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Fractionation of (Co-) Polymer Blends by Multiple Solvent Gradient Elution

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Integration of Fundamental Polymer Science and Technology—5

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Abstract

Polymer blends were fractionated in a precipitation-redissolution process via high performance precipitation liquid chromatography (HPPLC). Following precipitation of the blend in a non-solvent, fractionation was achieved according to solubility by multiple solvent gradient elution with increasing solvent power. Reproducible baseline resolved HPPLC fractionation of commercial poly(2, 6-dimethy1–1, 4-phenylene ether/poly (styrene) (PPE/PS), poly(styrene)/ ethylene-propylene-diene monomer (PS/EPDM) and aromatic poly(estercarbonate)/ polycarbonate (APEC/PC) blends was obtained.

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References

  1. Tung, L.H., Fractionation. In Encyclopedia of Polymer Science and Engineering. Wiley. 1987, volume 7, 298–327.

    CAS  Google Scholar 

  2. Barall, E.M., Johnson, J.F. and Cooper, A.R., In Fractionation of Synthetic Polymers. ed. L.H. Tung, Marcel Dekker, New York, 1977, Chapter 3.

    Google Scholar 

  3. Glöckner, G., Pure Appl. Chem. 1982. 55, 1553–1562.

    Article  Google Scholar 

  4. Glöckner, G., van den Berg, J.H.M., Meijerink, N.L.J., Scholte, T.G. and Koningsveld, R., Macromolecules. 1984, 17, 962–967.

    Article  Google Scholar 

  5. Glöckner, G., van den Berg, J.H.M., Meijerink, N.L.J., Scholte, T.G. and Koningsveld, R., J. Chromatogr. 1984, 317, 615–624.

    Article  Google Scholar 

  6. Mori, S., J. Chromatogr. 1987. 411, 355–362.

    Article  CAS  Google Scholar 

  7. Bui, K.H., Armstrong, D.W. and Boehm, R.E., J. Chromatogr. 1984, 288, 15–24.

    Article  CAS  Google Scholar 

  8. Quarry, M.A., Stadalius, M.A., Mourey, T.H. and Snyder, L.R., J. Chromatogr. 1986, 358, 1–16.

    Article  CAS  Google Scholar 

  9. Glöckner, G. and Müller, A.H.E., J. Appl. Polym. Sci. 1989, 38, 1761–1774.

    Article  Google Scholar 

  10. Glöckner, G., Stickler, M. and Wunderlich, W., Fresenius Z. Anal. Chem. 1987, 328, 76–81.

    Article  Google Scholar 

  11. Glöckner, G. and van den Berg, J.H.M., J. Chromatogr. 1987, 384, 135–144.

    Article  Google Scholar 

  12. Glöckner, G. and van den Berg, J.H.M., Chromatographia. 1987, 24, 233–240.

    Article  Google Scholar 

  13. Teramachi, S., Hasegawa, A., Shigekuni, Y. and Matunaga, S., Polymer J. 1989, 21, 803–808.

    Article  CAS  Google Scholar 

  14. Jansen, J.A.J., Fresenius J. Anal. Chem. in press.

    Google Scholar 

  15. Jansen, J.A.J. and Haas, W.E., Polymer Comm. 1988, 29, 77–80.

    CAS  Google Scholar 

  16. Olabisi, O., Robeson, L.M. and Shaw, M.T., Polymer-Polymer Miscibility. Academic Press, New York, 1979.

    Google Scholar 

  17. Pilati, F., Marianucci, E. and Berti, C., J.Appl. Polym. Sci. 1985, 30, 1267–1275.

    Article  CAS  Google Scholar 

  18. Robeson, L.M., J. Appl. Polym. Sci. 1985, 30, 4081–4098.

    Article  CAS  Google Scholar 

  19. Devaux, J., Deveaux, P. and Godard, P., Makromol. Chem. 1985, 186, 1227–1237.

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Philips PMF, Competence Centre Plastics, 218, 5600 MD, Eindhoven, The Netherlands

    J. A. J. Jansen, J. H. J. van den Bungelaar & A. J. H. Leenen

Authors
  1. J. A. J. Jansen
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  2. J. H. J. van den Bungelaar
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  3. A. J. H. Leenen
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Editor information

Editors and Affiliations

  1. Eindhoven University of Technology, Eindhoven, The Netherlands

    P. J. Lemstra

  2. DSM-Research, Geleen, The Netherlands

    L. A. Kleintjens

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© 1991 Elsevier Science Publishers Ltd

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Jansen, J.A.J., van den Bungelaar, J.H.J., Leenen, A.J.H. (1991). Fractionation of (Co-) Polymer Blends by Multiple Solvent Gradient Elution. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3890-1_41

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  • DOI: https://doi.org/10.1007/978-94-011-3890-1_41

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-85166-587-7

  • Online ISBN: 978-94-011-3890-1

  • eBook Packages: Springer Book Archive

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