Abstract
The identification of dye structure can usually be conducted using 1H and 13C NMR, mass spectra and elemental analysis, but the chromophoric system of the dye can be determined with the aid of visible and/or near infra-red (NIR) absorption spectra. For instance, advances in quantum chemistry and the application of the newer techniques to dye chemistry have resulted in the development of new methodology for the identification of dye chromophores. In addition, the absorption spectra of dye chromophores can be predicted using straightforward molecular orbital (MO) calculations, such as those employed in the Pariser-Parr-Pople molecular orbital (PPP MO) method. The molecular design of dyes having a predetermined absorption spectra thus becomes possible, and, consequently, the identification of dye chromophores from their absorption spectra also becomes possible.
Keywords
- Bathochromic Shift
- Substituent Effect
- Chromophoric System
- Large Bathochromic Shift
- Optical Recording Medium
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.
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Matsuoka, M. (1995). Near IR spectroscopy. In: Peters, A.T., Freeman, H.S. (eds) Analytical Chemistry of Synthetic Colorants. Advances in Color Chemistry Series, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1358-8_3
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DOI: https://doi.org/10.1007/978-94-011-1358-8_3
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