Skip to main content

Arsenic removal in anode refining by flux injection

  • Chapter
Mining Latin America / Minería Latinoamericana
  • 266 Accesses

Abstract

Refining operations present an opportunity for impurity removal from molten copper. Anode copper at Chuquicamata Smelter contains, at certain times, levels of As which is inacceptably high for the subsequent step of electrorefining. Several tests were carried out to implement the flux injection technique as a standard practice in the anode furnace. Test results for arsenic removal from molten copper and flux utilization as a function of several operational parameters are analyzed. Special reference is made to the effect of Na2O and CaO content in slag on the removal of arsenic and antimony. It is shown that the rate of removal content is dependent on the flux rate of injection into the copper. On the basis of the above, the flux injection rate is now calculated using an appropiate model.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Basagoitía, A. (1974) As and Sb eliminations in copper fire refining. IIMCh, Santiago, Chile, pp. 219–231.

    Google Scholar 

  2. Devia, M. and Luraschi, A. (1984) Kinetics of arsenic and antimony elimination by slagging in copper refining. TMS Symposium on metallurgical slags and fluxes, Nevada, USA, pp. 643–648.

    Google Scholar 

  3. Takeda, Y. and Riveros, G. (1986) Equilibria among sodium carbonate, sodium ferrite slag and liquid copper. Metallurgical review of MMIJ, Tokyo, 3 (3), pp. 60–71.

    Google Scholar 

  4. Riveros, G., Péndola, E. and Luraschi, A. (1988) Consideraciones básicas en el diseño de sistemas de transporte e inyección de sólidos para procesos metalúrgicos no ferrosos. CONAMET 88, Santiago, Chile, pp. 371–382.

    Google Scholar 

  5. Bassa, R., Del Campo, A. and Barría, C. (1988) Copper pyrorefining using flux injection through tuyeres in a rotary anode furnace. Copper 87,4, Santiago, Chile, pp. 149–166.

    Google Scholar 

  6. Riveros, G., Gajardo, P. and Luraschi, A. (1988) Developments in fire refining of copper-flux injection into molten copper. Copper 87, 4, Santiago, Chile, pp. 239–254.

    Google Scholar 

  7. Riveros, G., Luraschi, A., et al., (1989) Procedimiento para la remoción de As, Sb y otras impurezas mediante inyección de fundentes en hornos de refino. Chilean Patent No. 37 876.

    Google Scholar 

  8. Riveros, G. and Luraschi, A. (1994) Advances in the copper fire refining process in Chile. To be presented at TMS Annual Meeting, 1994.

    Google Scholar 

  9. Luraschi, A., Riveros, G. and Urra, F. (1982) Puesta en operación del proceso de refinación a fuego con horno basculante. CIMM Report P-173 for El Teniente, Santiago, Chile.

    Google Scholar 

  10. Riveros, G. (1984) Investigación sobre la distributión de As y Sb en sistemas líquidos escoria-cobre. Procs. IV Congress of Mining Eng., Copiapó, Chile, pp. 413–422.

    Google Scholar 

  11. Recaval, H., Del Campo, A. and N. Santander, (1984) Estudio de la etapa de oxidación del refino a fuego mediante coeficientes de distributión escoria-metal Procs. IV Congress of Mining Eng., Copiapó, Chile, pp. 443–454.

    Google Scholar 

  12. Riveros, G., Salas R. and J. Zúñiga, (1992) Suministro de tecnología de pirorefinación de cobre y eliminación de arsénico en horno de anodos. CIMM Report NQ 4, P-5008 for Chuquicamata, Santiago, Chile.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1994 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Riveros, G.A., Salas, R.I., Zúñiga, J.A., Jiménez, O.H. (1994). Arsenic removal in anode refining by flux injection. In: Mining Latin America / Minería Latinoamericana. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1216-1_28

Download citation

  • DOI: https://doi.org/10.1007/978-94-011-1216-1_28

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4533-9

  • Online ISBN: 978-94-011-1216-1

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics