Abstract
Surface-active agents are compounds which will adsorb at an air-water or oil-water interface and at the surface of solids. The adsorption process plays a fundamental role in an understanding of the properties of surfactants (an acronym for surface-active agents), since it is the change in interfacial free energy and surface charge resulting from adsorption which leads to their emulsifying and suspending properties. In addition to adsorption at interfaces, surfactants give rise to aggregates, named micelles, provided their concentration attains a threshold value (critical micelle concentration, cmc). Adsorption and micellization are, therefore, the two ways by which surfactants display their unusual properties.
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References
M. J. Rosen, Chemtec, 292 (1985).
D. Attwood and A. T. Florence, Surfactant Systems, Chapman & Hall, London and New York, 1985, Ch. 1.
Surfactant Science Series, Marcel Dekker, New York and Basel.
M. E. Diaz Garcia and A. Sanz-Medel, Talanta, 33, 255 (1986).
E. Barni, P. Savarino and G. Viscardi, Acc. Chem. Res., 24, 98 (1991).
K. Hoshino, T. Saji, K. Suga and M. Fujira, J. Chem. Soc. Faraday Trans. 1, 84, 2667 (1988).
H. E. Fierz-David and K. Kuster, Helv. Chim. Acta, 22, 82 (1939).
J. Meybeck and P. Galafassi, Appl. Polym. Symp., 18, 463 (1971).
H. Kuhn, D. Möbius and H. Bücher, in Techniques of Chemistry, Vol I, Physical Methods of Chemistry, (A. Weissberger and B. W. Rossiter eds), Part IIIB, Wiley-Interscience, New York, 1972, p. 577.
K. B. Blodgett and I. Langmuir, Phys. Rev., 51, 980 (1937).
C.H. Giles, Rev. Prog. Color. Relat. Top., 11, 89 (1981).
H. Kuhn and D. Möbius, Angew. Chem., 10, 620 (1971).
I. Ledoux, D. Josse, P. Vidakovic, J. Zyss, R. A. Hann, P. F. Gordon, B. D. Bothwell, S. K. Gupta, S. Allen, P. Robin, E. Chastaing and J. C. Dubois, Europhys. Lett., 3, 803 (1987).
Jian Ping Gao and G. D. Darling, J. Am. Chem. Soc., 114, 3997 (1992).
P. F. Gordon, in The Chemistry and Application of Dyes (D. R. Waring and G. Hallas eds), Plenum Press, New York and London, 1990, pp. 402–4.
K. Naito, A. Miura and M. Azuma, J. Am. Chem. Soc., 113, 6386 (1991).
H. Grüniger, D. Möbius and H. Meyer, J. Chem. Phys., 79, 3701 (1983).
G. Scheibe, Z. Angew. Chem., 50, 212 (1937).
E. E. Jelley, Nature (London), 139, 631 (1937).
U. Lehmann, Thin Solid Films, 160, 257 (1988).
T. Nagamura, K. Matano and T. Ogawa, J. Phys. Chem., 91, 2019 (1987).
S. P. Gromov, M. V. Fomina, G. K. Chudinova, V. A. Barachevskii and M. V. Alfimov, Dokl. Akad. Nauk SSSR, 321, 739 (1991);
S. P. Gromov, M. V. Fomina, G. K. Chudinova, V. A. Barachevskii and M. V. Alfimov, Chem. Abstr., 116, 196207d (1992).
K. Ogawa, K. Ueda, H. Tamura, M. Hatada and T. Ishihara, Langmuir, 5, 1326 (1989).
H. Junichi and A. Eiji, Jpn. Kokai Tokkyo Koho JP 01 148 590;
H. Junichi and A. Eiji, Chem. Abstr., 112, 45815a (1990).
G. Decher and B. Tieke (Ciba-Geigy A.G.) Eur. Pat. Appl. EP 299 921;
G. Decher and B. Tieke Chem. Abstr., 111, 24961a (1989).
M. Matsumoto, T. Sekiguchi, H. Tanaka, M. Tanaka, T. Nakamura, H. Tachibana, E. Manda and Y. Kawabata, J. Phys. Chem., 93, 5877 (1989).
