Abstract
Since the beginning of the 90s the manganese dioxide became the most investigated material for lithium secondary cells. Many attempts have been made to elucidate the factors influencing the rechargeability and the cyclability of the MnO2 and to improve its electrochemical characteristics. The appearance of cathode materials with high energy density based on lithiated transition metal oxides as Co, Ni, or Mn, and high discharge voltage of 4 V, shifted the main interest to them. But the problems arise faster: oxidation of the electrolyte due to the high operation potential dissolution of some active cathode materials, fast self-discharge, etc.
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References
Ilchev, N., Manev, V., and Hamparzumian, K. (1989) The lithium-manganese dioxide cell: II Behavior of MnO2 in non-aqueous electrolyte, J. Power Sources 25, 177.
Ilchev, N. and Banov, B. (1991) The Lithium-Manganese Dioxide Cell. IV. Relationship between physicochemical properties and electrochemical characteristics of manganese dioxides in nonaqueous electrolytes, J. Power Sources 35, 175.
Ilchev, N., Banov, B., Kvachkov, R. (1994) “Physicochemical characteristics and electrochemical behavior of MnO2 in primary lithium cells”, 6th IMLB Ext. Abstr. p. 416.
Ilchev, N., Banov, B., and Bourilkov, Y. (1994) Reversible cathode material obtained by electrochemical reduction of MnO2 in nonaqueous electrolyte, 6th IMLB Ext. Abstr. p. 329.
Ilchev, N. and Banov, B. (1991) Research Studies of the Li/MnO2 System, Progress in Batt. & Batt. Materials, JEC Press 10, 232.
Li, L. and Pistoia, G. (1991) Secondary Li cells: A composition of the behaviour of cathodes based on pure and lithiated manganese oxides, Solid State Ionics 47, 231.
Li, L. and Pistoia, G. (1991) Secondary Li Cells: Characteristics of lithiated manganese oxides synthesized from LiNO3 and MnO2, Solid State Ionics 47, 241.
Huang, H. and Bruce, P. (1994) A 3-V lithium manganese oxide cathode for rechargeable lithium batteries, J. Electrochem. Soc. 141, L76.
Kurimoto, H., Suzuoka, K., Murakami, T., Xia, Y., Nakamura, H., and Yoshio, M. (1995) High surface area electromigration damage for 3V Li cell cathodes, J. Electrochem. Soc. 142, 2156.
Yoshio, M., Noguchi, H., Miyashita, T., Nakamura, H., and Kozawa, A. (1995) Three or 4 V Li-Mn composite as cathode in Li batteries prepared by LiNO2 method as Li source, J. Power Sources, 54, 483.
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© 2000 Springer Science+Business Media Dordrecht
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Banov, B., Trifonova, A., Momchilov, A., Puresheva, B. (2000). New Generation of 3-Volt Lithiated Manganese Oxide for High-Performance Lithium Batteries. In: Julien, C., Stoynov, Z. (eds) Materials for Lithium-Ion Batteries. NATO Science Series, vol 85. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4333-2_25
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DOI: https://doi.org/10.1007/978-94-011-4333-2_25
Publisher Name: Springer, Dordrecht
Print ISBN: 978-0-7923-6651-5
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