Abstract
High pressure studies of solid electrolytes [1] or molten salts mixtures [2] have been a very valuable tool in order to determine the nature of charge carriers and to investigate ionic transport mechanisms. More recently, such studies have concerned polymer electrolytes [3–5]. In that case, ionic transport occurs concurrently by anionic and cationic migrations. This simultaneous transport of anions and cations makes difficult the interpretation of electrical conductivity measurements with temperature and pressure. During this work, we have used a new family of polymer electrolytes in which the transport number of alkali cation is unity because the counter anion is fixed on polymeric chains.
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Brylev, O., Duclot, M., Alloin, F., Sanchez, JY., Souquet, JL. (2000). Single Conductive Polymer Electrolytes: From Pressure Conductivity Measurements to Transport Mechanism. In: Julien, C., Stoynov, Z. (eds) Materials for Lithium-Ion Batteries. NATO Science Series, vol 85. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4333-2_32
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DOI: https://doi.org/10.1007/978-94-011-4333-2_32
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