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Recovery of acids and bases used in metal treatment processes by diffusion dialysis

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Hydrometallurgy ’94

Abstract

The recovery of waste acid has been successfully achieved for a number of years using various processes. DD (Diffusion Dialysis) has been shown to be an attractive process on a commercial scale, because of its simplicity, reliability and relatively low operating cost.

DD has been particularly successful in the recovery of relatively expensive acids such as HF and HN03. However, with increasingly strict control of waste stream quality, the recovery of even less expensive acids has been found of interest.

Recovery of acids by means of DD is in the range of 80 – 90%, treating acids in a concentration range of 1 – 7 Normal. It is possible to attain salt content as low as 10 ppm, by the use of Neosepta AHS-2.

Recently, new membranes have been developed which can be used in the DD process for the recovery of bases. Base permeable membranes are of particular interest to industries where basic surface treatment is involved, such as surface etching of aluminium in the aerospace industry. An industrial plant for the treatment of aluminium etchant has recently been built. This involves a system which maintains the purity of the etching solution and controls the metal level without giving rise to a waste stream; DD is an important component of the system.

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References

  1. Noma Y. (dy1989) Recovery of Metal Ions and Acid by Ion-Exchange Membranes, Extraction Metallurgy ′89, 1081–1105

    Google Scholar 

  2. Use of Dialysis in Metal Finishing Process, Technical Bulletin, Asahi Glass Co.

    Google Scholar 

  3. Kobuchi Y., Motomura H., Noma Y. and Hanada F. (1984) Application of the Ion Exchange Membranes/Acid Recovery by Diffusion Dialysis, Paper presented at Europe-Japan Congr. on Membranes and Membrane Processes, Stresa, Italy

    Google Scholar 

  4. Kawate H., Tsuzura K. and Shimizu H. (1991) Chapter 1.10, Ion Exchangers ed. Dorfner K., de Gruyter, Berlin, New York

    Google Scholar 

  5. Recovery of Acid in a Process of Plating — Diffusion Dialysis Process, Technical Bulletin, Tokuyama Soda Co. Tokyo, Japan.

    Google Scholar 

  6. Sato J., Onuma M., Motomura H., Noma Y. (1984) Recovery of Nitric Acid and Hydrofluoric Acid from the Pickling Solution by Diffusion Dialysis, Jitsumu Hyomen Gijitsu (The Metal Finishing Society of Japan)

    Google Scholar 

  7. Diffusion Dialyzer for Acid Recovery, Technical Bulletin, Tokuyama Soda Co.

    Google Scholar 

  8. Tokuyama Soda Co., Private Communication

    Google Scholar 

  9. Eurodia, Private Communication

    Google Scholar 

  10. Herz G. (1991) Treatment of Pickling Acids with Ion Exchange and Related Processes, Chapter 2.9, Ion Exchangers, ed. Dorfner K., de Gruyter, Berlin, New York

    Google Scholar 

  11. Byszewski C. and Jaffari M. (1993) Diffusion Dialysis for the Recovery of Aluminium from Caustic Etchant / Milling Solutions, Separation Science & Technology

    Google Scholar 

  12. Davis T.A. (1991) Recovery of Sodium Hydroxide and Aluminium Hydroxide from Etching Wastes: U.S. Patent 5, 049, 233. The Graver Company

    Google Scholar 

  13. Jaffari M. and Byszewski C. (1992) New Membrane-Based Caustic Recycle Process: Paper presented at the 7th Annual Aerospace Hazardous Materials Management Conference, Sept

    Google Scholar 

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© 1994 Springer Science+Business Media Dordrecht

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Herz, G.P., Byszewski, C., Jaffari, M. (1994). Recovery of acids and bases used in metal treatment processes by diffusion dialysis. In: Hydrometallurgy ’94. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1214-7_40

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  • DOI: https://doi.org/10.1007/978-94-011-1214-7_40

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4532-2

  • Online ISBN: 978-94-011-1214-7

  • eBook Packages: Springer Book Archive

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