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Modelling Complex Kinetic Systems

Part 1. Steady-State and Transient-State

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Combinatorial Catalysis and High Throughput Catalyst Design and Testing

Part of the book series: NATO Science Series ((ASIC,volume 560))

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Abstract

Kinetic analysis is a very important tool in chemistry and catalysis. Chemistry in general, and catalysis in particular, deals with the transformation of a set of species into another set of species. These processes are rarely simple, even when using pure reactants it is quite common to have several interacting pathways present in any given system.

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References

  1. Keii, T. (1972) in Kinetics of Ziegler-Natta Polymerization, Kondasha Ltd., Tokyo.

    Google Scholar 

  2. Braks, J.G. and Huang, R.Y. (1975) J. Polymer Sci., Polym. Chem. Ed. 13, 1063.

    Article  CAS  Google Scholar 

  3. Kissin, Y.V. and Beach, D.L. (1984) J. Appt. Polymer Sci. 29, 1171.

    Article  CAS  Google Scholar 

  4. Maschio, G., Artigiani, F., Maim, M. Di, and Giusti, P. (1984) J. Appt. Polymer Sci. 29, 1215.

    Article  CAS  Google Scholar 

  5. Nirisen, O., Rytter, E., and Lindstrom, T.L. (1986) Macromol. Chem, Rapid Commun. 7, 103.

    Article  CAS  Google Scholar 

  6. Achnauss, A. and Reichert, K-H (1990) Macromol. Chem, Rapid Commun. 11, 315.

    Article  Google Scholar 

  7. Nagel, E.J., Kirillov, V.A., and Ray, W.H. (1980) Ind Eng. Chem. Prod Res. Dev. 19, 372.

    Article  CAS  Google Scholar 

  8. Sarkar, P. and Gupta, S.K. (1992) Polymer 33, 1477.

    Article  CAS  Google Scholar 

  9. Fischer, D. and Mülhaupt, R. (1991) J. Organomet. Chem. 417, C7 - C11.

    Article  CAS  Google Scholar 

  10. Huanh, J. and Rempel, G.L (1992) in K.J. Smith. and E. Sanfor (eds.), Progress in Catalysis,Elsevier Science Publ., p. 169.

    Google Scholar 

  11. Marques, M.M., Lemos, F., Costa, C., Ribeiro, F. Ramôa, and Dias, A.R. (1997) Polymer International 43, 77.

    Article  CAS  Google Scholar 

  12. Marques, M.M., Costa, C., Lemos, F., Justino, J., Ribeiro, F. Ramôa, and Dias, A.R. (1997) Polymer International 43, 86.

    Article  CAS  Google Scholar 

  13. Bonini, F., Fraaije, V., and Fink, G. (1995) J. Polymer Sci.: Part A: Polym. Chem. 33, 2393.

    Article  CAS  Google Scholar 

  14. Chien, J.C. and Wang, B.P. (1990) J. Polym. Sci. Part A: Polym. Chem. 28, 15.

    Article  CAS  Google Scholar 

  15. Vela, Estrada J. M. and Hamielec, A. E. (1994) Polymer 35, 808.

    Article  Google Scholar 

  16. Kakugo, M., Sadatochi, H., Sakai, J., and Yokoyama, M. (1989) Macromolecules 22, 3172.

    Article  CAS  Google Scholar 

  17. Ferrero, M.A, Kaffi, E., Sommer, R., and Conner, W.C. (1992) J. Polym. Sci. Part A: Polym. Chem. 30, 2131.

    Article  CAS  Google Scholar 

  18. Nagel, E.J., Kirillov, V.A., and Ray, W.H. (1980) Ind Eng. Chem. Prod Res. Dev. 19, 372.

    Article  CAS  Google Scholar 

  19. Ewen, J.A., Elder, M.J., Jones, R.L., Curtis, S., and Cheng, N.H. (1990) in K. Soga, and T. Keii (eds.), Stud Surf Sci. Catal., Elsevier, New York 56, 439.

    Google Scholar 

  20. Herfert, N. and Fink, G. (1992) Makromol. Chem. 193, 1359;

    Article  CAS  Google Scholar 

  21. Herfert, N. and Fink, G. (1993) Makromol. Chem., Macromol. Symp. 66, 157;

    Article  CAS  Google Scholar 

  22. Herfert, N. and Montag, P. (1995), in G. Fink, R. Mulhaupt, and H.H. Brintzinger (eds.) Ziegler Catalysts, Spring-Verlag; Berlin, p 159.

