Skip to main content

Commercial scale decaffeination of coffee and tea using supercritical CO2

  • Chapter
Book cover Extraction of Natural Products Using Near-Critical Solvents

Abstract

Coffee and tea both contain caffeine and are the most widely used stimulants in our society. They are valued all over the world either as day-to-day drinks or as semi-luxury beverages. In consequence, raw green coffee and tea together constitute, after wheat, the world’s second largest cultivated crop. In 1990, for example, the world production for green coffee was about 5.5 million tons, the most important cultivation areas being in South America and Africa. About 70% of this production was exported to Europe (2.5 millions tons) and North America (1.5 million tons). The market in Asia is much smaller, but is increasing particularly in Japan. Agreements regulating the international coffee trade are described by McClumpha [1]. These are designed to stabilise the market which can suffer from periods of oversupply and then shortage brought about, for example, by frost or drought damage in a major producing area.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. McClumpha, A.D. (1988), The trading of green coffee, Chapter 1 inCoffeeVol. 6 Commercial and Technico-Legal Aspects(eds. R.J. Clarke and R. Macrae), Elsevier, London.

    Google Scholar 

  2. F.O. Licht’s International Coffee Report, October 1990.

    Google Scholar 

  3. OIC Document DB-3206/90.

    Google Scholar 

  4. International Tea Committee (1990) Annual Bulletin of Statistics.

    Google Scholar 

  5. Viani, R. (1986) Coffee, in Ullmann’s Encyclopedia of Industrial chemistry (1990), Vol. A7, 5th edn., VCH, Weinheim, pp. 315–339.

    Google Scholar 

  6. James, J.E. (1991)Caffeine and HealthAcademic Press, London.

    Google Scholar 

  7. Wurziger, J. (1982) Tee, in Ullmann’s Encyklopädie der technischen Chemie, Vol. 22, 4th edn., VCH, Weinhiem, pp. 405–410.

    Google Scholar 

  8. United States of America Coffee Drinking Study, Winter 1989 (1984).

    Google Scholar 

  9. European Coffee Report 1988.*

    Google Scholar 

  10. European Coffee Report 1989.*

    Google Scholar 

  11. European Coffee Report 1990.*

    Google Scholar 

  12. Katz, S.N. (1987) Decaffeination of Coffee, Chapter 3 in Coffee Vol. 2, Technology, (eds. R.J. Clarke and R. Macrae, Elsevier, London.

    Google Scholar 

  13. Patel, J.M. and Wolfson, A.B. (1972) Semi-continuous countercurrent decaffeination processes, US Patent No. 3, 671, 263.

    Google Scholar 

  14. Patel, J.M., Wolfson, A.B. and Lawrence, B. (1972) Decaffeination Process, U.S. Patent No. 3, 671, 263.

    Google Scholar 

  15. Norris, F.A. (1982) Extraction of Fats and Oils, Chapter 3 in Bailey’s Industrial Oil and Fat ProductsVol. 2, 4th edn, (ed. D. Swem), Wiley, New York.

    Google Scholar 

  16. Berry, N.E. and Walters, R.H. (1943) Process of decaffeinating coffee, U.S. Patent No. 2,309,092.

    Google Scholar 

  17. Nutting, L. and Chong, G.S. (1968) Continuous process for producing decaffeinated beverage extract, U.S. Patent No. 3, 361, 571.

    Google Scholar 

  18. Korner, J-P. (1984) Supercritical gas extraction, Food Engineering International, November Issue, 40.

    Google Scholar 

  19. Sims, M. (1990) Decaffeinating with carbon dioxide, Tea and Coffee Trade Journal, September Issue, 8–10.

    Google Scholar 

  20. Zosel, K. (1964) Belgium Patent No. 646641.

    Google Scholar 

  21. Zosel, K. (1965) Studiengesellschaft Kohle, Chemical Abstracts, 63, 110456.

    Google Scholar 

  22. Zosel, K. (1976) U.S. Patent 3,969, 196.

    Google Scholar 

  23. Zosel, K. (1974) U.S. Patent 3,806, 619.

    Google Scholar 

  24. Zosel, K. (1980) Separation with supercritical gases; practical applications, Chapter in Extraction with Supercritical Gases (ed. Verlag Chemie, Weinheim.

