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Towards an Artificial Photosynthesis. Di-, Tri-, Tetra-, and Heptanuclear Luminescent and Redox-Reactive Metal Complexes

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Photochemical Conversion and Storage of Solar Energy

Abstract

We have synthesized more than 30 mono-, di-, tri-, tetra-, and heptanuclear Ru(II) and/or Os(II) complexes containing 2,3-dpp and 2,5-dpp as bridging ligands and bpy and biq as peripheral ligands. These oligonuclear complexes are quite interesting because they accumulate many chromophoric and redox centers in the same “supermolecule” and exhibit luminescence from relatively long-lived excited states.

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References

  1. Balzani, V.; Moggi, L.; Scandola, F. in Supramolecu1ar Photochemistry, Balzani, V. Ed., Reidel, 1987.

    Google Scholar 

  2. Balzani, V.; Scandola, F. Supramolecular Photochemistry, Horwood, Chichester, 1990.

    Google Scholar 

  3. Deisenhofer, J.; Michel, H. Angew. Chem. Int. Ed. Engl., 1989, 28, 829.

    Article  Google Scholar 

  4. Connolly, J. S.; Bolton, J. R. in Photoinduced Electron Transfer, Fox, M. A.; Chanon, M. Eds, Part D, Elsevier, 1988, p.303.

    Google Scholar 

  5. Juris, A.; Balzani, V.; Barigelletti, F.; Campagna, S.; Belser, P.; von Zelewsky, A. Coord. Chem. Rev., 1988, 84, 85.

    Article  CAS  Google Scholar 

  6. Kober, E. M.; Caspar, J. V.; Sullivan, B. P.; Meyer, T. J. Inorg. Chem., 1988, 27, 4587.

    Article  CAS  Google Scholar 

  7. Scandola, F.; Indelli, M. T.; Chiorboli, C.; Bignozzi, C. A. Topics Curr. Chem., 1990, 158, in press.

    Google Scholar 

  8. Fuchs, Y.; Lofters, S.; Dieter, T.; Shi, W.; Morgan, R.; Strekas, T. C.; Gafney, H. D.; Baker, A. D. J. Am. Chem. Soc., 1987, 109, 2691.