    Google Scholar 

  23. Jungling, S., Mulhaupt, R., Stehling, U., Brintzinger, H-H., Fischer, D. and, Langhauser, F. (1995) Macromol. Symp. 97, 205.

    Article  Google Scholar 

  24. Busico, V. and Cipullo, R. (1994) J. Am. Chem. Soc. 116, 9329;

    Article  CAS  Google Scholar 

  25. Busico, V., Cipullo, R., Chadwick, J.C., Modder, J.F. and, Sudmeijer, O. (1994) Macromolecules 27, 7538.

    Article  CAS  Google Scholar 

  26. Chien, J.C.W., Yu, Z., Marques, M., Flores, J.C., and Rausch, M.D. (1998) J. Polym. Sci.: Part A: Polymer Chemistry 36, 319.

    Article  CAS  Google Scholar 

  27. Keii, T., Soga, K., and Saiki, N. (1967) J. Polym. Sci Polym. Symp. 16, 1507.

    Google Scholar 

  28. Pino, P., Rotzinger, B., and Achenbach, B. von (1985) Makromol. Chem., Chem Suppl. 13, 105.

    Article  CAS  Google Scholar 

  29. Berger, M.N. and Grieveson, B. M. (1965) Makromol. Chem. 83, 80.

    Article  CAS  Google Scholar 

  30. Justino, J., Marques, M., Correia, S., Dias, A.R., Lemos, F., and Ribeiro, F. Ramôa (1997) Polymer International 44, 517.

    Article  CAS  Google Scholar 

  31. Justino, J., Dias, A.R., Marques, M., Correia, S., and Lemos, F. (1998) in Simposio Latiniamericano de Polímeros, IV Congresso Iberoamericano de Polímeros, October 25th - 29th, Viïla del Mar, Chile.

    Google Scholar 

  32. Soares, J.B.P. and Hamielec, A.E. (1995) Poly. React. Eng. 3, 261;

    CAS  Google Scholar 

  33. Soares, J.B.P. and Hamielec, A.E. (1996) Poly. React. Eng. 4, 153.

    CAS  Google Scholar 

  34. Resconi, L., Fait, A., Piemontesi, F., Colonnesi, M., and Rychlicki, H. (1995) R. Ziegler Macromolecules 28, 6667.

    Article  CAS  Google Scholar 

  35. Tsutsui, T., Kashiwa, N., and Mizuno, A. (1990) MakromoL Chem. Rapid Commun. 11, 565.

    Article  CAS  Google Scholar 

  36. Busico, V., Cipullo, R., and Corradini, P. (1993) Makromol. Chem. Rapid Commun. 14, 97.

    Article  CAS  Google Scholar 

  37. Jungling, S., Muihaupt, R., Stehling, U., Brintzinger, H-H., Fisher, D., and Langhauser, F. (1995) Makromol. Symp. 97, 205.

    Article  Google Scholar 

  38. Novaro, O., Chow, S. and Magnonat, P. (1976) J. Catal. 41, 91;

    Article  CAS  Google Scholar 

  39. Novaro, O. and Blaisten-Barosas, E. (1978) J. Chem. Phys. 68, 2337.

    Article  CAS  Google Scholar 

  40. Zakharov, I.I. and Zakharov, V.A. (1982) J. Mol. Catal. 14, 171.

    Article  CAS  Google Scholar 

  41. Zakharov, I.I. and Zakharov, V.A. (1983) React. Kinet. Catal. 23, 61;

    Article  CAS  Google Scholar 

  42. Zakharov, V.A. and Bukatov, G.D. (1983) Adv. Polym. Sci. 51, 61.

    Article  CAS  Google Scholar 

  43. Yasyerli, N., Dogu, T., Dogu, G., and Ar, I. (1996) Chem. Eng. Sci. 51 (11), 2523.

    Article  CAS  Google Scholar 

  44. Lizzio, A.A., Jiang, H., and Radovic, L.R. (1990) Carbon 28 (1), 7.

    Article  CAS  Google Scholar 

  45. Silva, I. Santos, Palma, C., Lemos, F., Ribeiro, F. Ramôa, and Lobo, J. Sousa (1997) in G.F. Froment and K.C. Waugh (eds.), Stud. Surf Sci. Catal.: Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis 109, 535.

