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Hydrogen-Bonded Liquids pp 333–356Cite as

The properties of hydrogen bonded liquids studied by high pressure NMR

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Part of the book series: NATO ASI Series ((ASIC,volume 329))

Abstract

The translational self diffusion coefficients D of a series of simple liquids and supercooled water obtained in a wide temperature range and at pressures up to 400 MPa are given. The model descriptions published for the ϱ,T-dependence of D are tested with these data. With spin lattice relaxation time (T1) measurements of the protons, deuterons and oxygen-17 nuclei in neat emulsified supercooled water as function of frequency models for the rotational mobility of water are evaluated. The anomalous temperature dependence of D and T1 at p ⩽ 150 MPa is discussed. The deuteron-T1 measurements have been extended to supercooled aqueous alkali and alkali earth halide emulsions. A simple two state model for the description of the temperature and concentration dependence of the deuteron-T1 in these solutions is given.

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Authors and Affiliations

  1. Institut für Biophysik und Physikalische Biochemie, Universität Regensburg, Postfach 397, D-8400, Regensburg, Germany

    E. W. Lang & H.-D. Lüdemann

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  1. E. W. Lang
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  2. H.-D. Lüdemann
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Editors and Affiliations

  1. Physics Department, University of Kent at Canterbury, Canterbury, UK

    John C. Dore

  2. Laboratoire Leon Brillouin, C.E.N., Saclay, France

    José Teixeira

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Lang, E.W., Lüdemann, HD. (1991). The properties of hydrogen bonded liquids studied by high pressure NMR. In: Dore, J.C., Teixeira, J. (eds) Hydrogen-Bonded Liquids. NATO ASI Series, vol 329. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3274-9_23

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  • DOI: https://doi.org/10.1007/978-94-011-3274-9_23

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5445-4

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