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Part of the book series: NATO ASI Series ((ASIC,volume 431))

Abstract

A well developed approach to the study of complicated systems (proteins, liquid crystals, membranes) is based on the use of probes, either molecules or stable free radicals, which, dissolved in the system under investigation, report on the structure and dynamics of the complex system. In liquid crystals the order and dynamics of the probe, revealed by a suitable spectroscopic technique, can be used to investigate the mesophases under various conditions, including phase changes and biphasic regions. For lyotropic systems the solvent itself can be used as a probe of the behaviour of the aggregates. We should be aware, however, that the probe can disturb the mesophase or vice versa that the solvent can more or less deform the dissolved molecular probe. Moreover the anisotropic potential acting on a dissolved molecule is a solute-solvent property of the solution and therefore can provide the possibility of gaining valuable insight into the mechanism governing solute-solvent interactions.

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References

  1. Luz, Z. and Meiboom, S. (1973) J. chem. Phys., 59, 275;

    Article  ADS  Google Scholar 

  2. Ramanavare, S. R., Pisipati, V. G. K. M. and Freed, J. H. (1988) Liq. Crystals, 3, 95.

    Article  Google Scholar 

  3. Attard, G. S., Emsley, J., Khoo, S. K. and Luckhurst, G. R. (1984) Chem. Phys. Left., 103, 244.

    Article  ADS  Google Scholar 

  4. Yannoni, C. (1969) J. Am. chem. Soc., 90, 4610.

    Google Scholar 

  5. Orwoll, R. D. and Vold, R. L. (1971) J. Am. Chem. Soc., 93, 5335.

    Article  Google Scholar 

  6. Catalano, D., Forte, C., Veracini, C. A., Emsley, J. and Shilstone, G. N. (1987) Liq. Crystals, 2, 357.

    Article  Google Scholar 

  7. Luz, Z., Goldfarb, D. and Zimmermann, H. (1985) Nuclear Magnetic Resonance of Liquid Crystals, J. W. Emsley (ed.), Reidel, Dordrecht, p. 343.

    Google Scholar 

  8. Poliks, M. D., Parks, Y. W. and Samulski, E. T. (1987) Molec. Crystals Liq. Crystals, 153, 321.

    Google Scholar 

  9. Vold, R. R. (1985) Nuclear Magnetic Resonance of Liquid Crystals, J. W. Emsley (ed.), Reidel, Dordrecht, p. 231;

    Google Scholar 

  10. Vold, R. R. ibid., p. 253.

    Google Scholar 

  11. Toriumi, H. and Samulski, E. T. (1982) Liquid Crystals and Ordered Fluids, J. F. Johnson and A. C. Griffm (eds.), Plenum Press, Vol. 4;

    Google Scholar 

  12. b) Catalano, D., Di Bari, L., Veracini, C. A., Shilstone, G. N. and Zannoni, C. (1991) J. chem. Phys., 94, 3928.

    Article  ADS  Google Scholar 

  13. Zannoni, C. (1985) in Nuclear Magnetic Resonance of Liquid Crystals, J. W. Emsley (ed.), Reidel, Dordrecht, p. 1. and references therein.

    Google Scholar 

  14. Veracini, C. A. (1985) in Nuclear Magnetic Resonance of Liquid Crystal, J. W. Emsley (ed.), Reidel, Dordrecht, p. 99.

    Book  Google Scholar 

  15. Nordio, P. L. and Segre, U. (1979) in The Molecular Physics of Liquid Crystals, G. R Luckhurst, and G. W. Gray (eds.), Academic Press.

    Google Scholar 

  16. a) Luckhurst, G. R. and Yeates, R. N. (1976) Molec. Crystals Liq. Crystals, 34, 57.

    Article  Google Scholar 

  17. Freed, J. H., Nayeem, A. and Rananavare, S. B., Chapter 12.

    Google Scholar 

  18. Fontana, M., Chapter 16.

    Google Scholar 

  19. Zannoni, C., Arcioni, A. and Cavatorta, P. (1983) in Chemistry and Physics of Lipids, 32, 179.

    Article  Google Scholar 

  20. Jaynes, E. T. (1957) Phys. Rev., 106, 620.

    Article  MathSciNet  ADS  MATH  Google Scholar 

  21. Zannoni, C. (1988) in Polarized Spectroscopy of Ordered System, A. Samori and E. N. Thulstruip (eds.), Kluwer.

    Google Scholar 

  22. Doane, J. W. (1979) in Magnetic Resonance of Phase Transitions, Academic Press.

    Google Scholar 

  23. Shilstone, G. N., Zannoni, C. and Veracini, C. A. (1989) Liq. Crystals, 4, 303.

    Article  Google Scholar 

  24. Ellis, D. M. and Bjorkstam, J. L. (1967) J. chem. Phys., 46, 4460;

    Article  ADS  Google Scholar 

  25. Barnes, E. G. and Bloom, J. W. (1972) J. chem. Phys., 57, 3082;

    Article  ADS  Google Scholar 

  26. Chapman, G. E., Cambell, I. D. and McLachlan, K. A. (1970) Nature, 225, 639.

    Article  ADS  Google Scholar 

  27. Catalano, D., Forte, C. and Veracini, C. A. (1984) J. Magn. Reson., 60, 190;

    Google Scholar 

  28. Ambrosetti, R., Catalano, D., Forte, C. and Veracini, C. A. (1985) Z. Naturforsch., 41a, 431.

    ADS  Google Scholar 

  29. Catalano, D., Veracini, C. A., Chidichimo, G. and Longeri, M. (1981) J. chem. Soc. Faraday Trans. 2, 77, 2267.

    Google Scholar 

  30. Pedulli, G. F. in Cristalli Liquidi Unical 81, CLUT - Torino.

    Google Scholar 

  31. Luckhurst, G. R. and Zannoni, C. (1977) Proc. Roy. Soc. A, 353, 87.

    Article  ADS  Google Scholar 

  32. Maier, W. and Saupe, A. (1959) Z. Naturforsch. 13a, 564; 14a (1959) 882; 15a (1960) 287.

    ADS  Google Scholar 

  33. Cotter, M. A. (1979) in The Molecular Physics of Liquid Crystals, G. R. Luckhurst and G. W. Gray (eds.), Academic Press, p. 169 and references therein.

    Google Scholar 

  34. Barker, P. B., Van Der Est, A. J., Burnell, E. E., Patey, G. N., de Lange, C. A. and Snijders, J. G. (1984) Chem. Phys. Lett., 107, 426.

    Article  ADS  Google Scholar 

  35. Luckhurst, G. R. (1979) in The Molecular Physics of Liquid Crystals, G. R. Luckhurst and G. W. Gray (eds.), Academic Press, p. 85.

    Google Scholar 

  36. Luckhurst, G. R., Zannoni, C., Nordio, P. L. and Segre, U. (1975) Molec. Phys., 30, 1345.

    Article  ADS  Google Scholar 

  37. Emsley, J. W., Hashin, R., Luckhurst, G. R., Rumbles, R. N. and Viloria, F. R. (1983) Molec. Phys., 49, 1321.

    Article  ADS  Google Scholar 

  38. Catalano, D., Forte, C., Veracini, C. A. and Zannoni, C. (1983) Israel J. Chem., 23, 283.

    Google Scholar 

  39. Emsley, J. W., Luckhurst, G. R., Shilstone, G. N. and Sage, I. (1987) J. chem. Soc. Faraday Trans. 2, 83 371.

    Google Scholar 

  40. Catalano, D., Forte, C., Veracini, C. A., Emsley, J. W. and Shilstone, G. N. (1987) Liq. Crystals, 2, 357.

    Article  Google Scholar 

  41. Van Der Est, A. J., Kok, M. Y. and Burnell, E. E. (1987) Molec. Phys., 60, 387.

    Google Scholar 

  42. Diehl, P., Sykora, S., Niederberger, W. and Burnell, E. E. (1974) J. Magn. Reson., 14, 260.

    Google Scholar 

  43. Diehl, P. (1985) Nuclear Magnetic Resonance of Liquid Crystals, J. W. Emsley (ed.), Reidel, Dordrecht, p. 147.

    Book  Google Scholar 

  44. Snijders, J. G., de Lange, C. A. and Burnell, E. E. (1982) J. chem. Phys., 77, 5386;

    Google Scholar 

  45. b) Emsley, J. W. and Luckhurst, G. R. (1980) Molec. Phys., 41, 19.

    Article  ADS  Google Scholar 

  46. Snyder, L. C. and Meiboom, S. (1986) J. chem. Phys., 44, 4057;

    Article  ADS  Google Scholar 

  47. Ader, R. and Loewenstein, A. (1975) Molec. Phys., 30, 199;

    Article  ADS  Google Scholar 

  48. Amanzi, A., Barili, P. L., Chidichimo, P. and Veracini, C. A. (1976) Phys. Lett., 44, 110.

    Google Scholar 

  49. Lounila, J. and Diehl, P. (1984) Molec. Phys., 56, 254.

    Google Scholar 

  50. Jokisaari, J. and Hiltunen, Y. (1983) Molec. Phys., 50, 1013.

    Article  ADS  Google Scholar 

  51. Imbardelli, D., Chidichimo, G. and Longeri, M. (1987) Chem. Phys. Lett., 135, 319.

    Article  ADS  Google Scholar 

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Veracini, C.A., Shilstone, G.N. (1994). Probe Studies of Liquid Crystals. In: Luckhurst, G.R., Veracini, C.A. (eds) The Molecular Dynamics of Liquid Crystals. NATO ASI Series, vol 431. Springer, Dordrecht. https://doi.org/10.1007/978-94-011-1168-3_11

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  • DOI: https://doi.org/10.1007/978-94-011-1168-3_11

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-4509-4

  • Online ISBN: 978-94-011-1168-3

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