    Google Scholar 

  46. Nicholson, R.S. and Shain, I. (1964) Anal. Chem. 36 (4), 706.

    Article  CAS  Google Scholar 

  47. Nicholson, R.S. and Shain, I. (1965) And Chem. 37 (2), 178.

    CAS  Google Scholar 

  48. Nicholson, R.S. (1965)Anal. Chem. 37, 1351.

    Article  CAS  Google Scholar 

  49. Polcyn, D.S. and Shain, I. (1966) Anal. Chem. 38 (3) 370.

    Article  CAS  Google Scholar 

  50. Feldberg, S.W. (1969) in A.J. Bard (ed.), Electroanalytical Chemistry - vol. 3, Marcel Dekker, New York.

    Google Scholar 

  51. Feldberg, S.W. and Auerbach, C. (1964) Anal. Chem. 36, 505.

    Article  CAS  Google Scholar 

  52. Feldberg, S.W. (1981) J. Electroanal. Chem. 127, 1.

    Article  CAS  Google Scholar 

  53. Joslin, J. and Pletcher, D. (1974) J. Electroanal Chem. 49, 171.

    Article  CAS  Google Scholar 

  54. Moulton, R.D., Bard, A.J., and Feldberg, S.W. (1988) J. Electroanal. Chem. 256, 291.

    Article  CAS  Google Scholar 

  55. Moulton, R.D., Bard, A.J., and Feldberg, S.W. (1988) J. Electroanal. Chem. 256, 291.

    Article  CAS  Google Scholar 

  56. Silva, B. Marques da, Avaca, L.A. and Gonzales, E.R. (1989) J. Electroanal. Chem. 269, 1.

    Article  Google Scholar 

  57. Britz, D., Silva, B. Marques da, Avaca, L., and Gonzales, E.R. (1990) Anal. Chim. Acta 239, 87.

    Article  CAS  Google Scholar 

  58. Feldberg, S.W. (1990) J. Electroanal. Chem. 290, 49.

    Article  CAS  Google Scholar 

  59. Lerke, S.A., Evans, D.H., and Feldberg, S.W. (1990) J. Electroanal. Chem. 296, 299.

    Article  CAS  Google Scholar 

  60. Booman, G.L. and Pence, D.T. (1965) Anal. Chem. 37, 1366.

    Article  CAS  Google Scholar 

  61. Lemos, M.A.N.D.A., Silva, M.F.C. Guedes da, and Pombeiro, A.J.L. (1994) Inorg. Chim. Acta 226, 9.

    Article  CAS  Google Scholar 

  62. Li, J.-W., Pfanner, K., and Calzaferri, G. (1995) J Phys. Chem. 99, 2119;

    Article  CAS  Google Scholar 

  63. Rolison, D.R. (1990) Chem. Rev. 90, 867.

    Article  CAS  Google Scholar 

  64. Balkus, Jr. K., Gabrielov, A.G., Bell, S.L., Bedoui, F., Roué, L., and Devynck, J. (1994) Inorg. Chem. 33, 67

    Article  CAS  Google Scholar 

  65. Bedioui, F., Boysson, E. De, Devynck, J., and Balkus, Jr. K.J. (1991) J Chem. Soc. Faraday Trans. 87(24), 3831.

    Article  CAS  Google Scholar 

  66. Lemos, M.A.N.D.A., Sousa, P., Lemos, F., Pombeiro, A.J.L., and Ribeiro, R. Ramôa (1999) in G.F. Froment and K.C. Waugh (eds.), Stud. Surf Sci. Catal.: Reactions Kinetics and the Development of Catalytic Processes, Elsevier, 122, 443.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Departamento de Engenharia Química, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001, Lisboa, Portugal

    F. Lemos, M. A. N. D. A. Lemos, C. Costa & M. M. Marques

  2. Departamento de Química, Universidade Nova de Lisboa, Monte da Caparica, Portugal

    I. S. Silva

Authors
  1. F. Lemos
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  2. M. A. N. D. A. Lemos
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  3. I. S. Silva
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  4. C. Costa
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  5. M. M. Marques
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Editor information

Editors and Affiliations

  1. Leverhulme Centre for Innovative Catalysis, University of Liverpool, UK

    Eric G. Derouane

  2. Instituto Superior Técnico, Lisboa, Portugal

    Francisco Lemos  & Fernando Ramõa Ribeiro  & 

  3. Instituto de Tecnologica Quimica, UPV-CSIC, Spain

    Avelino Corma

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Lemos, F., Lemos, M.A.N.D.A., Silva, I.S., Costa, C., Marques, M.M. (2000). Modelling Complex Kinetic Systems. In: Derouane, E.G., Lemos, F., Corma, A., Ribeiro, F.R. (eds) Combinatorial Catalysis and High Throughput Catalyst Design and Testing. NATO Science Series, vol 560. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-4329-5_6

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  • DOI: https://doi.org/10.1007/978-94-011-4329-5_6

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7923-6628-7

  • Online ISBN: 978-94-011-4329-5

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