Summary
This paper will outline the role of dielectrometry in the study of the hydrogen bond and its effects on the structure and dynamics of associated liquids. After a brief description of the experimental techniques used, data referring to water, alcohols and their mixtures are reported. A review of the models suggested by various authors over the past fifty years to explain the dielectric relaxation of these liquids is also presented.
The last section is devoted to the illustration of a recent model developed by the Liquid Research Group at IFAM; this model traces the dynamic behaviour of H-bonded liquids back to the stochastic formation and breaking of their hydrogen bonds. The results predicted by the model and the experimental results for water are shown to be in good agreement.
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Salvetti, G. (1991). Dielectric Measurements of Water, Alcohols and their Mixtures. In: Dore, J.C., Teixeira, J. (eds) Hydrogen-Bonded Liquids. NATO ASI Series, vol 329. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3274-9_25
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DOI: https://doi.org/10.1007/978-94-011-3274-9_25
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