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Structural Analysis of Liquid Formic Acid Using Neutron Diffraction

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Hydrogen-Bonded Liquids

Part of the book series: NATO ASI Series ((ASIC,volume 329))

Abstract

The structure of liquid formic acid is investigated using neutron diffraction. H/D isotopic substitution techniques are employed to obtain partial structural information. The bond lengths obtained from the intramolecular analysis are consistent with those obtained by other methods. The intermolecular structure consists of molecules linked extensively through hydrogen bonds of bond length 1.8Å to form long chains.

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References

  1. L. Pauling and L. O. Brockway. The structure of the carboxylic group. I. the investigation of formic acid by the diffraction of electrons. Proc. Nat. Acad. Sci, 20:336, 1934.

    Article  ADS  Google Scholar 

  2. A. Almenningen, O. Bastiansen, and Tove Motzfeldt. A reinvestigation of the structure of monomer and dimer formic acid by gas electron diffraction technique. Acta Chem. Scand., 23:2848, 1969.

    Article  Google Scholar 

  3. L. G. Bonner and R. Hofstadter. Vibration spectra and molecular stucture IV. infra-red absorption spectra of the double and single molecules of formic acid. J. Chem. Phys, 6:531, 1938.

    Article  ADS  Google Scholar 

  4. I. Nahringbauer. A reinvestigation of the structure of formic acid (at 98K). Acta Cryst, B34:316, 1978.

    Google Scholar 

  5. T. V. Gorbunova, V. V. Shilov, and G. I. Batalin. X-ray diffraction study of formic, acetic, and propionic acids in the liquid state. Russ. J. Struct Chem., 14:388, 1973.

    Article  Google Scholar 

  6. C. P. Smyth and H. E. Rogers. The dielectric polarization of liquids. VIII. acetic and butyric acids. J. Amer. Chem. Soc, 52:1824, 1930.

    Article  Google Scholar 

  7. O. Faurskov and P. -A. Lund. Inter molecular raman active vibrations of hydrogen bonded acetic acid dimers in the liquid state. J. Chem. Phys, 78:652, 1983.

    Article  ADS  Google Scholar 

  8. J. F. Johnson and R. H. Cole. Dielectric polarization of liquid and solid formic acid. J. Amer. Chem. Soc, 73:4536, 1951.

    Article  Google Scholar 

  9. S. M. Blumenfeld and H. Fast. Low frequency spectra of solid and liquid formic acid. Spectrochim. Acta, 24A:1449, 1968.

    Article  ADS  Google Scholar 

  10. D. Chapman. The infrared spectra of liquid and solid formic acid. J. Chem. Soc., 225, 1956.

    Google Scholar 

  11. A. Kratochwill and H. G. Hertz. NMR relaxation study and molecular pair distribution functions of the system formic acid/chloroform. J. Chimie Physique, 74:814, 1977.

    Google Scholar 

  12. H. Bertagnolli, P. Chieux, and H. G. Hertz. The structure of the formic acid molecule in the liquid state from neutron diffraction measurements involving five isotopically different species. Ber. Bunsenges. Phys. Chem., 88:977, 1984.

    Article  Google Scholar 

  13. H. Bertagnolli and H. G. Hertz. Pair configuration of maximum occurrence probability in liquid formic acid as determined from neutron scattering and proton magnetic relaxation results. Ber. Bunsenges. Phys. Chem, 89:500, 1985.

    Article  Google Scholar 

  14. J. P. Ambroise, M. C. Bellissent-Funel, and R. Bellissent. Neutron scattering determination of local order in amorphous and liquid systems using a position sensitive detector. Revue Phys. Appl., 19:731, 1984.

    Article  Google Scholar 

  15. G. I. Swan. Structural Studies of Liquid Formic Acid and Water in Porous Silica by Neutron Diffraction. PhD thesis, Univesity of Kent at Canterbury, 1989.

    Google Scholar 

  16. E. Lorch. Neutron diffraction by germania, silica and radiation silica glasses. J. Phys. C (Solid St. Phys.), 2:229, 1969.

    Article  ADS  Google Scholar 

  17. R. L. Mcgreevy and L. Pusztai. Reverse monte carlo simulations: a new technique for the determination of disordered structures. Molecular Simulation, 1:359, 1988.

    Article  Google Scholar 

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© 1991 Springer Science+Business Media Dordrecht

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Swan, G.I. (1991). Structural Analysis of Liquid Formic Acid Using Neutron Diffraction. In: Dore, J.C., Teixeira, J. (eds) Hydrogen-Bonded Liquids. NATO ASI Series, vol 329. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3274-9_11

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  • DOI: https://doi.org/10.1007/978-94-011-3274-9_11

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5445-4

  • Online ISBN: 978-94-011-3274-9

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