Abstract
Spontaneous polarity formation in molecular crystals is a key issue in the design of materials featuring tensorial properties of interest to technical applications. This review discusses theoretical models for the prediction of spontaneous polarity formation in channel-type zeolites, channel-type inclusion compounds and organic solid solutions. Theoretical models presented here are based on a general principle of polarity formation, typical for growth processes where dipolar compounds are attached to surfaces.
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Hulliger, J., Roth, S.W., Quintel, A. (1999). The Prediction and Production of Polarity in Crystalline Supramolecular Materials. In: Braga, D., Grepioni, F., Orpen, A.G. (eds) Crystal Engineering: From Molecules and Crystals to Materials. NATO Science Series, vol 538. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4505-3_20
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