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Infrared Spectroscopy as a Probe of Surface Acidity

  • Chapter
Elementary Reaction Steps in Heterogeneous Catalysis

Part of the book series: NATO ASI Series ((ASIC,volume 398))

Abstract

The application of infrared spectroscopy for the study of surface acidity requires suitable probe molecules. A classification of such probe molecules is given and their suitablility for discrimination between protonic (Bronsted) and non-protonic (Lewis) acidity, and for the determination of surface acidity in terms of acid strength and site density is discussed. Selected examples are described with special emphasis being payed to acidic properties of simple binary oxides, supported oxides and zeolites.

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Authors and Affiliations

  1. Institut für Physikalische Chemie, Universität München, 8000, München 2, Germany

    H. Knözinger

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  1. H. Knözinger
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Editors and Affiliations

  1. Leverhulme Centre for Innovative Catalysis, Department of Chemistry, University of Liverpool, Liverpool, UK

    R. W. Joyner

  2. Schuit Institute of Catalysis, Eindhoven Technical University, Eindhoven, The Netherlands

    R. A. van Santen

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Knözinger, H. (1993). Infrared Spectroscopy as a Probe of Surface Acidity. In: Joyner, R.W., van Santen, R.A. (eds) Elementary Reaction Steps in Heterogeneous Catalysis. NATO ASI Series, vol 398. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1693-0_16

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  • DOI: https://doi.org/10.1007/978-94-011-1693-0_16

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