chem. 220, 77–88.
Sebesta, F., Motl, A., John, J., Pratsky, M. and Binka J. (1993) Composite Ion-Exchangers and their Possible Use in Treatment of Low/Intermediate Level Liquid Radioactive Wastes. In: R. Baschwitz, et al. (eds.) Proc. 19931nt. Conf. Nucl. Wastes Management and Environmental Remediation, September 5–11, 1993, Prague; ASME, New York, Vol. 3, pp.871–878.
Sebesta, F. and tefula, V. (1990) Composite ion exchanger with ammonium molybdophosphate and its properties, J. Radioanal. Nucl. Chem., Articles 140, 15–21.
Sebesta, F., John, J., Motl, A., Uvirová K. and Smréková, S. (1998) New generation of composite absorbers with polyacrylonitrile binding matrix, in 13 h’ Radiochemical Conference, April 19–24, 1998, Mariánské Lázně-Jáchymov, Czech Republic.
Sebesta, F., John, J., Motl, A. and Watson J. (1995) Development of PAN-based absorbers for treating waste problems at U.S. DOE facilities, in S. Slate, F. Feizollahi and J. Creer (eds.), ICEM’95 Proc. The Fifth International Conference on Radioactive Waste Management and Environmental Remediation, September 3–7, 1995, Berlin; ASME, New York, Vol. 1, pp.361–365.
Sebesta, F., John, J., Motl, A. and tamberg, K. (1995) Evaluation of polyacrylonitrile (PAN) as a binding polymer for absorbers used to treat liquid radioactive wastes, SAND95–2729, 46 pp.
Sebesta, F., John, J., Motl, A. Evaluation of PAN—based inorganic—organic composite absorbers for chemical separation applications at DOE sites, Part II: Development and testing of PAN absorbers for treatment of alkaline waste streams, to be published as a report of Idaho National Engineering and Environmental Laboratory (INEEL).
Sebesta, F., John, J. and Motl, A. (1994) Separation and Concentration of Contaminants Using Inorganic-Organic Composite Absorbers, in Proc. BUDAPEST ’84 Second International Symposium and Exhibition on Environmental Contamination in Central and Eastern Europe, Budapest, Hungary, September 20–23, 1994; Florida State University, Tallahassee, FL, pp.1052–1055.
Šebesta, F., John, J. and Motl, A. (1994) Inorganic-Organic Composite Absorbers with Polyacrylonitrile Binding Matrix - Possible Applications, in Proc. SPECTRUM ’84 Nuclear and Hazardous Waste Management International Topical Meeting, Atlanta, USA, August 14–18, 1994, ANS, LaGrange Park, II, Vol. 2, pp.856–861.
Šebesta, F. (1996) Present status of PAN-based absorbers technology, in Proc. WARSAW ’86 Third International Symposium and Exhibition on Environmental Contamination in Central and Eastern Europe, Warsaw, Poland, September 10–13, 1996, Florida State University, Tallahassee, FL, pp. 693–695.
Šebesta, F., John, J. and Motl, A. (1997) Development of composite ion exchangers and their use in treatment of liquid radioactive waste, in see Ref. 3, pp.79–103.
Field, D.P., Harding, K., Hooper, E.W., Keltot, D., Krásny, D., Sebesta, F. (1998), Caesium removal from fuel pond waters using a composite ion exchanger containing nickel hexacyanoferrate, in Proc. 13 th ’ Radiochemical Conference, April 19–24, 1998, Mariánské Lázné—Jáchymov, Czech Republic, Czechoslovak J. Physics, in press.
Šebesta, F., John, J. and Motl, A. Evaluation of PAN—based inorganic—organic composite absorbers for chemical separation applications at DOE sites, Part I: Pilot plant hot cell demonstration of PAN-technology at INEEL CPP, to be published as a report of Idaho National Engineering and Environmental Laboratory (INEEL).
Šebesta, F., John, J., Motl, A. (1997) Removal of cesium and strontium from highly saline acidic or alkaline HLW using PAN based composite absorbers, in R. Baker, S. Slate and G. Benda (eds.), in ICEM’97 Proc. The Sixth International Conference on Radioactive Waste Management and Environmental Remediation,October 12–16, 1997, Singapore; ASME, New York, pp.241–244.
Brewer, K.N., Todd, T.A., Wood, D.J., Tullock, P.A., Šebesta, F., John, J., Motl, A. (1998) AMP-PAN column tests for the removal of 137Cs from actual and simulated INEEL high-activity wastes, in Proc. 13` h Radiochemical Conference, April 19–24, 1998, Mariánské Lázné—Jáchymov, Czech Republic, Czechoslovak J. Physics, in press.
Šebesta, F., John, J., Motl, A. (1996) Phase II Report on the Evaluation of Polyacrylonitrile (PAN) as a Binding Polymer for Absorbers Used to Treat Liquid Radioactive Wastes, SAND96–1088, 29 pp.
Šebesta, F., John, J., Bühler, C., Raz, U. (1994) Treatment of underground water contaminated by 137Cs at NAGRA Grimsel Test Site, Switzerland, in Proc. SPECTRUM ’84 Nuclear and Hazardous Waste Management International Topical Meeting, Atlanta, USA, August 14–18, 1994, ANS, LaGrange Park, II, Vol. 2, pp. 231–236.
Šebesta, F., Motl, A., John, J. (1997) Evaluation of the potential for the use of ammonium reagents for the elution of cesium from the AMP—PAN/SF02 absorber, Czech Technical University in Prague, 30 pp.
Šebesta, F., John, J., Motl, A., Peka, V., Vacková, E. (1997) Composite absorbers consisting of inorganic ion-exchangers and polyacrylonitrile binding matrix. III. Options for treatment of spent composite absorbers for final disposal, J. Radioanal. Nucl. Chem. 220, 65–67.
John, J., Šebesta, F., Motl, A. (1997) Composite absorbers consisting of inorganic ion-exchangers and polyacrylonitrile binding matrix: Leaching of 137Cs from cemented NiFC-PAN absorber, Radiochim. Acta 78, 131–135.
Motl, A., John, J., Šebesta, F. Composite absorbers consisting of inorganic ion-exchangers and polyacrylonitrile binding matrix. V. Influence of the ionising radiation on the leachability of 13 Cs from cemented composite NiFC-PAN absorber, J. Radioanal. Nucl. Chem. 220, 205–207.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1999 Springer Science+Business Media Dordrecht
About this chapter
Cite this chapter
John, J., Ĺ ebesta, F., Motl, A. (1999). Application of New Inorganic-Organic Composite Absorbers with Polyacrylonitrile Binding Matrix for Separation of Radionuclides from Liquid Radioactive Wastes. In: Choppin, G.R., Khankhasayev, M.K. (eds) Chemical Separation Technologies and Related Methods of Nuclear Waste Management. NATO Science Series, vol 53. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4546-6_9
Download citation
DOI: https://doi.org/10.1007/978-94-011-4546-6_9
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-5639-4
Online ISBN: 978-94-011-4546-6
eBook Packages: Springer Book Archive