Abstract
The phenomenon of high viscosity and glass formation in supercooling hydrogen-bonded liquids is compared with that in other liquids, and peculiarities which may be associated with the presence of the specific hydrogen-bonding interaction are singled out. In the first part of the paper, these are discussed in the context of “strength” and “fragility” in liquids and linked to specific features of the topology of the potential energy hypersurfaces for such liquids. In the second part, a higher level of complexity in the behavior of certain hydrogen-bonding liquids, such as the normal alcohols and water is discussed and interpreted in terms of hydrogen bond-driven cluster formation. Large clusters of water molecules formed spontaneously in microemulsion systems are then examined spectroscopically to distinguish surface from bulk hydrogen bonds. Finally, the role of hydrogen bonding and glass formation in preservation of life in simple organisms under hostile conditions is briefly examined.
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Angell, C.A. (1991). Transport Processes, Relaxation, and Glass Formation in Hydrogen-Bonded Liquids. In: Dore, J.C., Teixeira, J. (eds) Hydrogen-Bonded Liquids. NATO ASI Series, vol 329. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3274-9_5
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DOI: https://doi.org/10.1007/978-94-011-3274-9_5
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