Abstract
Raman spectra of the C-C stretching region of strained high-modulus polyethylene fibers shows the existence of a bi-modal molecular stress distribution. Experiments with various PE fibers showed that the fraction of high-stress bearing C-C bonds increased with increasing E-modulus. During stress relaxation the fraction of high- stress bearing C-C bonds decreases at the same rate as macroscopic stress.
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© 1991 Elsevier Science Publishers Ltd
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Kip, B.J., van Eijk, M.C.P., Meier, R.J. (1991). Molecular Strain in High Modulus Polyethylene Fibers During Stress Relaxation Studied by Raman Microscopy. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—5. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3890-1_22
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DOI: https://doi.org/10.1007/978-94-011-3890-1_22
Publisher Name: Springer, Dordrecht
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Online ISBN: 978-94-011-3890-1
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