    Google Scholar 

  25. Zosel, K. (1981) U.S. Patent 4,247, 570.

    Google Scholar 

  26. Prasad, R., Gottesman, M. and Scarella, R.A. (1981) U.S. Patent 4,246,291.

    Google Scholar 

  27. McHugh, M. and Krukonis, V. (1986) Supercritical Fluid Extraction, Butterworths, Boston, p. 343.

    Google Scholar 

  28. Margolis, G. and Chiovini, J. (1981) US Patent 4, 251, 559.

    Google Scholar 

  29. Lack, E., Seidlitz, H. and Toro, P. (1989) Proceedings of 13th ASIC Conference held at Paipa, Columbia, in August.

    Google Scholar 

  30. Lack, E. and Seidlitz, H. (1990). Findings and experience acquired in operating industrial high pressure extraction plants with supercritical CO2, in Second International Symposium on High Pressure Chemical Engineering (Erlangen, September 1990), organisers Dechema (Frankfurt) and GVC (Dusseldorf), abstract Handbook pp. 473–480.

    Google Scholar 

  31. Hubert, P. and Vitzthum, O. (1978) German Patent Specification DE 2637197 C2.

    Google Scholar 

  32. Vitzthum, O. and Hubert, P. (1975) US Patent 3, 879, 569.

    Google Scholar 

  33. Peter, S. (1979) German Patent Application 2737793.

    Google Scholar 

  34. Peter, S. and Brunner, G. (1982) US Patent 4, 322, 445.

    Google Scholar 

  35. Roselius, L., Kurzhals, H.A. and Hubert, P. (1981) US Patent 4, 255, 458.

    Google Scholar 

  36. Katz, S.N. and Gottesman, M. (1981) US Patent 4, 276, 315.

    Google Scholar 

  37. McHugh, M. and Krukonis, V. (1986) Supercritical Fluid Extraction, Butterworths, Boston, p. 357.

    Google Scholar 

  38. Roselius, W, Vitzthum, O. and Hubert, P. (1971) German Patent Specification DE 2119678.

    Google Scholar 

  39. Roselius, W. Vitzthum, O. and Hubert, P. (1974) U.S. Patent 3, 843, 824.

    Google Scholar 

  40. Gehring, Vitzthum, O. and Wiengas (1984) German Patent Specification DE 3303679 C2.

    Google Scholar 

  41. Vitzthum, O. and Hubert, P. (1973) German Patent Specification DE 2127642. (See also U.S. Patent 4,167,589.)

    Google Scholar 

  42. Klima, Schutz, and Vollbrecht, (1990) European Patent Specification 0200150.

    Google Scholar 

  43. Clarke, R.J. (1988) Patenting of Inventions, Chapter 7 in Coffee, Vol. 6 Commercial and Technico-Legal Aspects, (eds. R.J. Clarke and R. Macrae), Elsevier, London, pp.

    Google Scholar 

  44. McHugh, M. and Krukonis, V. (1986) Supercritical Fluid Extraction, Butterworths, Boston, pp. 182–185.

    Google Scholar 

  45. Meyer, J.F., Roselius, L. and Wimmer, K.H. (1908) US Patent 897, 763.

    Google Scholar 

  46. Zogg, M., Inhomogens Fliessbett, in Einfuhrung in die Mechanische Verfohrenstechnitz,Teabner, Stuttgart, pp.

    Google Scholar 

  47. Saamer, P., Hiltowsky, J. and Dierkes, H. (1984) Chemie Technik, 13 (9), 152–159.

    Google Scholar 

Download references

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1993 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Lack, E., Seidlitz, H. (1993). Commercial scale decaffeination of coffee and tea using supercritical CO2 . In: King, M.B., Bott, T.R. (eds) Extraction of Natural Products Using Near-Critical Solvents. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-2138-5_5

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-2138-5_5

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4947-4

  • Online ISBN: 978-94-011-2138-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics