Abstract
Pollution prevention is one of the key objectives of a processing facility. Notwithstanding its importance, it must be reconciled with other process objectives such as cost effectiveness, quality assurance, yield enhancement, debottlenecking, safety, and energy conservation. For many years, environmental issues of manufacturing operations have been conveniently isolated and addressed with little or no interaction with the other process objectives. The result has been a widespread adoption of pollution control, strategies that focus primarily on end-of-pipe treatment, in which chemical, biological, and physical processes are applied to terminal,streams to reduce toxicity or magnitude of environmentally undesirable compounds. This approach has enabled engineers to avoid in-plant changes and has, therefore, allowed the development of pollution-control technologies as stand-alone devices that can be used to treat the symptoms without much regard to the root causes within the core processing operations. The result has been in the form of solutions that worked but nonetheless had poor economic indicators. This situation has led to the common misconception that the solution to environmental problems of the process is an economic burden and that objectives of cost effectiveness and benign manufacturing cannot be reconciled.
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References
Achenie, L. E. K., and Duvedi, A. P. (1996). Designing environmentally safe refrigerants using mathematical programming, Chem. Eng. Sci., 51 (15), 3727–3739.
Anastas, P. T. and Williamson, T. C. (eds.) (1996). “Green chemistry: Designing chemistry for the environment,” ACS Symp. Ser., vol. 626, ACS Pub., Washington, D. C.
Anastas, P. T. and Farris, C. A. (eds.) (1994). “Benign by design: Alternative synthetic design for pollution prevention,” ACS Symp. Ser., vol. 577, ACS Pub., Washington, D. C..
Beveridge, G. S. G. and Schechter, R. (1970).Optimization: Theory and Practice. McGraw Hill, New York.
Brignole, E. A., Bottini, S., and Gani, R. (1986). A strategy for the design and selection of solvents for separation processes, Fluid Phase Equilibria, 29, 125–132.
Cabezas, H. and R. Zhao (1998). Designing environmentally benign solvents: Physical property considerations. AIChE Spring Meeing, New Orleans, March.
Chase, V. (1995). Green chemistry: The middle way to a cleaner environment. R & D Magazine, 25–26, August
Constantinou, L., Jacksland, C., Bagherpour, K., Gani, R. and Bogle, L. (1994). Application of group contribution approach to tackle environmentally-related problems, AIChE Symp. Ser., 90 (303), 105–116.
Crabtree, E. W. and El-Halwagi, M. M. (1994). Synthesis of environmentally-acceptable reactions, AIChE Symp. Ser, 90(303), 117–127.
Dhole, V. R., Ramchandani, N., Tainsh, R. A., and Wasilewski, M. (1996). Make your process water pay for itself, Chem. Eng., January, pp. 100–103.
Douglas, J. M. (1992). Process synthesis for waste minimization. Ind. Eng. Chem. Res., 31, 238–243.
Dunn, R. F., A. M. Dobson, and M. M. El-Halwagi (1997) “Optimal Design of Environemntally Acceptable Solvent Blends for Coating,”Adv. Env. Res. 1(2), 243–252.
Dunn, R. F. and El-Halwagi, M. M. (1993). Optimal recycle/reuse policies for minimizing the wastes of pulp and paper plants, Environ. Sci. Health A28 (1), 217–234.
Dunn, R. F., and El-Halwagi, M. M. (1996). Design of cost-effective VOC recovery systems. TVA Pub., Muscle Shoals, AL.
Dunn, R. F., and El-Halwagi, M. M. (1994a). Optimal design of multicomponent VOC Condensation Systems, J. Hazard. Mater., 38, 187–206.
Dunn, R. F., and El-Halwagi, M. M. (1994b). Selection of optimal VOC condensation systems, J. Waste Manage. 14 (2), 103–113.
Dunn, R. F., and B. K. Srinivas, “Synthesis of Heat-Induced Waste Minimization Networks (HIWAMINs),” Adv. Env. Res., 1 (3), pp. 275–301 (1997).
Dunn, R. F., Zhu, M., Srinivas, B. K., and El-Halwagi, M. M. (1995). Optimal design of energy induced separation networks for VOC recovery, AIChE Symp. Ser. 90 (303), 74–85.
Dunn, R. F., El-Halwagi, M. M., Lakin, J., and Serageldin, M. (1995). Selection of organic solvent blends for environmental compliance in the coating industries. Proceedings of the First International Plant Operations and Design Conference, eds. E. D. Griffith, H. Kahn and M. C. Cousins, Vol. III, pp. 83–107, AIChE, New York.