K. Yasujiro, Nippon Kagaku Kaish 1, 1087 (1990);
K. Yasujiro, Chem. Abstr., 114, 12635w (1991).
E. Barni, P. Savarino, E. Pelizzetti and G. Rothenberger, Helv. Chim. Acta, 64, 1943 (1981).
E. Barni, P. Savarino, G. Viscardi and E. Pelizzetti, J. Heterocycl. Chem., 20, 23 (1983).
E. Barni, P. Savarino and E. Pelizzetti, Nouv. J. Chim., 7, 711 (1983).
E. Barni, P. Savarino, R. Larovere, G. Viscardi and E. Pelizzetti, J. Heterocycl. Chem., 23, 209 (1986).
E. Barni, P. Savarino, G. Viscardi and E. Pelizzetti, Heterocycl. Chem., 22, 1727 (1985).
J. H. Fendler, Membrane Mimetic Chemistry, Wiley, New York, 1982.
D. M. Marmion, Handbook of U. S. Colorants, Wiley, New York, 1991, p. 120.
J. H. Fuhrhop, M. Krull, A. Schulz and D. Möbius, Langmuir, 6, 497 (1990).
M. Shimomura and T. Kunitake, J. Am. Chem. Soc., 109, 5175 (1987).
Tatsuo Katsura, Langmuir, 5, 883 (1989).
H. Ephardt and P. Fromherz, J. Phys. Chem., 93, 7717 (1989).
S. Shigeru, G. Yasuo, M. Sanae and I. Yutaka, Shikizai Kyokaishi, 62, 594 (1989); Chem Abstr.
I. Yutaka, G. Yasuo and M. Sanae, Shikizai Kyokaishi, 64, 431 (1991);
I. Yutaka, G. Yasuo and M. Sanae, Chem. Abstr., 116, 85791v (1992).
D. Langevin, J. Meunier and A. M. Cazabat, La Recherche, 16, 720 (1985).
S. E. Friberg and P. Bothorel, Microemulsions: Structure and Dynamics, CRC Press, Boca Raton, 1987.
H. L. Rosano and M. Clausse, Microemulsions Systems, Marcel Dekker, New York and Basel, 1987.
K. R. Wormuth, L. A. Cadwell and E. W. Kaler, Langmuir, 6, 1035 (1990).
P. Savarino, G. Viscardi and E. Barni, Colloids Surf., 48, 47 (1990).
L. K. J. Tong, in The Theory of the Photographic Process (T. H. James ed), 4th edn, Macmillan, New York, Collier Macmillan, London, 1977, pp. 339–53.
L. J. Fleckenstein, in The Theory of the Photographic Process (T. H. James ed), 4th edn, Macmillan, New York, Collier Macmillan, London, 1977, pp. 353–62.
P. Savarino, G. Viscardi, E. Barni, E. Pelizzetti, E. Pramauro and C. Minero, Ann. Chim. (Rome), 77, 285 (1987).
H. Zollinger, Color Chemistry, VCR, Weinheim, 1991, Ch. 11.
W. L. Hinze and D. W. Armstrong (eds), Ordered Media in Chemical Separations, ACS Symp. Ser. 342, American Chemical Society, Washington, DC, 1987.
E. Pramauro and E. Pelizzetti, Trends Anal. Chem., 7, 260 (1988).
R. O. Dunn, Jr, J. F. Scamehorn and S. D. Christian, Sep. Sci. Technol., 20, 257 (1985).
E. Pramauro, A. Bianco, E. Barni, G. Viscardi and W. L. Hinze, Colloids Surf., 63, 291 (1992).
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Barni, E., Savarino, P., Viscardi, G. (1995). Amphiphilic dyes. In: Peters, A.T., Freeman, H.S. (eds) Modern Colorants: Synthesis and Structure. Advances in Color Chemistry Series, vol 3. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1356-4_7
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DOI: https://doi.org/10.1007/978-94-011-1356-4_7
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