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Rational Design of Polar Solids

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Crystal Engineering: From Molecules and Crystals to Materials

Part of the book series: NATO Science Series ((ASIC,volume 538))

Abstract

Solids that crystallize in acentric space groups are predisposed to exhibit useful bulk physical properties in the context of new materials for electrooptical applications’, especially devices based upon second-order nonlinear optic (NLO), piezoelectric, pyroelectric or ferroelectric activity. It should therefore be unsurprising that the pursuit of new classes of acentric, or polar, solids has been ongoing for many years. Although a crystallographic center of inversion can be precluded by building materials from homochiral components, there are two significant limitations: (1) requirements for homochiral starting materials and/or products are significant hurdles for synthetic chemists; (2) the use of homochiral building blocks does not in any way ensure optimum alignment of dipoles. The potential importance of new design strategies that are independent of the need for chiral building blocks should therefore be apparent.

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  1. The University of Winnipeg 515 Portage Ave., Winnipeg, Manitoba, R3B 2E9, Canada

    B. Moulton & M. J. Zaworotko

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  1. B. Moulton
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  1. Dipartimento di Chimica, UniversitĂ  di Bologna, Bologna, Italy

    Dario Braga

  2. Dipartimento di Chimica, UniversitĂ  di Sassari, Sassari, Italy

    Fabrizia Grepioni

  3. School of Chemistry, University of Bristol, Bristol, UK

    A. Guy Orpen

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Moulton, B., Zaworotko, M.J. (1999). Rational Design of Polar Solids. In: Braga, D., Grepioni, F., Orpen, A.G. (eds) Crystal Engineering: From Molecules and Crystals to Materials. NATO Science Series, vol 538. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4505-3_18

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