Dye, S. R., Berry, D. A. and Ng, K. M. (1995). Synthesis of crytallization-based separation schemes, AIChE Symp. Ser., 91 (304), 238–241.
Edgar, T. F. and Himmelblau, D. M. (1988). Optimization of chemical processes. McGraw Hill, New York.
El-Halwagi, M. M. (1997) “Pollution Prevention through Process Integration: Systematic Design Tools,” AcademicPress, San Diego.
El-Halwagi, M. M. (1993). A process synthesis approach to the dilemma of simultaneous heat recovery, waste reduction and cost effectiveness. In “Proceedings of the Third Cairo International Conference on Renewable Energy Sources” (A. I. El-Sharkawy and R. H. Kummler, eds.), Vol. 2, pp. 579–594.
El-Halwagi, M. M. (1993). Optimal design of membrane hybrid systems for waste reduction, Sep. Sci. Technol. 28 (1–3), 283–307.
El-Halwagi, M. M., (1992). Synthesis of reverse osmosis networks for waste reduction, AIChE J.,38 (8),1185–1198.
El-Halwagi A. M., and El-Halwagi, M. M. (1992). Waste minimization via computer aided chemical process synthesis-A new design philosophy, TESCE J. 18 (2), 155–187.
El-Halwagi, M. M., El-Halwagi, A. M., and Manousiouthakis, V. (1992). Optimal design of dephenolization networks for petroleum-refinery waste, Trans. Inst. Chem. Eng. 70, Part B,131–139.
El-Halwagi, M. M., Hamad, A. A. and Garrison, G. W. (1996). Synthesis of waste interception and allocation networks, AIChE J., 42(11), 3087–3101.
El-Halwagi, M.M. and Manousiouthakis, V. (1989a). Synthesis of mass-exchange networks, AIChE J., 35 (8), 1233–1244.
El-Halwagi, M. M., and Manousiouthakis, V. (1989b). Design and analysis of mass exchange networks with multicomponent targets, AIChE Annu. Meet., San Francisco, November.
El-Halwagi, M. M., and Manousiouthakis, V. (1990a). Automatic synthesis of mass exchange networks with single-component targets, Chem. Eng. Sci. 45 (9), 2813–2831.
El-Halwagi, M. M., and Manousiouthakis, V. (1990b). Simultaneous synthesis of mass exchange and regeneration networks, AIChE J., 36 (8),1209–1219.
El-Halwagi, M. M. and Spriggs, H. D. (1998). Solve Design Puzzles with Mass Integration, Chem. Eng. Prog., August, pp. 25–44.
El-Halwagi, M. M. and Spriggs, H. D. (1996). An integrated approach to cost and energy efficient pollution prevention. Proceedings of Fifth World Congr. of Chem. Eng., Vol. III, pp. 344–349, San Diego.
El-Halwagi, M. M and Srinivas, B. K. (1992). Synthesis of reactive mass exchange networks, Chem. Eng. Sci., 47 (8), 2113–2119.
El-Halwagi, M.M., Srinivas, B. K., and Dunn, R. F. (1995). Synthesis of optimal heat-induced separation networks, Chem. Eng. Sci., 50 (1),81–97.
Evangelista, F. (1986). Improved graphical analytical method for the design of reverse osmosis desalination plants, Ind. Eng. Chem. Process Des. Dey., 25 (2), 366–375.
Garrison, G. W., Spriggs, H. D., and El-Halwagi, M. M. (1996). A global approach to integrating environmental, energy, economic and technological objectives. Proceedings of Fifth World Congr. of Chem. Eng., Vol. I, pp. 675–680, San Diego.
Garrison, G. W., Hamad, A. A. and El-Halwagi, M. M. (1995a). Synthesis of waste interception networks. AIChE Annu. Meet., Miami.
Garrison, G. W., Cooley, B. L., and El-Halwagi, M. M. (1995b). Synthesis of mass exchange networks with multiple target mass separating agents, Dev. Chem. Eng. Miner. Proc. 3 (1), 31–49
Grossmann, I. E., Editor Global Optimization in Engineering Design, Kluwer Academic Pub., Dordrecht, The Netherlands, 1996
Gundersen, T. and Naess, L. (1988). The synthesis of cost optimal heat exchanger networks: an industrial review of the state of the art, Comput. Chem. Eng., 12 (6), 503–530.
Hallale, N., and D. M. Fraser, (1997). Synthesis of Cost Optimum Gas Treating Process Using Pinch Analysis. Proceedings, Top. Conf. on Sep. Sci. and Techs., W. S. Ho, and R. G. Luo, eds., Part II, pp. 1,708–1,713, AIChE, New York.
