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Polysilazanes

  • Chapter
Silicon-Containing Polymers

Abstract

Polymers that contain repeating -Si-O- units in their backbone, the polyorgano-siloxanes (1), have been widely studied and have found many technological applications [1,2]. In contrast, the isoelectronic polyorganosilazanes, polymers with -Si-N- bonds in the main chain (2), have received little attention. This is partly a result of the high chemical reactivity (with water, protic compounds, oxygen etc.) of one of the first polymers of the series (3) and mainly because of a lack of suitable preparative methods for producing linear chains of really high molar mass. Indeed, many of the obvious routes to polysilazanes result not in polymers but in mixtures of cyclic compounds and linear oligomers with generally a rather complicated structure [3–5].

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Author information

Authors and Affiliations

  1. Laboratoire de Chimie des Polymères Organiques, Unité Mixte de Recherche CNRS, Universite Bordeaux l Ecole Nationale Supérieure de Chimie et de Physique de Bordeaux, Avenue Pey Berland, BP 108, 33402, Talence Cedex, France

    Alain Soum

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  1. Alain Soum
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Editors and Affiliations

  1. University of Kent, Canterbury, UK

    Richard G. Jones

  2. Dow Corning Asia Ltd., Kanagawa, Japan

    Wataru Ando

  3. Polish Academy of Sciences, Lódz, Poland

    Julian Chojnowski

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© 2000 Springer Science+Business Media Dordrecht

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Soum, A. (2000). Polysilazanes. In: Jones, R.G., Ando, W., Chojnowski, J. (eds) Silicon-Containing Polymers. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3939-7_11

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  • DOI: https://doi.org/10.1007/978-94-011-3939-7_11

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-4020-0348-6

  • Online ISBN: 978-94-011-3939-7

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