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Diffusion Bonding 2 pp 224–231Cite as

Interfaces in Metal/Ceramic Diffusion Bonds

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Abstract

Diffusion bonds of Pd/ZrO2 and Pd/Al2O3 made in vacuum at 1100°C 10 MPa have been studied. Their strengths measured by four-point bend tests show strong bonding occurred in the Pd/ZrO2 bands. Investigation of published phase diagrams suggested this to be due to an eutectic reaction between Pd and ZrO2. The existence of such a reaction was further characterised by optical and electron microscopy (TEM). Possible eutectic temperatures were found at 707 and 890° by differential thermal analysis (DTA).

TEM results of Pd/Al2O3 found no reaction layer between these two materials. This possibly explains the low strengths of these diffusion bonds.

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Author information

Authors and Affiliations

  1. Department of Materials, University of Oxford, OX1 3PH, UK

    C.-D. Qin & B. Derby

Authors
  1. C.-D. Qin
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  2. B. Derby
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Editor information

Editors and Affiliations

  1. School of Industrial and Manufacturing Science, Cranfield Institute of Technology, UK

    D. J. Stephenson

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© 1991 Elsevier Science Publishers Ltd

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Qin, CD., Derby, B. (1991). Interfaces in Metal/Ceramic Diffusion Bonds. In: Stephenson, D.J. (eds) Diffusion Bonding 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3674-7_18

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  • DOI: https://doi.org/10.1007/978-94-011-3674-7_18

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-1-85166-591-4

  • Online ISBN: 978-94-011-3674-7

  • eBook Packages: Springer Book Archive

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