Hamad, A. A., V. Varma, G. Krishnagopalan, and M. M. El-Halwagi (1998). Application of Mass Integration to Reduce Methanol and Effluent Discharge in Pulp Mills TAPPI J., October.
Hamad, A. A., and M. M. El-Halwagi, (1998). Simultaneous Synthesis of Mass Separating Agents and Interception Networks, Trans. I. Chem. E., 76, Part A, pp. 376–388.
Hamad, A. A., Garrison, G. W., Crabtree, E. W. and El-Halwagi, M. M. (1996). Optimal design of hybrid separation systems for waste reduction. Proceedings of Fifth World Congr. of Chem. Eng., Vol. III, pp. 453–458, San Diego.
Hamad, A. A., Varma, V., El-Halwagi, M. M. and Krishnagopalan, G. (1995). Systematic integration of source reduction and recycle reuse for the cost-effective compliance with the cluster rules. AIChE Annu. Meet., Miami.
Hilaly, A. and S. Sikdar, Process Simulation Tools for Pollution Prevention: New Methods Reduce the Magnitude of Waste Streams, Chem. Eng., pp. 98–105, Feb. 1996.
Huang, Y. L., and Fan, L. T. (1995). Intelligent process design and control for in-plant waste minimization. In Waste Minimization Through Process Design (A. P. Rossiter, eds.), pp.165–180. McGraw Hill, New York.
Huang, Y. L., and Edgar, T. F. (1995). Knowledge based design approach for the simultaneous minimization of waste generation and energy consumption in a petroleum refinery. In Waste Minimization Through Process Design (A. P. Rossiter, eds.), pp. 181–196. McGraw Hill, New York.
Joback, K. G. (1994) Solvent Substitution for Pollution Prevention, AIChE Symp. Ser. 90 (303), 98–104.
Joback, K. G., and Stephanopoulos, G. (1990). Designing molecules possessing desired physical property values. In Foundations of Computer Aided Process Design ‘FOCAPD’ III (J. J. Siirola, I. Grossmann, and G. Stephanopoulos, eds.), pp. 363–387. CACHE/Elsevier, New York.
Kiperstok, A., and Sharratt, P. N. (1995). On the optimization of mass exchange networks for removal of pollutants, Trans. Inst. Chem. Eng. 73, Part B, 271–277.
Kuo, W. C. J. and R. Smith, Designing for the Interactions Between Water Use and Effluent Treatment, Trans. Inst. Chem. Eng., 76, Part A, 287–301, 1998.
Linnhoff, B., Townsend, D. W., Boland, D., Hewitt, G. F., Thomas, B. E. A., Guy, A. R., and Marsland, R. H. (1994). A User Guide on Process Integration for the Efficient Use of Energy., Revised 1st Ed., Institution of Chemical Engineers, Rugby, UK.
Linnhoff, B. (1993). Pinch analysis- A state of the art overview, Trans. Inst. Chem. Eng. Chem. Eng. Res. Des., 71, Part A5, 503–522.
Malone, M. F. and Doherty, M. F. (1995). Separation system synthesis for nonideal liquid mixtures. AIChE Symp. Ser., 91 (304), 9–18.
Naser, S. F. and Fournier, R. L. (1991). A system for the design of an optimum liquid-liquid extractant molecule. Comp. Chem. Eng., 15 (6), 397–414.
Nishida, N., Stephanopoulos, G., and Westerberg, A. (1981). A review of process synthesis. AIChE J., 27 (3), 321–351.
Noureldin, M. B. and M. M. El-Halwagi (1998). A shortcut approach to integrating design and operation. AIChE Spring Meeting, New Orleans, March.
Odele, O. and Macchietto, S. (1993). Computer aided molecular design: A novel method for optimal solvent selection. Fluid Phase Equilibria, 82, 47–54.
Parthasarathy, G. and El-Halwagi M. M. (1997) “Mass Integration for Multicomponent Nonideal Systems,” presented at AIChE Annual Meeting (Los Angeles), AIChE, New York.
Papalexandri, K. P., and Pistikopoulos, E. N. (1994). A multiperiod MINLP model for the synthesis of heat and mass exchange networks. Comput. Chem. Eng. 18 (12), 1125–1139.
Reklaitis, G. V., Ravindran A., and Ragsdell, K. M. (1983). Engineering Optimization. Wiley, New York.
Richburg, A. and El-Halwagi, M. M. (1995). A graphical approach to the optimal design of heat-induced separation networks for VOC recovery. AIChE Symp. Ser., 91 (304), 256–259.
Rudd, D. F., Powers, G.J. and Siirola, J. J. (1973). “Process Synthesis”;, Prentice Hall, Inc., New Jersey.
Sahinidis, N. V. and Grossmann, I. E. (1991). Convergence properties of generalized Benders decomposition“ Comput. Chem. Eng., 15 (7), 481–491.
Shelley, M., G. Parthasarathy, and M. El-Halwagi (1998). Clustering Techniques for the Optimal Design of Processing Facilities for Complex Hydrocarbons. AIChE Annual Meeting, Miami, November.
Shenoy, U. V. (1995). “Heat Exchange Network Synthesis: Process Optimization by Energy and Resource Analysis.” Gulf Pub. Co., Houston, TX.
Spriggs, H. D., “Design for Pollution Prevention,” AIChE Symp. Ser., 90 (303), pp. 1–11 (1995).
Srinivas, B. K., and El-Halwagi, M. M. (1994a). Synthesis of reactive mass-exchange networks with general nonlinear equilibrium functions. AIChE J. 40(3), 463–472.
Srinivas, B. K., and El-Halwagi, M. M. (1994b). Synthesis of combined heat reactive mass-exchange networks. Chem. Eng. Sci, 49 (13), 2059–2074.
Srinivas, B. K., and M. M. El-Halwagi, (1993). Optimal Design of Pervaporation Systems for Waste Reduction.
Comp. Chem. Eng. 17 (10), pp. 957–970.
Stanley, C., and M. M. El-Halwagi, (1995). Synthesis of Mass-Exchange Networks Using Linear
Programming Techniques. In “Waste Minimization through Process Design,” A. P. Rossiter
ed., pp. 209–224, McGraw-Hill, New York.
Stephanopoulos, G. and Townsend, D. (1986). Synthesis in process development.Chem. Eng. Res. Des., 64 (3), 160–174.
US EPA (1994). Paris Manual. EPA, Cincinnati, Ohio.
Vaidyanathan, R. and El-Halwagi, M. M. (1994a). Global optimization of nonconvex nonlinear programs via interval analysis . Comput. Chem. Eng., 18 (10), 889–897.
Vaidyanathan, R and El-Halwagi, M. M. (1994b). Computer-aided design of high performance polymers. J. of Elastomers and Plastics, 26,277–293.
Vaidyanathan, R. and El-Halwagi, M. M. (1996a). Global optimization of nonconvex MINLP’s by interval analysis. In “Global Optimization in Engineering Design,” (I. E. Grossmann, ed.), pp. 175–194. Springer Science+Business Media Dordrecht, Dordrecht, The Netherlands.
Vaidyanathan, R and El-Halwagi, M. M. (1996b). Computer-Aided synthesis of polymers and blends with target properties. Ind. Eng. Chem. Res., 35, 627–634.
Venkatasubramanian, V., Chan, K., and Cauthers, J. M. (1994). Computer-aided molecular design using genetic algorithms. Comp. Chem. Eng., 18, 833–844.
Visweswaran, V. and Floudas, C. A. (1990). A global optimization procedure for certain classes of nonconvex NLP’s--II. application of theory and test problems“Comput. Chem. Eng., 14 (2), 1419–1434.
Wahnschafft, O. M., Jurian, T. P., and Westerberg, A. W. (1991). SPLIT: A separation process designer. Comput. Chem. Eng., 15,565–581.
Wang, Y. P., and Smith, R. (1994). Wastewater minimization. Chem. Eng. Sci. 49 (7), 981–1006.
Warren, A., Srinivas, B. K., and El-Halwagi, M. M. (1995). Design of cost-effective waste-reduction systems for synthetic fuel plants.J. Environ. Eng. 121 (10), 742–747.
Westerberg, A. W. (1987). Process synthesis: A morphological view. In “Recent Developments in Chemical Process and Plant Design,” (Y. A. Liu, H. A. McGee, Jr., and W. R. Epperly, eds). pp. 127–145. Wiley, New York.
Zhu, M., and El-Halwagi, M.M. (1995). Synthesis of flexible mass exchange networks.Chem. Eng. Commun.., 138,193–211.
Zhu, M., El-Halwagi, M. M., and M. Alahmad (1997). Optimal design and scheduling of flexible reverse-osmosis networks.J. Membrane Sci. 129, 161–174.
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El-Halwagi, M.M. (1999). Sustainable Pollution Prevention Through Mass Integration. In: Sikdar, S.K., Diwekar, U. (eds) Tools and Methods for Pollution Prevention. NATO Science Series, vol 62. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4445-2_16
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