Abstract
This report attempts to present the state of the research in photocatalysis on powder semiconductors by considering the studies that allow one to determine the properties of the solids and to obtain information on surface sites and adsorbed species. First, the importance of surface features and associated phenomena, the dependence of adsorption equilibria and surface entities mobilities upon band-gap illumination, and the information that can be derived from kinetic measurements and some spectroscopic methods, are briefly discussed. Then, the objectives and results of recent studies attempting to prepare particulate photocatalysts with controlled texture or higher stability, as well as semiconductors deposited on or incorporated in inorganic supports, are reviewed. Finally, the capabilities of contactless time-resolved microwave conductivity and photoacoustic spectroscopy are shown.
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Pichat, P. (1991). Photocatalysis: Heterogeneous Regime. Catalysts, Adsorption and New Techniques. In: Pelizzetti, E., Schiavello, M. (eds) Photochemical Conversion and Storage of Solar Energy. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3396-8_16
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