Abstract
Fluid inclusions of brines with daughter salt crystals are known from magma tic, metamorphic and metasomatic rocks, and have received considerable attention in the literature (e.g. Poty et al., 1974; Crawford et al., 1979; Kreulen, 1980; Touret, 1981; Yardley and Bottrell, 1988). Not infrequently, they coexist with pure or almost pure carbonic inclusions. Such observations demonstrate that natural fluids must be considered as composed of at least 3 essential components: salt, CO2 and H2O, but there has been a paucity of experimental data on fluid systems of this complexity. Studies of metamorphic fluid evolution including the effects of fluid immiscibility by Bowers and Helgeson (1983), Trommsdorff et al. (1985), Trommsdorff and Skippen (1986) and Skippen (1988) have been based on the data of Gehrig (1980).
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References
Antony, T.R. and Cline, H.E. (1972) The thermomigration of biphase vapor-liquid droplet in solid. Acta Metallurgica, 20, 247–55.
Aranovich, L.Ya., Shmulovich, K.I. and Fed’kin, V.V. (1987) The H2O and CO2 regime in regional metamorphism. Intern. Geolog. Review, 29,1379–1401.
Balashov, V.N., Korotaev, M.Yu. and Zaraisky, G.P. (1989) Stationary infiltration of H2O−NaCl solutions under heterogenization conditions. Geokhem. Int., 26 (6), 58–67.
Belonozhko, A.B. and Shmulovich, K.I. (1987) A molecular-dynamics study of a dense fluid in micropores. Geokhem. Int., 24 (6), 1–12.
Bischoff, J.L. and Rosenbauer, R.J., (1986) The system NaCl−H2O: Relations of vapor-liquid near the critical temperature of water and of vapor-liquid-halite from 300 to 500°C. Geochim. Cosmochim. Acta, 50(7), 1437–44.
Bischoff, J.I. and Pitzer, K.S. (1989) Liquid-vapour relations for the system NaCl−H2O: Summary of the P-T-X surface from 300 to 500°C. Amer. J. Sci., 289, 217–48.
Bodnar, R.J., Burnham, C.W. and Sterner, S.M. (1985) Synthetic fluid inclusions in natural quartz: III. Determination of phase equilibrium properties in the system H2O−NaCl to 1000°C and 1500 bars. Geochim. Cosmochim. Acta, 49, 1861–73.
Bodnar, R.J. and Sterner, S.M. (1987) Synthetic fluid inclusions, in Hydro-thermal Experimental Techniques (eds G.C. Ulmer and H.L. Barnes) Wiley-Intersciences, New York, N.Y., pp. 423–57.
Crawford, M.L., Kraus, D.W. and Hollister, L.S. (1979) Petrologic and fluid inclusions study of calc-silicate rocks, Prince Rupert, British Columbia. Amer. J. Sci., 279, 1135–59.
Ebadi, A. and Johannes, W. (1991) Beginning of melting and composition of first melts in the system Qtz−Ab−Or−H2O−CO2. Contrib. Mineral. Petrol., 106, 286–95.
Gehrig, M. (1980) Phasengleichgewichte und PVT-Daten ternarer Mischungen aus Wasser, Kohlendioxid und Natriumclorid bis 3 kbar und 550°C. Dissertation, Univer. Karlsruhe, Hochschulverlag, Freiburg, 212 pp.
Giggenbach, W.F. (1980) Geothermal gas equilibria. Geochim. Cosmochim. Acta, 44, 2021–32.
Hemley, J.J., Cygan, G.L. and D’Angelo, W.M. (1986) Effect of pressure on ore mineral solubilities under hydrothermal conditions. Geology, 14, 377–79.
Japas, M.L. and Franck, E.U. (1985) High pressure phase equilibria and PVT-data of water-nitrogen system to 673 K and 250 MPa. Ber. Bunsenges. Phys. Chem., 89, 793–800.
Koshemchuk, S.K. (1993) The investigation of regularities of two-phase filtration of the water-gas system through porous media. Ph.D. thesis, Moscow, Ver-nadsky Institute of Geochemistry and Analytical Chemistry, 28 pp.
Krader, T. (1985) Phasengleichgewichte und kritische Kurven des ternaren Systems H2O−CH4-NaCl bis 250 MPa und 800 K. Dissertation Univer. Karlsruhe, 107 pp.
Kreulen, R. (1980) CO2-rich fluids during regional metamorphism on Naxos (Greece). Carbon isotopes and fluid inclusions. Amer. J. Sci., 280, 745–71.
Petrenko, G.V., Malinin, S.D. and Arutyunyan, L.A. (1989) An experimental investigation of solubility of heavy metal sulfides in the heterogeneous systems chloride solution-vapor phase. Geokhimia, 6, 882–97 (in Russian).
Plyasunova, N.V. and Shmulovich, K.I. (1991) Phase equilibria in the system CaCl2−H2O at 5 kbar and 500°C. Doklady Academii Nauk SSSR, 319 (3), 738–41 (in Russian).
Poty, B.P., Stalder, H.A. and Weisbrod, A.M. (1974) Fluid inclusions studies in quartz from fissures of Western and Central Alps. Schweiz. Mineral. Petrogr. Mitt., 54, 717–52.
Ramboz, C., Pichavant, M. and Weisbrod, A. (1982) Fluid immiscibility in natural processes: Use and misuse of fluid inclusion data. Chemical Geology, 37, 29–48.
Ravich, M.I. (1974) Water-salt Systems at Elevated Temperatures and Pressures. Nauka Press, Moscow (in Russian).
Ryabchikov, I.D. (1975) The Thermodynamic of Fluid Phase of Granitic Magmas. Nauka Press, Moscow (in Russian).
Skippen, G. (1988) Phase relations in model fluid systems. Rendiconti Delia Societa Italiana di Mineralogia e Pterologia, 43, 7–14.
Shmulovich, K.I. (1988) Carbon Dioxide in High-temperature Processes of Mineral Formations. Nauka Press, Moscow (in Russian).
Shmulovich, K.I. and Plyasunova, N.V. (in press) Phase equilibria in the ternary system H2O−CO2-salt (CaCl2, NaCl) at high temperatures and pressures. Geochem. Int.
Sourirajan, S. and Kennedy, G.C. (1962) The system H2O-NaCl at elevated temperatures and pressures. Amer. J. Sci., 260,115–41.
Steinberg, G.S., Steinberg, A.S. and Merzhanov, A.G. (1984) The fluid mechanism of increasing pressure in magmatic systems. Doklady Academii Nauk, 279 (5), 1081–4 (in Russian).
Suvorova, V.A. and Shmulovich, K.I. (1992) High temperature isotope salt effect. In Proceed. IV Intern. Sympos. Experim. Miner. Petrol, and Geochem. Clermont-Ferrand, p. 43.
Takenouchi, S. and Kennedy, G.C. (1964) The binary system H2O−CO2 at high temperatures and pressures. Amer. J. Sci., 262, 1055–67.
Takenouchi, S. and Kennedy, G.C. (1965) The solubility of carbon dioxide in NaCl solutions at high temperatures and pressures. Amer. J. Sci., 263, 445–64.
Tkachenko, S.I. and Shmulovich, K.I. (1992) Liquid-vapour equilibria in the systems water-salt (NaCl, KCl, CaCl2, or MgCl2) at 400-600°C. Doklady Akademii Nauk SSSR, 326 (6), 1055–9 (in Russian).
Touret, J. (1981). Fluid inclusions in high grade metamorphic rocks. Mineral. Assoc. Canada Short Handbook, 6,182–208.
Trommsdorff, V., Skippen, G. and Ulmer, P. (1985) Halite and sylvite assolid inclusions in high-grade metamorphic rocks. Contrib. Mineral. Petrol., 89, 24–9.
Trommsdorff, V. and Skippen, G. (1986) Vapour loss (Boiling) as a mechanism for fluid evolution in metamorphic rocks. Contrib. Miner. Petrol., 94, 317–22.
Urusova, M.A. (1974) Phase equilibria and thermodynamic characteristics of solutions in the systems NaCl−H2O and NaOH−H2O at 350–550°C. Geochem. Int., 11 (5), 944–50.
Vakulenko, A.G., Alekhin Yu.V. and Razina, M.V. (1989) Solubility and thermodynamic properties of alkali chlorides in steam. In Proc. II Intern. Sympos. ‘Properties of water and steam’, Prague, pp. 395–401.
Vapnik, Eu.A. (1988) The fluid regime of anatexis and diatexis at different metamorphic conditions. Ph.D. thesis, Leningrad Univers., 23 pp. (in Russian).
Yardley, B.W.D. and Bottrell, S.H. (1988) Immiscible fluids in metamorphism: Implications of two-phase flow for reaction history. Geology, 16, 199–202.
Zhang, Yi-G. and Frantz, J.D. (1989) Experimental determination of the compositional limits of immiscibility in the system CaCl2H2O−CO2 at high temperatures and pressures using synthetic fluid inclusions. Chemical Geology, 74, 289–308.
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Shmulovich, K.I., Tkachenko, S.I., Plyasunova, N.V. (1994). Phase equilibria in fluid systems at high pressures and temperatures. In: Shmulovich, K.I., Yardley, B.W.D., Gonchar, G.G. (eds) Fluids in the Crust. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1226-0_8
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DOI: https://doi.org/10.1007/978-94-011-1226-0_8
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