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Aspects of Component Interactions in Polymer Systems

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Book cover The Interfacial Interactions in Polymeric Composites

Part of the book series: NATO ASI Series ((NSSE,volume 230))

Abstract

The paper examines the influence of interactions at polymer surfaces and interfaces on the properties of polymer systems, with emphasis on acid/base interactions. The method of inverse gas chromatography is used to evaluate the donor-acceptor interaction potential of components in polymer systems. The usefulness of the interaction parameters is established by their ability to rationalize diverse properties of polymer systems, including the adsorption of polymers on pigments, and the effectiveness of thermal stabilizers in pigmented polymers. Various strategies for controlling surface and interfacial interactions in polymer systems are reviewed, with emphasis placed on the ability of polymers to adopt various surface orientations and compositions. These inherent surface modification effects are attributed to thermodynamic driving forces, and are shown to influence polymer adhesion, barrier and other properties dependent on surface and interfacial forces.

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Author information

Authors and Affiliations

  1. Department of Chemical Engineering, Ecole Polytechnique, P.O. Box 6079, Stn.A, Montreal, Que, H3C 3A7, Canada

    H. P. Schreiber

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  1. H. P. Schreiber
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Editor information

Editors and Affiliations

  1. Department of Chemistry, Polymer Science and Technical Program, Middle East Technological University, Ankara, Turkey

    Güneri Akovali

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© 1993 Springer Science+Business Media Dordrecht

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Schreiber, H.P. (1993). Aspects of Component Interactions in Polymer Systems. In: Akovali, G. (eds) The Interfacial Interactions in Polymeric Composites. NATO ASI Series, vol 230. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1642-8_2

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  • DOI: https://doi.org/10.1007/978-94-011-1642-8_2

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4717-3

  • Online ISBN: 978-94-011-1642-8

  • eBook Packages: Springer Book Archive

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