On the ⁵³Mn Heterogeneity in the Early Solar System

Abstract

It is well established that the prolonged and thorough mixing of numerous nucleosynthetic components that constitutes the matter in the solar nebula resulted in an essential isotopic homogeneity of the solar system material. This may or may not be true for the short-lived radionuclides which were injected into or formed within the solar nebula just prior to or during solar system formation. Distinguishing between their heterogeneous or homogeneous distribution is important because the short- lived radionuclides are now widely used for the relative chronology of various objects and processes in the early solar system and as constraints for models of nucleosynthesis. The recent studies of the ⁵³Mn-⁵³Cr isotope system (half life of ⁵³Mn is 3.7 Ma) in various solar system objects have shown that the relative abundance of radiogenic ⁵³Cr is consistent with essentially homogeneous distribution of ⁵³Mn in the asteroid belt. Thus, the relative ⁵³Mn-⁵³Cr chronometer can be directly used for dating samples which originated in the asteroid belt. Importantly, however, all meteorite groups studied so far indicate a clear excess of ⁵³Cr as compared to Earth and to a lunar sample, which exhibits also a terrestrial ⁵³Cr/⁵²Cr ratio. The results from the Martian (SNC) meteorites show that their ⁵³Cr excesses are less than half of those found in the asteroid belt bodies. Thus, the characteristic ⁵³Cr/⁵²Cr ratio of Mars is intermediate between that of the Earth-Moon system and those of the other meteorites. If these ⁵³Cr variations are viewed as a function of the heliocentric distance, the radial dependence of the relative abundances of radiogenic Cr is indicated. This observed gradient can be explained by either an early, volatility controlled, Mn/Cr fractionation within the nebula or by an initial radial heterogeneous distribution of ⁵³Mn. Although model calculations of the Mn/Cr ratios in the bulk terrestrial planets seem to be inconsistent with the volatility driven scenario, the precision of these calculations is inadequate for eliminating this possibility. In contrast, recent studies of the ⁵³Mn-⁵³Cr system in the enstatite chondrites indicate that, while their bulk Mn/Cr ratios are essentially the same as in ordinary chondrites, the ⁵³Cr excess in bulk enstatite chondrites is three times lower than that in the bulk ordinary chondrites. This difference cannot be explained by a Mn/Cr fractionation and, thus, strongly suggests that a radial heterogeneous distribution of ⁵³Mn must have existed in at least the early inner solar system. Using the observed gradient and the ⁵³Cr/⁵²Cr ratio of the bulk enstatite chondrites, their parent body(ies) formed at ~1.4 AU or somewhat closer to the Sun.