Abstract
Spinel ferrites are derived from magnetite Fe3O4 by partial substitutions of the iron ions by other metallic cations. Their chemical composition can accordingly be described by a simple chemical formula such as MxM’y...Fe3-x-y...O4 where M, M’... are metallic cations. Spinel ferrites have mainly been prepared and studied in two forms, powders coarse-grained and bulk ceramics. These phases are very close to stoichiometry, i.e. the metallic cations/oxygen anions ratio is close to 3/4, because of their poor reactivity to oxygen. They also have a high structural stability, most of them retaining the spinel structure above 1000 to 1500°C.
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Tailhades, P. (1999). Original Spinel Ferrites for New Mass Storage Media. In: Nedkov, I., Ausloos, M. (eds) Nano-Crystalline and Thin Film Magnetic Oxides. NATO Science Series, vol 72. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4493-3_1
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DOI: https://doi.org/10.1007/978-94-011-4493-3_1
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