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Application of Direct and Indirect Electrochemical Techniques to the Investigation of Fast Kinetics

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Microelectrodes: Theory and Applications

Part of the book series: NATO ASI Series ((NSSE,volume 197))

Abstract

Ultramicroelectrode techniques are able to detect and kinetically characterize short-lived intermediates down to the sub-microsecond range. The redox catalysis method allows such characterization in the microsecond to the nanosecond range. Both approaches also permit the determination of fast heterogeneous and homogeneous electron transfer rate constants.

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Authors and Affiliations

  1. Laboratoire d’Electrochimie Moléculaire de l’Université de Paris 7, Unité Associée au CNRS No 438, 2 place Jussieu, 75251, Paris Cedex 05, France

    Jean-Michel Saveant

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  1. Jean-Michel Saveant
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Editors and Affiliations

  1. Universidade do Minho, Largo do Paço, Braga, Portugal

    M. Irene Montenegro  & M. Arlete Queirós  & 

  2. Department of Chemistry, University of Utah, Salt Lake City, Utah, USA

    John L. Daschbach

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Saveant, JM. (1991). Application of Direct and Indirect Electrochemical Techniques to the Investigation of Fast Kinetics. In: Montenegro, M.I., Queirós, M.A., Daschbach, J.L. (eds) Microelectrodes: Theory and Applications. NATO ASI Series, vol 197. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-3210-7_19

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  • DOI: https://doi.org/10.1007/978-94-011-3210-7_19

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  • Online ISBN: 978-94-011-3210-7

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