    Google Scholar 

  9. Brewer, K. J.; Murphy, W. R. Jr.; Spurlin, S. R.; Petersen, J. D. Inorg. Chem., 1986, 25, 882

    Article  CAS  Google Scholar 

  10. Murphy, W. R. Jr.; Brewer, K. J.; Gettliffe, G.; Petersen, J. D. Inorg. Chem., 1989, 28, 81.

    Article  CAS  Google Scholar 

  11. Kalyanasundaram, K.; Nazeeruddin, Md. K. Chem. Phys. Letts, 1989, 158, 45

    Article  CAS  Google Scholar 

  12. Kalyanasundaram, K.; Nazeeruddin, Md. K. Inorg. Chem., 1990, 29, 1888.

    Article  CAS  Google Scholar 

  13. Ernst, S. D.; Kasack, V.; Kaim, W. Inorg. Chem., 1988, 27, 1146

    Article  CAS  Google Scholar 

  14. Ernst, S. D.; Kaim, W. Inorg. Chem., 1989, 28, 1520.

    Article  CAS  Google Scholar 

  15. Campagna, S.; Denti, G.; De Rosa, G.; Sabatino, L.; Ciano, M.; Balzani, V. Inorg. Chem., 1989, 28, 2565.

    Google Scholar 

  16. Campagna, S.; Denti, G.; Sabatino, L.; Serroni, S.; Ciano, M.; Balzani, V. J. Chem. Soc. Chem. Comm., 1989, 1500.

    Google Scholar 

  17. Campagna, S.; Denti, G.; Sabatino, L.; Serroni, S.; Ciano, M.; Balzani, V. Gazz. Chim. Ital., 1989, 119, 415.

    CAS  Google Scholar 

  18. Denti, G.; Campagna, S.; Sabatino, L.; Serroni, S.; Ciano, M.; Balzani, V., Inorg. Chem., in press.

    Google Scholar 

  19. Denti, G.; Campagna, S.; Sabatino, L.; Serroni, S.; Ciano, M.; Balzani, V., Inorg. Chim. Acta, in press.

    Google Scholar 

  20. Denti, G.; Sabatino, L.; Serroni, S.; Ciano, M.; Ricevuto, V.; Campagna, S., manuscript in preparation.

    Google Scholar 

  21. Kohnke, F. H.; Mathias, J. P.; Stoddart, J. F. Angew. Chem. Int. Ed. Engl., 1989, 28, 1103.

    Article  Google Scholar 

  22. Tomalia, D. A.; Naylor, A. M.; Goddard III W. A. Angew. Chem. Int. Ed. Engl., 1990, 29, 138.

    Article  Google Scholar 

  23. Chirayil, S.; Thummel, R. P. Inorg. Chem., 1989, 28, 85.

    Article  Google Scholar 

  24. Balzani, V.; Carassiti, V. Photochemistry of Coordination Compounds, Academic Press, 1970.

    Google Scholar 

  25. De Armond, M. K.; Carlin, C. M. Coord. Chem. Rev., 1981, 36, 325.

    Article  Google Scholar 

  26. Myrick, M. L.; Blakley, R. L.; De Armond, M. K. J. Phys. Chem., 1989, 93, 3936

    Article  CAS  Google Scholar 

  27. Myrick, M. L.; De Armond, M. K.; Blakley, R. L. Inorg. Chem., 1989, 28, 4077.

    Article  CAS  Google Scholar 

  28. Meyer, T. J. Accounts Chem. Res., 1989, 22, 163.

    Article  CAS  Google Scholar 

  29. Chen, P.; Duesing, R.; Tapolsky, G.; Meyer, T. J. J. Am. Chem. Soc, 1989, 111, 8305.

    Article  CAS  Google Scholar 

  30. Balzani, V.; Barigelletti, F.; De Cola, L. Topics Curr. Chem., 1990, 158, in press.

    Google Scholar 

  31. Vlachopulos, N.; Liska, P.; Augustynski, J.; Graetzel, M. J. Am. Chem. Soc., 1988, 110, 1216.

    Article  Google Scholar 

  32. Amadelli, R.; Argazzi, R.; Bignozzi, C. A.; Scandola, F. J. Am. Chem. Soc., in press.

    Google Scholar 

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Author information

Authors and Affiliations

  1. Istituto di Chimica Agraria dell’Università, Pisa, Italy

    G. Denti

  2. Dipartimento di Chimica Inorganica dell’ Università, Messina, Italy

    S. Campagna

  3. Dipartimento di Chimica, Università della Calabria, Rende, Italy

    L. Sabatino & S. Serroni

  4. Istituto FRAE-CNR, Bologna, Italy

    M. Ciano & V. Balzani

  5. Dipartimento di Chimica “G. Ciamician” dell’ Università, Bologna, Italy

    V. Balzani

Authors
  1. G. Denti
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  2. S. Campagna
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  3. L. Sabatino
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  4. S. Serroni
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  5. M. Ciano
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  6. V. Balzani
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Editor information

Editors and Affiliations

  1. University of Torino, Italy

    E. Pelizzetti

  2. University of Palermo, Italy

    M. Schiavello

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© 1991 Springer Science+Business Media Dordrecht

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Denti, G., Campagna, S., Sabatino, L., Serroni, S., Ciano, M., Balzani, V. (1991). Towards an Artificial Photosynthesis. Di-, Tri-, Tetra-, and Heptanuclear Luminescent and Redox-Reactive Metal Complexes. In: Pelizzetti, E., Schiavello, M. (eds) Photochemical Conversion and Storage of Solar Energy. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3396-8_3

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  • DOI: https://doi.org/10.1007/978-94-011-3396-8_3

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5502-4

  • Online ISBN: 978-94-011-3396-8

  • eBook Packages: Springer Book Archive

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