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MICC 90 pp 164–168Cite as

Structural and Chemical Transformation of the Polyacrylonitrile Fiber in the Process of Thermal—Oxidizing Destruction

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Abstract

In the course of this work we managed to find the criterion of the transformation degree of the polyacrylonitrile (PAN) fiber in the process of thermal-oxidizing destruction (TOD). We have found out, that TOD may be devided into two stages during isothermal processing. During the second stage oxidation processes are more intensive. The values of transformations degrees F, corresponding to the ending of the first stage Fopt, and the second stage Ffin, depend linearly on the treatment temperature. We suppose, that, after the first stage of TOD, along the whole volume of filaments,there forms a rigid space carcasse, consisting of sewn packs of heteroaromatic layers.

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References

  1. Shevenkova N.V. Crystal structure of PAN-fibre and its changes in the process of carbon fibre production. M. 1989, 9s. The manuscript is presented by graphite research institute. Dep. in VINITI, May 22, 1989, 1815–89.

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  2. Emanuel N.M. Buchaenko A.L. Chemical physics of ageing and stabilization of polymers. M.Nauka. 1982, 360 s.

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© 1991 Elsevier Science Publishers Ltd

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Podkopaev, S.S., Balahonov, J.A., Kaverov, A.T. (1991). Structural and Chemical Transformation of the Polyacrylonitrile Fiber in the Process of Thermal—Oxidizing Destruction. In: Fridlyander, I.N., Kostikov, V.I. (eds) MICC 90. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3676-1_17

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  • DOI: https://doi.org/10.1007/978-94-011-3676-1_17

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-85166-648-5

  • Online ISBN: 978-94-011-3676-1

  • eBook Packages: Springer Book Archive

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