Skip to main content

Catalytic CO Oxidation Over Manganese-Containing Perovskites

  • Chapter

Abstract

Mixed metal oxides are discussed as possible substitutes for noble metals in automobile catalytic converters. The catalytic activity for CO oxidation of LaMnO3 and La0.5Sr0.5MnO3 catalysts was examined.

The ability of these catalysts to provide lattice oxygen and to sustain the oxidation reaction, even in the absence of molecular oxygen, has been confirmed. Measurements were performed of the reversible oxygen uptake on the two catalysts.

Author for correspondence.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Carberry, J.J., Rajadurai, S., Alcock, C.B. and Li, B.: 1990, ‘Solid Oxide Solutions-A Comparison with Supported Pt’, Cat. Lett. 4, 43–48.

    Google Scholar 

  • Chuah, G.K., Jaenicke, S. and Lee, J.Y.: 1991, ‘Steady State Multiplicity in Carbon Monoxide Oxidation over LaMnO3Applied Cat. 72, 51–61

    Google Scholar 

  • Gallagher, P.K., Johnson, Jr., D.W., and Schrey, F.: 1974, ‘Studies of Some Supported Perovskite Oxidation Catalysts’, Mat. Res. Bull. 9, 1345–1352.

    Google Scholar 

  • Greek, B.F.: 1989, ‘Process Catalysts Enjoy Surging Market’, Chemical & Engineering News, May 29, 29–56.

    Google Scholar 

  • Johnson, D.W., Gallagher, P.K., Schrey, F., Rhodes, W.W.: 1976, ‘Preparation of High Surface Area Substituted LaMnO3 Catalysts’ Am. Ceram. Soc. Bull. 55(5), 520–523.

    Google Scholar 

  • Kim, G.: 1982, ‘Ceria-Promoted Threc-Way Catalyst for Auto Exhaust Emission Control’, Ind. Eng. Chem. Prod. Res. Dev. 21, 267–274.

    Google Scholar 

  • Libby, W.F.: 1971, ‘Promising Catalyst for Auto Exhaust’, Science 171, 499–500.

    Google Scholar 

  • Meadowcraft, D.B.: 1970, ‘Low-Cost Oxygen Electrode Material’, Nature 226, 847–848.

    Google Scholar 

  • Nakamura, T., Misono, M., and Yoneda, Y.: 1982, ‘Catalytic Properties of Perovskite-Type Mixed Oxides La1-xSrxCoO3’, Bull. Chem. Sce. Jpn. 55, 394–399.

    Google Scholar 

  • Nakamura, T., Misono, M., and Yoneda, Y.: 1983, ‘Reduction-Oxidation and Catalytic Properties of La1-xSrxCoO3’, J. Catal. 83, 151–159.

    Google Scholar 

  • Shelef, M., Otto, K., and Otto, N.C.: 1978, ‘Poisoning of Automotive Catalysts’, Advances in Catalysis 27, D.D. Eley, H. Pines and P.B. Weisz (Eds.), Academic Press, New York, 1978, 311–365.

    Google Scholar 

  • Shyu, J.Z., Otto, K., Watkins, W.L.H., Belitz, R.K., and Gandhi, H.S.: 1988, ‘Characterization of Pd/γ-Alumina Catalysts Containing Ceria’, J. Catal. 114, 23–33.

    Google Scholar 

  • Snyder, T.P. and Hili, C.G.: 1989, ‘The Mechanism for the Partial Oxidation of Propylene over Bismuth Molybdate Catalysts’, Catal. Rev.-Sci. Eng. 31, 43–95.

    Google Scholar 

  • Takasu, Y., Matsui, M., and Matsuda, Y.: 1982, ‘The Catalytic Contribution of the Lattice Oxygen Atoms of Praseodymium Oxide to the Oxidation of Carbon Monoxide’, J. Catal. 76, 61–64.

    Google Scholar 

  • Taylor, K.C.: 1984, ‘Automobile Catalytic Converters’ in: Catalysis-Science and Technology 5, J.R. anderson and M. Boudart (Eds.), Springer-Verlag, Berlin, pp. 120–170.

    Google Scholar 

  • Veprek, S., Cocke, D.L., Kehl, S., and Oswald, H.R: 1986, ‘Mechanism of the Deactivation of Hopcalite Catalysts Studied by XPS, ISS, and Other Techniques’, J. Catal. 100, 250–263.

    Google Scholar 

  • Voorhoeve, R.J.H.: 1977, ‘Perovskite-Related Oxides as Oxidation-Reduction Catalysts’, Advanced Materials in Catalysis, J.J. Barton and R.L. Garten (Eds.), Academic Press, N.Y., pp. 129–180.

    Google Scholar 

  • Yakel, Jr. H.L.: 1955, ‘On the Structures of some Compounds of the Perovskite Type’, Acta Cryst. 8, 394–398.

    Google Scholar 

  • Yao, Y.-F.Y.: 1975a, ‘The Oxidation of Hydrocarbons and CO over Metal Oxides’, J. Catal. 36, 266–275.

    Google Scholar 

  • Yao, Y.-F.Y.: 1975b, ‘The Oxidation of CO and C2H4 over Metal Oxides-Part V:SO2 Effects’, J. Catal. 39, 104–114.

    Google Scholar 

  • Zhang, H.M., Shimizu, Y., Teraoka, Y., Miura, N., and Yamazoe, N.: 1990, ‘Oxygen Sorption and Catalytic Properties of La1-xSrxCo1-yFeyO3 Perovskite-Type Oxides’, J. Catal. 121, 432–440.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1991 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Jaenicke, S., Chuah, G.K., Lee, J.Y. (1991). Catalytic CO Oxidation Over Manganese-Containing Perovskites. In: Lee, H.K. (eds) Fourth Symposium on our Environment. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2664-9_13

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-2664-9_13

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-5178-1

  • Online ISBN: 978-94-011-2664-9

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics